Isolation and Reaction of 1,2-Dithietan-3-one: Formation of Thiolato Thiocarboxylato Metal Complexes
The reaction of 4,4-di-tert-butyl-1,2-dithietan-3-one with triphenylphosphine afforded 1,1-di-tert-butylthiiran-2-one (86%). The reaction of 4,4-di-tert-butyl-1,2-dithietan-3-one with phenylmagnesium bromide gave S-phenyl 2-tert-butyl-2-mercapto-3,3-dimethylbutanethioate in 83% yield. The reaction o...
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| Veröffentlicht in: | Bulletin of the Chemical Society of Japan 2009, Vol.82 (7), p.855-859 |
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| container_title | Bulletin of the Chemical Society of Japan |
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| creator | Shigetomi, Toshiyuki Okuma, Kentaro Nagahora, Noriyoshi Yokomori, Yoshinobu |
| description | The reaction of 4,4-di-tert-butyl-1,2-dithietan-3-one with triphenylphosphine afforded 1,1-di-tert-butylthiiran-2-one (86%). The reaction of 4,4-di-tert-butyl-1,2-dithietan-3-one with phenylmagnesium bromide gave S-phenyl 2-tert-butyl-2-mercapto-3,3-dimethylbutanethioate in 83% yield. The reaction of 4,4-di-tert-butyl-1,2-dithietan-3-one with tetrakis(triphenylphosphine)palladium(0) gave square-planar complex in 84% yield, whose structure was determined by X-ray crystallographic analysis. |
| doi_str_mv | 10.1246/bcsj.82.855 |
| format | Article |
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| subjects | Bromides Crystallography X-rays |
| title | Isolation and Reaction of 1,2-Dithietan-3-one: Formation of Thiolato Thiocarboxylato Metal Complexes |
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