Zinc morphology in zinc–nickel flow assisted batteries and impact on performance
The zinc morphology on repeated charging and discharging in flow-assisted zinc–nickel oxide cells was studied. The results show that higher charge rates cause more dendritic growth of zinc deposition on charging and tend to cause deterioration of battery cells. However, when the electrolyte velocity...
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Veröffentlicht in: | Journal of power sources 2011-02, Vol.196 (4), p.2340-2345 |
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creator | Ito, Yasumasa Nyce, Michael Plivelich, Robert Klein, Martin Steingart, Daniel Banerjee, Sanjoy |
description | The zinc morphology on repeated charging and discharging in flow-assisted zinc–nickel oxide cells was studied. The results show that higher charge rates cause more dendritic growth of zinc deposition on charging and tend to cause deterioration of battery cells. However, when the electrolyte velocity is higher than 15
cm
s
−1, the direction of dendrites was distorted toward the flow direction and the internal short circuit was suppressed. Good cycle life was obtained – 1500 cycles at 100% depth of discharge and
C/2 charge and discharge rate. Also, the battery was scaled up to a 100
Wh prismatic cell, and more than 200 cycles were obtained. |
doi_str_mv | 10.1016/j.jpowsour.2010.09.065 |
format | Article |
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cm
s
−1, the direction of dendrites was distorted toward the flow direction and the internal short circuit was suppressed. Good cycle life was obtained – 1500 cycles at 100% depth of discharge and
C/2 charge and discharge rate. Also, the battery was scaled up to a 100
Wh prismatic cell, and more than 200 cycles were obtained.</description><identifier>ISSN: 0378-7753</identifier><identifier>EISSN: 1873-2755</identifier><identifier>DOI: 10.1016/j.jpowsour.2010.09.065</identifier><language>eng</language><publisher>Elsevier B.V</publisher><subject>Batteries ; Charge ; Charging ; Coulombic efficiency ; Discharge ; Distortion ; Electric batteries ; Electrolytic cells ; Energy efficiency ; Flow battery ; Morphology ; Zinc ; Zinc morphology ; Zinc–nickel oxide battery</subject><ispartof>Journal of power sources, 2011-02, Vol.196 (4), p.2340-2345</ispartof><rights>2010 Elsevier B.V.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c344t-b6d4414d6ebcdd2a8d7b41d317e6ce2f174901acbb4e2e08d3b053db5ad16383</citedby><cites>FETCH-LOGICAL-c344t-b6d4414d6ebcdd2a8d7b41d317e6ce2f174901acbb4e2e08d3b053db5ad16383</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jpowsour.2010.09.065$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,778,782,3539,27907,27908,45978</link.rule.ids></links><search><creatorcontrib>Ito, Yasumasa</creatorcontrib><creatorcontrib>Nyce, Michael</creatorcontrib><creatorcontrib>Plivelich, Robert</creatorcontrib><creatorcontrib>Klein, Martin</creatorcontrib><creatorcontrib>Steingart, Daniel</creatorcontrib><creatorcontrib>Banerjee, Sanjoy</creatorcontrib><title>Zinc morphology in zinc–nickel flow assisted batteries and impact on performance</title><title>Journal of power sources</title><description>The zinc morphology on repeated charging and discharging in flow-assisted zinc–nickel oxide cells was studied. The results show that higher charge rates cause more dendritic growth of zinc deposition on charging and tend to cause deterioration of battery cells. However, when the electrolyte velocity is higher than 15
cm
s
−1, the direction of dendrites was distorted toward the flow direction and the internal short circuit was suppressed. Good cycle life was obtained – 1500 cycles at 100% depth of discharge and
C/2 charge and discharge rate. Also, the battery was scaled up to a 100
Wh prismatic cell, and more than 200 cycles were obtained.</description><subject>Batteries</subject><subject>Charge</subject><subject>Charging</subject><subject>Coulombic efficiency</subject><subject>Discharge</subject><subject>Distortion</subject><subject>Electric batteries</subject><subject>Electrolytic cells</subject><subject>Energy efficiency</subject><subject>Flow battery</subject><subject>Morphology</subject><subject>Zinc</subject><subject>Zinc morphology</subject><subject>Zinc–nickel oxide battery</subject><issn>0378-7753</issn><issn>1873-2755</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqFkM1KxDAcxIMouK6-guTmqTVpkqa9KYtfsCDInryENPlXU9umJl1lPfkOvqFPYpfVs6eBYWZgfgidUpJSQvPzJm0G_x79OqQZmUxSpiQXe2hGC8mSTAqxj2aEySKRUrBDdBRjQwihVJIZenh0vcGdD8Ozb_3TBrsef0zW9-dX78wLtLhu_TvWMbo4gsWVHkcIDiLWvcWuG7QZse_xAKH2odO9gWN0UOs2wsmvztHq-mq1uE2W9zd3i8tlYhjnY1LllnPKbQ6VsTbThZUVp5ZRCbmBrKaSl4RqU1UcMiCFZRURzFZCW5qzgs3R2W52CP51DXFUnYsG2lb34NdRFULIjJSlnJL5LmmCjzFArYbgOh02ihK1Raga9YdQbREqUqoJ4VS82BVhuvHmIKhoHEwXrQtgRmW9-2_iByu6gUU</recordid><startdate>20110215</startdate><enddate>20110215</enddate><creator>Ito, Yasumasa</creator><creator>Nyce, Michael</creator><creator>Plivelich, Robert</creator><creator>Klein, Martin</creator><creator>Steingart, Daniel</creator><creator>Banerjee, Sanjoy</creator><general>Elsevier B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7TB</scope><scope>8FD</scope><scope>FR3</scope><scope>KR7</scope><scope>L7M</scope></search><sort><creationdate>20110215</creationdate><title>Zinc morphology in zinc–nickel flow assisted batteries and impact on performance</title><author>Ito, Yasumasa ; Nyce, Michael ; Plivelich, Robert ; Klein, Martin ; Steingart, Daniel ; Banerjee, Sanjoy</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c344t-b6d4414d6ebcdd2a8d7b41d317e6ce2f174901acbb4e2e08d3b053db5ad16383</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Batteries</topic><topic>Charge</topic><topic>Charging</topic><topic>Coulombic efficiency</topic><topic>Discharge</topic><topic>Distortion</topic><topic>Electric batteries</topic><topic>Electrolytic cells</topic><topic>Energy efficiency</topic><topic>Flow battery</topic><topic>Morphology</topic><topic>Zinc</topic><topic>Zinc morphology</topic><topic>Zinc–nickel oxide battery</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ito, Yasumasa</creatorcontrib><creatorcontrib>Nyce, Michael</creatorcontrib><creatorcontrib>Plivelich, Robert</creatorcontrib><creatorcontrib>Klein, Martin</creatorcontrib><creatorcontrib>Steingart, Daniel</creatorcontrib><creatorcontrib>Banerjee, Sanjoy</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of power sources</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ito, Yasumasa</au><au>Nyce, Michael</au><au>Plivelich, Robert</au><au>Klein, Martin</au><au>Steingart, Daniel</au><au>Banerjee, Sanjoy</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Zinc morphology in zinc–nickel flow assisted batteries and impact on performance</atitle><jtitle>Journal of power sources</jtitle><date>2011-02-15</date><risdate>2011</risdate><volume>196</volume><issue>4</issue><spage>2340</spage><epage>2345</epage><pages>2340-2345</pages><issn>0378-7753</issn><eissn>1873-2755</eissn><abstract>The zinc morphology on repeated charging and discharging in flow-assisted zinc–nickel oxide cells was studied. The results show that higher charge rates cause more dendritic growth of zinc deposition on charging and tend to cause deterioration of battery cells. However, when the electrolyte velocity is higher than 15
cm
s
−1, the direction of dendrites was distorted toward the flow direction and the internal short circuit was suppressed. Good cycle life was obtained – 1500 cycles at 100% depth of discharge and
C/2 charge and discharge rate. Also, the battery was scaled up to a 100
Wh prismatic cell, and more than 200 cycles were obtained.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.jpowsour.2010.09.065</doi><tpages>6</tpages></addata></record> |
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source | Elsevier ScienceDirect Journals |
subjects | Batteries Charge Charging Coulombic efficiency Discharge Distortion Electric batteries Electrolytic cells Energy efficiency Flow battery Morphology Zinc Zinc morphology Zinc–nickel oxide battery |
title | Zinc morphology in zinc–nickel flow assisted batteries and impact on performance |
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