Biological effects and photodegradation by TiO₂ of terpenes present in industrial wastewater
The aim of this work was to study the biological effects of four monoterpenes, i.e. α-pinene, β-pinene, 3-carene and d-limonene present in the wastewater of a citrus transformation factory. The study was carried out by exposing V79 Chinese hamster cells to single terpene or to the mixture of four te...
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| Veröffentlicht in: | Journal of hazardous materials 2011-01, Vol.185 (2-3), p.591-597 |
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| creator | Catanzaro, Irene Avellone, Giuseppe Marcì, Giuseppe Saverini, Marghereth Scalici, Lea Sciandrello, Giulia Palmisano, Leonardo |
| description | The aim of this work was to study the biological effects of four monoterpenes, i.e. α-pinene, β-pinene, 3-carene and d-limonene present in the wastewater of a citrus transformation factory. The study was carried out by exposing V79 Chinese hamster cells to single terpene or to the mixture of four terpenes at concentrations corresponding to those in the wastewater evaluated by head space solid phase micro extraction and gas chromatography (HS-SPME-GC) analyses. Treatments with single or combined terpenes similarly affected cell vitality, but only the combined treatments induced the 6-thioguanine resistant mutants. Moreover the photocatalytic degradation of the four terpenes was successfully achieved with the photocatalyst TiO₂ Degussa P25 in both the actual effluent and in synthetic solutions. |
| doi_str_mv | 10.1016/j.jhazmat.2010.09.059 |
| format | Article |
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The study was carried out by exposing V79 Chinese hamster cells to single terpene or to the mixture of four terpenes at concentrations corresponding to those in the wastewater evaluated by head space solid phase micro extraction and gas chromatography (HS-SPME-GC) analyses. Treatments with single or combined terpenes similarly affected cell vitality, but only the combined treatments induced the 6-thioguanine resistant mutants. Moreover the photocatalytic degradation of the four terpenes was successfully achieved with the photocatalyst TiO₂ Degussa P25 in both the actual effluent and in synthetic solutions.</description><identifier>ISSN: 0304-3894</identifier><identifier>EISSN: 1873-3336</identifier><identifier>DOI: 10.1016/j.jhazmat.2010.09.059</identifier><identifier>CODEN: JHMAD9</identifier><language>eng</language><publisher>Kidlington: Elsevier B.V</publisher><subject>alpha-pinene ; Applied sciences ; beta-pinene ; Biological effects ; carene ; Catalysis ; Catalytic reactions ; Chemical engineering ; Chemistry ; Chinese hamsters ; Citrus ; Degradation ; Exact sciences and technology ; Extraction ; gas chromatography ; General and physical chemistry ; General purification processes ; headspace analysis ; Manufacturing engineering ; mutants ; Photocatalysis ; photocatalyst ; photolysis ; Pollution ; Reactors ; Terpenes ; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry ; Titanium dioxide ; Transformations ; Waste water ; wastewater ; Wastewaters ; Water treatment and pollution</subject><ispartof>Journal of hazardous materials, 2011-01, Vol.185 (2-3), p.591-597</ispartof><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c409t-44880cb17c47ec7ef45c0e14628bcf00ff1d81a97f6e4b1fe97b4e2d8df2201c3</citedby><cites>FETCH-LOGICAL-c409t-44880cb17c47ec7ef45c0e14628bcf00ff1d81a97f6e4b1fe97b4e2d8df2201c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=23848855$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Catanzaro, Irene</creatorcontrib><creatorcontrib>Avellone, Giuseppe</creatorcontrib><creatorcontrib>Marcì, Giuseppe</creatorcontrib><creatorcontrib>Saverini, Marghereth</creatorcontrib><creatorcontrib>Scalici, Lea</creatorcontrib><creatorcontrib>Sciandrello, Giulia</creatorcontrib><creatorcontrib>Palmisano, Leonardo</creatorcontrib><title>Biological effects and photodegradation by TiO₂ of terpenes present in industrial wastewater</title><title>Journal of hazardous materials</title><description>The aim of this work was to study the biological effects of four monoterpenes, i.e. α-pinene, β-pinene, 3-carene and d-limonene present in the wastewater of a citrus transformation factory. The study was carried out by exposing V79 Chinese hamster cells to single terpene or to the mixture of four terpenes at concentrations corresponding to those in the wastewater evaluated by head space solid phase micro extraction and gas chromatography (HS-SPME-GC) analyses. Treatments with single or combined terpenes similarly affected cell vitality, but only the combined treatments induced the 6-thioguanine resistant mutants. Moreover the photocatalytic degradation of the four terpenes was successfully achieved with the photocatalyst TiO₂ Degussa P25 in both the actual effluent and in synthetic solutions.</description><subject>alpha-pinene</subject><subject>Applied sciences</subject><subject>beta-pinene</subject><subject>Biological effects</subject><subject>carene</subject><subject>Catalysis</subject><subject>Catalytic reactions</subject><subject>Chemical engineering</subject><subject>Chemistry</subject><subject>Chinese hamsters</subject><subject>Citrus</subject><subject>Degradation</subject><subject>Exact sciences and technology</subject><subject>Extraction</subject><subject>gas chromatography</subject><subject>General and physical chemistry</subject><subject>General purification processes</subject><subject>headspace analysis</subject><subject>Manufacturing engineering</subject><subject>mutants</subject><subject>Photocatalysis</subject><subject>photocatalyst</subject><subject>photolysis</subject><subject>Pollution</subject><subject>Reactors</subject><subject>Terpenes</subject><subject>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</subject><subject>Titanium dioxide</subject><subject>Transformations</subject><subject>Waste water</subject><subject>wastewater</subject><subject>Wastewaters</subject><subject>Water treatment and pollution</subject><issn>0304-3894</issn><issn>1873-3336</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNp9kcFq3DAQhk1poNu0j1CqS2kv3o4syZKObWiSQiCHJtcKWR5ttHgtV9IS0mMeNU8ShV16LAwIhm_-YT41zQcKawq0_7pdb-_s350t6w5qD_QahH7VrKiSrGWM9a-bFTDgLVOav2ne5rwFACoFXzW_v4c4xU1wdiLoPbqSiZ1HstzFEkfcJDvaEuJMhgdyE66fHh9J9KRgWnDGTJaEGedCwlxr3OeSQg26t7ngva3Uu-bE2ynj--N72tye_7g5u2yvri9-nn27ah0HXVrOlQI3UOm4RCfRc-EAKe87NTgP4D0dFbVa-h75QD1qOXDsRjX6rt7s2Gnz-ZC7pPhnj7mYXcgOp8nOGPfZKNFLBVqrSn75L0l7SblkdXdFxQF1Keac0JslhZ1ND4aCeTFvtuZo3ryYN6BNNV_nPh1X2Fy9-mRnF_K_4Y6peq4Qlft44LyNxm5SZW5_1SBRP0cDZ4I9A8cnke4</recordid><startdate>20110130</startdate><enddate>20110130</enddate><creator>Catanzaro, Irene</creator><creator>Avellone, Giuseppe</creator><creator>Marcì, Giuseppe</creator><creator>Saverini, Marghereth</creator><creator>Scalici, Lea</creator><creator>Sciandrello, Giulia</creator><creator>Palmisano, Leonardo</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>FBQ</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>7SR</scope><scope>7SU</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>JG9</scope><scope>KR7</scope><scope>7QH</scope><scope>7ST</scope><scope>7U7</scope><scope>7UA</scope><scope>SOI</scope></search><sort><creationdate>20110130</creationdate><title>Biological effects and photodegradation by TiO₂ of terpenes present in industrial wastewater</title><author>Catanzaro, Irene ; Avellone, Giuseppe ; Marcì, Giuseppe ; Saverini, Marghereth ; Scalici, Lea ; Sciandrello, Giulia ; Palmisano, Leonardo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c409t-44880cb17c47ec7ef45c0e14628bcf00ff1d81a97f6e4b1fe97b4e2d8df2201c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>alpha-pinene</topic><topic>Applied sciences</topic><topic>beta-pinene</topic><topic>Biological effects</topic><topic>carene</topic><topic>Catalysis</topic><topic>Catalytic reactions</topic><topic>Chemical engineering</topic><topic>Chemistry</topic><topic>Chinese hamsters</topic><topic>Citrus</topic><topic>Degradation</topic><topic>Exact sciences and technology</topic><topic>Extraction</topic><topic>gas chromatography</topic><topic>General and physical chemistry</topic><topic>General purification processes</topic><topic>headspace analysis</topic><topic>Manufacturing engineering</topic><topic>mutants</topic><topic>Photocatalysis</topic><topic>photocatalyst</topic><topic>photolysis</topic><topic>Pollution</topic><topic>Reactors</topic><topic>Terpenes</topic><topic>Theory of reactions, general kinetics. 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| subjects | alpha-pinene Applied sciences beta-pinene Biological effects carene Catalysis Catalytic reactions Chemical engineering Chemistry Chinese hamsters Citrus Degradation Exact sciences and technology Extraction gas chromatography General and physical chemistry General purification processes headspace analysis Manufacturing engineering mutants Photocatalysis photocatalyst photolysis Pollution Reactors Terpenes Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry Titanium dioxide Transformations Waste water wastewater Wastewaters Water treatment and pollution |
| title | Biological effects and photodegradation by TiO₂ of terpenes present in industrial wastewater |
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