Coordination polymer adsorbent for matrix solid-phase dispersion extraction of pesticides during analysis of dehydrated Hyptis pectinata medicinal plant by GC/MS
The coordination polymer [Zn(BDC)(H 2O) 2] n was tested for extraction of pyrimethanil, ametryn, dichlofluanid, tetraconazole, flumetralin, kresoxim-methyl and tebuconazole from the medicinal plant Hyptis pectinata, with analysis using gas chromatography–mass spectrometry in selected ion monitoring...
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| Veröffentlicht in: | Talanta (Oxford) 2010-12, Vol.83 (2), p.631-636 |
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| creator | Aquino, Adriano Wanderley, Kaline A. Paiva-Santos, Carlos de Oliveira de Sá, Gilberto F. Alexandre, Marcelo da R. Júnior, Severino A. Navickiene, Sandro |
| description | The coordination polymer [Zn(BDC)(H
2O)
2]
n
was tested for extraction of pyrimethanil, ametryn, dichlofluanid, tetraconazole, flumetralin, kresoxim-methyl and tebuconazole from the medicinal plant
Hyptis pectinata, with analysis using gas chromatography–mass spectrometry in selected ion monitoring mode (GC/MS, SIM). Experiments carried out at different fortification levels (0.1, 0.5 and 1.0
μg
g
−1) resulted in recoveries in the range 73–97%, and RSD values were between 5 and 12% for the [Zn(BDC)(H
2O)
2]
n
sorbent. Detection and quantification limits ranged from 0.02 to 0.07
μg
g
−1 and from 0.05 to 0.1
μg
g
−1, respectively, for the different pesticides studied. The method developed was linear over the range tested (0.04–14.0
μg
g
−1), with correlation coefficients ranging from 0.9987 to 0.9998. Comparison between [Zn(BDC)(H
2O)
2]
n
and the commercial phase C
18-bonded silica showed good performance of the [Zn(BDC)(H
2O)
2]
n
polymeric sorbent for the pesticides tested. |
| doi_str_mv | 10.1016/j.talanta.2010.10.014 |
| format | Article |
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2O)
2]
n
was tested for extraction of pyrimethanil, ametryn, dichlofluanid, tetraconazole, flumetralin, kresoxim-methyl and tebuconazole from the medicinal plant
Hyptis pectinata, with analysis using gas chromatography–mass spectrometry in selected ion monitoring mode (GC/MS, SIM). Experiments carried out at different fortification levels (0.1, 0.5 and 1.0
μg
g
−1) resulted in recoveries in the range 73–97%, and RSD values were between 5 and 12% for the [Zn(BDC)(H
2O)
2]
n
sorbent. Detection and quantification limits ranged from 0.02 to 0.07
μg
g
−1 and from 0.05 to 0.1
μg
g
−1, respectively, for the different pesticides studied. The method developed was linear over the range tested (0.04–14.0
μg
g
−1), with correlation coefficients ranging from 0.9987 to 0.9998. Comparison between [Zn(BDC)(H
2O)
2]
n
and the commercial phase C
18-bonded silica showed good performance of the [Zn(BDC)(H
2O)
2]
n
polymeric sorbent for the pesticides tested.</description><identifier>ISSN: 0039-9140</identifier><identifier>EISSN: 1873-3573</identifier><identifier>DOI: 10.1016/j.talanta.2010.10.014</identifier><identifier>PMID: 21111184</identifier><identifier>CODEN: TLNTA2</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Adsorption ; Analytical chemistry ; Aniline Compounds - analysis ; Chemistry ; Chemistry Techniques, Analytical ; Chlorobenzenes - analysis ; Chromatographic methods and physical methods associated with chromatography ; Coordination polymer ; Exact sciences and technology ; Gas chromatographic methods ; Gas Chromatography-Mass Spectrometry - methods ; GC/MS ; Hyptis - metabolism ; Matrix solid-phase dispersion ; Medicinal plant ; Methacrylates - analysis ; Microscopy, Electron, Scanning - methods ; Pesticides ; Pesticides - analysis ; Pesticides - chemistry ; Pesticides - pharmacology ; Phenylacetates - analysis ; Plant Extracts ; Plants, Medicinal - metabolism ; Polymers - chemistry ; Pyrimidines - chemistry ; Solid Phase Extraction - methods ; Spectrometric and optical methods ; Strobilurins ; Triazines - analysis ; Triazoles - analysis</subject><ispartof>Talanta (Oxford), 2010-12, Vol.83 (2), p.631-636</ispartof><rights>2010 Elsevier B.V.</rights><rights>2015 INIST-CNRS</rights><rights>Copyright © 2010 Elsevier B.V. All rights reserved.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c473t-b06a5c3f551d1788dcb50a0836e86ddabbcdb86ef762abd6df6b6f837a8c1d933</citedby><cites>FETCH-LOGICAL-c473t-b06a5c3f551d1788dcb50a0836e86ddabbcdb86ef762abd6df6b6f837a8c1d933</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0039914010007897$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65534</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=23630471$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/21111184$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Aquino, Adriano</creatorcontrib><creatorcontrib>Wanderley, Kaline A.</creatorcontrib><creatorcontrib>Paiva-Santos, Carlos de Oliveira</creatorcontrib><creatorcontrib>de Sá, Gilberto F.</creatorcontrib><creatorcontrib>Alexandre, Marcelo da R.</creatorcontrib><creatorcontrib>Júnior, Severino A.</creatorcontrib><creatorcontrib>Navickiene, Sandro</creatorcontrib><title>Coordination polymer adsorbent for matrix solid-phase dispersion extraction of pesticides during analysis of dehydrated Hyptis pectinata medicinal plant by GC/MS</title><title>Talanta (Oxford)</title><addtitle>Talanta</addtitle><description>The coordination polymer [Zn(BDC)(H
2O)
2]
n
was tested for extraction of pyrimethanil, ametryn, dichlofluanid, tetraconazole, flumetralin, kresoxim-methyl and tebuconazole from the medicinal plant
Hyptis pectinata, with analysis using gas chromatography–mass spectrometry in selected ion monitoring mode (GC/MS, SIM). Experiments carried out at different fortification levels (0.1, 0.5 and 1.0
μg
g
−1) resulted in recoveries in the range 73–97%, and RSD values were between 5 and 12% for the [Zn(BDC)(H
2O)
2]
n
sorbent. Detection and quantification limits ranged from 0.02 to 0.07
μg
g
−1 and from 0.05 to 0.1
μg
g
−1, respectively, for the different pesticides studied. The method developed was linear over the range tested (0.04–14.0
μg
g
−1), with correlation coefficients ranging from 0.9987 to 0.9998. Comparison between [Zn(BDC)(H
2O)
2]
n
and the commercial phase C
18-bonded silica showed good performance of the [Zn(BDC)(H
2O)
2]
n
polymeric sorbent for the pesticides tested.</description><subject>Adsorption</subject><subject>Analytical chemistry</subject><subject>Aniline Compounds - analysis</subject><subject>Chemistry</subject><subject>Chemistry Techniques, Analytical</subject><subject>Chlorobenzenes - analysis</subject><subject>Chromatographic methods and physical methods associated with chromatography</subject><subject>Coordination polymer</subject><subject>Exact sciences and technology</subject><subject>Gas chromatographic methods</subject><subject>Gas Chromatography-Mass Spectrometry - methods</subject><subject>GC/MS</subject><subject>Hyptis - metabolism</subject><subject>Matrix solid-phase dispersion</subject><subject>Medicinal plant</subject><subject>Methacrylates - analysis</subject><subject>Microscopy, Electron, Scanning - methods</subject><subject>Pesticides</subject><subject>Pesticides - analysis</subject><subject>Pesticides - chemistry</subject><subject>Pesticides - pharmacology</subject><subject>Phenylacetates - analysis</subject><subject>Plant Extracts</subject><subject>Plants, Medicinal - metabolism</subject><subject>Polymers - chemistry</subject><subject>Pyrimidines - chemistry</subject><subject>Solid Phase Extraction - methods</subject><subject>Spectrometric and optical methods</subject><subject>Strobilurins</subject><subject>Triazines - analysis</subject><subject>Triazoles - analysis</subject><issn>0039-9140</issn><issn>1873-3573</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkcFu1DAQhi0EotvCI4B8QZyytePE8Z4QWtEWqYgDcLbG9oR6lY2D7a2ax-FNcboLHOuLpfH3e2b-n5A3nK054_Jyt84wwJhhXbPH2prx5hlZcdWJSrSdeE5WjIlNteENOyPnKe0YY7Vg4iU5q_lyVLMiv7chROdHyD6MdArDvMdIwaUQDY6Z9iHSPeToH2gKg3fVdAcJqfNpwpgWDT7kCPZRHno6YcreeoeJukP0408KIwxz8ml5dXg3uwgZHb2Zp1yKExZp6Q50j64IC0ynZS9qZnq9vfzy7RV50cOQ8PXpviA_rj59395Ut1-vP28_3la26USuDJPQWtG3LXe8U8pZ0zJgSkhU0jkwxjqjJPadrME46XppZK9EB8pytxHigrw__jvF8OtQ1tB7nywOZRgMh6RVK4tU1fJpkrdtsxF1V8j2SNoYUorY6yn6PcRZc6aXGPVOn2LUS4xLucRYdG9PHQ6m-PJP9Te3Arw7AZAsDH2E0fr0nxNSsKbjhftw5LA4d-8x6mQ9jrZ4HYvz2gX_xCh_AHIewpE</recordid><startdate>20101215</startdate><enddate>20101215</enddate><creator>Aquino, Adriano</creator><creator>Wanderley, Kaline A.</creator><creator>Paiva-Santos, Carlos de Oliveira</creator><creator>de Sá, Gilberto F.</creator><creator>Alexandre, Marcelo da R.</creator><creator>Júnior, Severino A.</creator><creator>Navickiene, Sandro</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7QH</scope><scope>7UA</scope><scope>C1K</scope><scope>F1W</scope><scope>H96</scope><scope>L.G</scope></search><sort><creationdate>20101215</creationdate><title>Coordination polymer adsorbent for matrix solid-phase dispersion extraction of pesticides during analysis of dehydrated Hyptis pectinata medicinal plant by GC/MS</title><author>Aquino, Adriano ; Wanderley, Kaline A. ; Paiva-Santos, Carlos de Oliveira ; de Sá, Gilberto F. ; Alexandre, Marcelo da R. ; Júnior, Severino A. ; Navickiene, Sandro</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c473t-b06a5c3f551d1788dcb50a0836e86ddabbcdb86ef762abd6df6b6f837a8c1d933</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Adsorption</topic><topic>Analytical chemistry</topic><topic>Aniline Compounds - analysis</topic><topic>Chemistry</topic><topic>Chemistry Techniques, Analytical</topic><topic>Chlorobenzenes - analysis</topic><topic>Chromatographic methods and physical methods associated with chromatography</topic><topic>Coordination polymer</topic><topic>Exact sciences and technology</topic><topic>Gas chromatographic methods</topic><topic>Gas Chromatography-Mass Spectrometry - methods</topic><topic>GC/MS</topic><topic>Hyptis - metabolism</topic><topic>Matrix solid-phase dispersion</topic><topic>Medicinal plant</topic><topic>Methacrylates - analysis</topic><topic>Microscopy, Electron, Scanning - methods</topic><topic>Pesticides</topic><topic>Pesticides - analysis</topic><topic>Pesticides - chemistry</topic><topic>Pesticides - pharmacology</topic><topic>Phenylacetates - analysis</topic><topic>Plant Extracts</topic><topic>Plants, Medicinal - metabolism</topic><topic>Polymers - chemistry</topic><topic>Pyrimidines - chemistry</topic><topic>Solid Phase Extraction - methods</topic><topic>Spectrometric and optical methods</topic><topic>Strobilurins</topic><topic>Triazines - analysis</topic><topic>Triazoles - analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Aquino, Adriano</creatorcontrib><creatorcontrib>Wanderley, Kaline A.</creatorcontrib><creatorcontrib>Paiva-Santos, Carlos de Oliveira</creatorcontrib><creatorcontrib>de Sá, Gilberto F.</creatorcontrib><creatorcontrib>Alexandre, Marcelo da R.</creatorcontrib><creatorcontrib>Júnior, Severino A.</creatorcontrib><creatorcontrib>Navickiene, Sandro</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Aqualine</collection><collection>Water Resources Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 2: Ocean Technology, Policy & Non-Living Resources</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><jtitle>Talanta (Oxford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Aquino, Adriano</au><au>Wanderley, Kaline A.</au><au>Paiva-Santos, Carlos de Oliveira</au><au>de Sá, Gilberto F.</au><au>Alexandre, Marcelo da R.</au><au>Júnior, Severino A.</au><au>Navickiene, Sandro</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Coordination polymer adsorbent for matrix solid-phase dispersion extraction of pesticides during analysis of dehydrated Hyptis pectinata medicinal plant by GC/MS</atitle><jtitle>Talanta (Oxford)</jtitle><addtitle>Talanta</addtitle><date>2010-12-15</date><risdate>2010</risdate><volume>83</volume><issue>2</issue><spage>631</spage><epage>636</epage><pages>631-636</pages><issn>0039-9140</issn><eissn>1873-3573</eissn><coden>TLNTA2</coden><abstract>The coordination polymer [Zn(BDC)(H
2O)
2]
n
was tested for extraction of pyrimethanil, ametryn, dichlofluanid, tetraconazole, flumetralin, kresoxim-methyl and tebuconazole from the medicinal plant
Hyptis pectinata, with analysis using gas chromatography–mass spectrometry in selected ion monitoring mode (GC/MS, SIM). Experiments carried out at different fortification levels (0.1, 0.5 and 1.0
μg
g
−1) resulted in recoveries in the range 73–97%, and RSD values were between 5 and 12% for the [Zn(BDC)(H
2O)
2]
n
sorbent. Detection and quantification limits ranged from 0.02 to 0.07
μg
g
−1 and from 0.05 to 0.1
μg
g
−1, respectively, for the different pesticides studied. The method developed was linear over the range tested (0.04–14.0
μg
g
−1), with correlation coefficients ranging from 0.9987 to 0.9998. Comparison between [Zn(BDC)(H
2O)
2]
n
and the commercial phase C
18-bonded silica showed good performance of the [Zn(BDC)(H
2O)
2]
n
polymeric sorbent for the pesticides tested.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><pmid>21111184</pmid><doi>10.1016/j.talanta.2010.10.014</doi><tpages>6</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
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| language | eng |
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| source | MEDLINE; Elsevier ScienceDirect Journals Complete |
| subjects | Adsorption Analytical chemistry Aniline Compounds - analysis Chemistry Chemistry Techniques, Analytical Chlorobenzenes - analysis Chromatographic methods and physical methods associated with chromatography Coordination polymer Exact sciences and technology Gas chromatographic methods Gas Chromatography-Mass Spectrometry - methods GC/MS Hyptis - metabolism Matrix solid-phase dispersion Medicinal plant Methacrylates - analysis Microscopy, Electron, Scanning - methods Pesticides Pesticides - analysis Pesticides - chemistry Pesticides - pharmacology Phenylacetates - analysis Plant Extracts Plants, Medicinal - metabolism Polymers - chemistry Pyrimidines - chemistry Solid Phase Extraction - methods Spectrometric and optical methods Strobilurins Triazines - analysis Triazoles - analysis |
| title | Coordination polymer adsorbent for matrix solid-phase dispersion extraction of pesticides during analysis of dehydrated Hyptis pectinata medicinal plant by GC/MS |
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