Novel antifouling oligo(ethylene glycol) methacrylate particles via surfactant-free emulsion polymerization
Cross-linked PEGEEM colloids that display novel antifouling surface properties are introduced. A simple surfactant-free emulsion polymerization is used to prepare monodisperse cross-linked particles which were characterized by DLS and TEM. [Display omitted] ► PEGEEM colloids with novel antifouling s...
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| Veröffentlicht in: | Journal of colloid and interface science 2011-03, Vol.355 (1), p.76-80 |
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| container_title | Journal of colloid and interface science |
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| creator | Buyukserin, Fatih Camli, Sevket Tolga Yavuz, Mustafa Selman Budak, Gurer Guven |
| description | Cross-linked PEGEEM colloids that display novel antifouling surface properties are introduced. A simple surfactant-free emulsion polymerization is used to prepare monodisperse cross-linked particles which were characterized by DLS and TEM.
[Display omitted]
► PEGEEM colloids with novel antifouling surface properties is reported for the first time. ► Surfactant-free emulsion polymerization was used to prepare monodisperse crosslinked particles. ► A prominent blockage of BSA adsorption was obtained for the PEG-based sub-micron colloids.
The use of particle formulations with antifouling surface properties attracts increasing interest in several biotechnological applications. Majority of these studies utilize a poly(ethylene glycol) coating to render the corresponding surface nonrecognizable to biological macromolecules. Herein, we report a simple way to prepare novel antifouling colloids composed of oligo(ethylene glycol) backbones via surfactant-free emulsion polymerization. Monodisperse cross-linked poly(ethylene glycol) ethyl ether methacrylate particles were characterized by dynamic light scattering and transmission electron microscopy. The effects of monomer, cross-linker and initiator on particle characteristics were investigated. More importantly, a prominent blockage of bovine serum albumin adsorption was obtained for the poly(ethylene glycol)-based sub-micron (∼200
nm) particles when compared with similar-sized poly(methyl methacrylate) counterparts. |
| doi_str_mv | 10.1016/j.jcis.2010.11.081 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_855716902</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0021979710013597</els_id><sourcerecordid>843412888</sourcerecordid><originalsourceid>FETCH-LOGICAL-c417t-df9c10381827676711bd38d65a83e2fca755a2b880267388565d54787c973dd73</originalsourceid><addsrcrecordid>eNqFkU9v1DAQxS1ERZfCF-CAckHAIYvHWce21Auq-FOpKhc4W15nsnhx4sV2VgqfHke79Eg1h9GMfvP0NI-QV0DXQKH9sF_vrUtrRpcFrKmEJ2QFVPFaAG2ekhWlDGollLgkz1PaUwrAuXpGLhmAoq0SK_LrPhzRV2bMrg-Td-OuCt7twjvMP2ePI1Y7P9vg31dD2RgbZ28yVgcTs7MeU3V0pkpT7I3NRaTuI2KFw-STC2N1CH4eMLo_JpfxBbnojU_48tyvyI_Pn77ffK3vvn25vfl4V9sNiFx3vbLFvwTJRFsKYNs1smu5kQ2y3hrBuWFbKSlrRSMlb3nHN0IKq0TTdaK5Im9PuocYfk-Ysh5csui9GTFMSUvOBbSKssfJTbMBJqUsJDuRNoaUIvb6EN1g4qyB6iUNvddLGnpJQwPokkY5en2Wn7YDdg8n_95fgDdnwCRrfB_NuGg8cI1qoKW8cNcnDsvbjg6jTtbhaLFzEW3WXXD_8_EXYyipRA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>843412888</pqid></control><display><type>article</type><title>Novel antifouling oligo(ethylene glycol) methacrylate particles via surfactant-free emulsion polymerization</title><source>MEDLINE</source><source>ScienceDirect Journals (5 years ago - present)</source><creator>Buyukserin, Fatih ; Camli, Sevket Tolga ; Yavuz, Mustafa Selman ; Budak, Gurer Guven</creator><creatorcontrib>Buyukserin, Fatih ; Camli, Sevket Tolga ; Yavuz, Mustafa Selman ; Budak, Gurer Guven</creatorcontrib><description>Cross-linked PEGEEM colloids that display novel antifouling surface properties are introduced. A simple surfactant-free emulsion polymerization is used to prepare monodisperse cross-linked particles which were characterized by DLS and TEM.
[Display omitted]
► PEGEEM colloids with novel antifouling surface properties is reported for the first time. ► Surfactant-free emulsion polymerization was used to prepare monodisperse crosslinked particles. ► A prominent blockage of BSA adsorption was obtained for the PEG-based sub-micron colloids.
The use of particle formulations with antifouling surface properties attracts increasing interest in several biotechnological applications. Majority of these studies utilize a poly(ethylene glycol) coating to render the corresponding surface nonrecognizable to biological macromolecules. Herein, we report a simple way to prepare novel antifouling colloids composed of oligo(ethylene glycol) backbones via surfactant-free emulsion polymerization. Monodisperse cross-linked poly(ethylene glycol) ethyl ether methacrylate particles were characterized by dynamic light scattering and transmission electron microscopy. The effects of monomer, cross-linker and initiator on particle characteristics were investigated. More importantly, a prominent blockage of bovine serum albumin adsorption was obtained for the poly(ethylene glycol)-based sub-micron (∼200
nm) particles when compared with similar-sized poly(methyl methacrylate) counterparts.</description><identifier>ISSN: 0021-9797</identifier><identifier>EISSN: 1095-7103</identifier><identifier>DOI: 10.1016/j.jcis.2010.11.081</identifier><identifier>PMID: 21190697</identifier><identifier>CODEN: JCISA5</identifier><language>eng</language><publisher>Amsterdam: Elsevier Inc</publisher><subject>Adsorption ; Albumin adsorption ; Animals ; Antifouling ; Cattle ; Chemistry ; Colloidal state and disperse state ; Colloids - chemistry ; Colloids - metabolism ; Cross-linked ; Disinfectants ; Emulsions - chemistry ; Ethylene Glycol - chemistry ; Exact sciences and technology ; General and physical chemistry ; Microscopy, Electron, Transmission ; Nanoparticles - chemistry ; Nanoparticles - ultrastructure ; Particle Size ; Physical and chemical studies. Granulometry. Electrokinetic phenomena ; Poly(ethylene glycol) ethyl ether methacrylate ; Polyethylene Glycols - chemistry ; Polymerization ; Polymethyl Methacrylate - chemistry ; Polymethyl Methacrylate - metabolism ; Serum Albumin, Bovine - metabolism ; Surface physical chemistry ; Surface Properties ; Surface-Active Agents ; Surfactant-free emulsion polymerization</subject><ispartof>Journal of colloid and interface science, 2011-03, Vol.355 (1), p.76-80</ispartof><rights>2010 Elsevier Inc.</rights><rights>2015 INIST-CNRS</rights><rights>Copyright © 2010 Elsevier Inc. All rights reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c417t-df9c10381827676711bd38d65a83e2fca755a2b880267388565d54787c973dd73</citedby><cites>FETCH-LOGICAL-c417t-df9c10381827676711bd38d65a83e2fca755a2b880267388565d54787c973dd73</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jcis.2010.11.081$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=23931605$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/21190697$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Buyukserin, Fatih</creatorcontrib><creatorcontrib>Camli, Sevket Tolga</creatorcontrib><creatorcontrib>Yavuz, Mustafa Selman</creatorcontrib><creatorcontrib>Budak, Gurer Guven</creatorcontrib><title>Novel antifouling oligo(ethylene glycol) methacrylate particles via surfactant-free emulsion polymerization</title><title>Journal of colloid and interface science</title><addtitle>J Colloid Interface Sci</addtitle><description>Cross-linked PEGEEM colloids that display novel antifouling surface properties are introduced. A simple surfactant-free emulsion polymerization is used to prepare monodisperse cross-linked particles which were characterized by DLS and TEM.
[Display omitted]
► PEGEEM colloids with novel antifouling surface properties is reported for the first time. ► Surfactant-free emulsion polymerization was used to prepare monodisperse crosslinked particles. ► A prominent blockage of BSA adsorption was obtained for the PEG-based sub-micron colloids.
The use of particle formulations with antifouling surface properties attracts increasing interest in several biotechnological applications. Majority of these studies utilize a poly(ethylene glycol) coating to render the corresponding surface nonrecognizable to biological macromolecules. Herein, we report a simple way to prepare novel antifouling colloids composed of oligo(ethylene glycol) backbones via surfactant-free emulsion polymerization. Monodisperse cross-linked poly(ethylene glycol) ethyl ether methacrylate particles were characterized by dynamic light scattering and transmission electron microscopy. The effects of monomer, cross-linker and initiator on particle characteristics were investigated. More importantly, a prominent blockage of bovine serum albumin adsorption was obtained for the poly(ethylene glycol)-based sub-micron (∼200
nm) particles when compared with similar-sized poly(methyl methacrylate) counterparts.</description><subject>Adsorption</subject><subject>Albumin adsorption</subject><subject>Animals</subject><subject>Antifouling</subject><subject>Cattle</subject><subject>Chemistry</subject><subject>Colloidal state and disperse state</subject><subject>Colloids - chemistry</subject><subject>Colloids - metabolism</subject><subject>Cross-linked</subject><subject>Disinfectants</subject><subject>Emulsions - chemistry</subject><subject>Ethylene Glycol - chemistry</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Microscopy, Electron, Transmission</subject><subject>Nanoparticles - chemistry</subject><subject>Nanoparticles - ultrastructure</subject><subject>Particle Size</subject><subject>Physical and chemical studies. Granulometry. Electrokinetic phenomena</subject><subject>Poly(ethylene glycol) ethyl ether methacrylate</subject><subject>Polyethylene Glycols - chemistry</subject><subject>Polymerization</subject><subject>Polymethyl Methacrylate - chemistry</subject><subject>Polymethyl Methacrylate - metabolism</subject><subject>Serum Albumin, Bovine - metabolism</subject><subject>Surface physical chemistry</subject><subject>Surface Properties</subject><subject>Surface-Active Agents</subject><subject>Surfactant-free emulsion polymerization</subject><issn>0021-9797</issn><issn>1095-7103</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkU9v1DAQxS1ERZfCF-CAckHAIYvHWce21Auq-FOpKhc4W15nsnhx4sV2VgqfHke79Eg1h9GMfvP0NI-QV0DXQKH9sF_vrUtrRpcFrKmEJ2QFVPFaAG2ekhWlDGollLgkz1PaUwrAuXpGLhmAoq0SK_LrPhzRV2bMrg-Td-OuCt7twjvMP2ePI1Y7P9vg31dD2RgbZ28yVgcTs7MeU3V0pkpT7I3NRaTuI2KFw-STC2N1CH4eMLo_JpfxBbnojU_48tyvyI_Pn77ffK3vvn25vfl4V9sNiFx3vbLFvwTJRFsKYNs1smu5kQ2y3hrBuWFbKSlrRSMlb3nHN0IKq0TTdaK5Im9PuocYfk-Ysh5csui9GTFMSUvOBbSKssfJTbMBJqUsJDuRNoaUIvb6EN1g4qyB6iUNvddLGnpJQwPokkY5en2Wn7YDdg8n_95fgDdnwCRrfB_NuGg8cI1qoKW8cNcnDsvbjg6jTtbhaLFzEW3WXXD_8_EXYyipRA</recordid><startdate>20110301</startdate><enddate>20110301</enddate><creator>Buyukserin, Fatih</creator><creator>Camli, Sevket Tolga</creator><creator>Yavuz, Mustafa Selman</creator><creator>Budak, Gurer Guven</creator><general>Elsevier Inc</general><general>Elsevier</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7QO</scope><scope>8FD</scope><scope>FR3</scope><scope>P64</scope></search><sort><creationdate>20110301</creationdate><title>Novel antifouling oligo(ethylene glycol) methacrylate particles via surfactant-free emulsion polymerization</title><author>Buyukserin, Fatih ; Camli, Sevket Tolga ; Yavuz, Mustafa Selman ; Budak, Gurer Guven</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c417t-df9c10381827676711bd38d65a83e2fca755a2b880267388565d54787c973dd73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Adsorption</topic><topic>Albumin adsorption</topic><topic>Animals</topic><topic>Antifouling</topic><topic>Cattle</topic><topic>Chemistry</topic><topic>Colloidal state and disperse state</topic><topic>Colloids - chemistry</topic><topic>Colloids - metabolism</topic><topic>Cross-linked</topic><topic>Disinfectants</topic><topic>Emulsions - chemistry</topic><topic>Ethylene Glycol - chemistry</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Microscopy, Electron, Transmission</topic><topic>Nanoparticles - chemistry</topic><topic>Nanoparticles - ultrastructure</topic><topic>Particle Size</topic><topic>Physical and chemical studies. Granulometry. Electrokinetic phenomena</topic><topic>Poly(ethylene glycol) ethyl ether methacrylate</topic><topic>Polyethylene Glycols - chemistry</topic><topic>Polymerization</topic><topic>Polymethyl Methacrylate - chemistry</topic><topic>Polymethyl Methacrylate - metabolism</topic><topic>Serum Albumin, Bovine - metabolism</topic><topic>Surface physical chemistry</topic><topic>Surface Properties</topic><topic>Surface-Active Agents</topic><topic>Surfactant-free emulsion polymerization</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Buyukserin, Fatih</creatorcontrib><creatorcontrib>Camli, Sevket Tolga</creatorcontrib><creatorcontrib>Yavuz, Mustafa Selman</creatorcontrib><creatorcontrib>Budak, Gurer Guven</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Biotechnology Research Abstracts</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Biotechnology and BioEngineering Abstracts</collection><jtitle>Journal of colloid and interface science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Buyukserin, Fatih</au><au>Camli, Sevket Tolga</au><au>Yavuz, Mustafa Selman</au><au>Budak, Gurer Guven</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Novel antifouling oligo(ethylene glycol) methacrylate particles via surfactant-free emulsion polymerization</atitle><jtitle>Journal of colloid and interface science</jtitle><addtitle>J Colloid Interface Sci</addtitle><date>2011-03-01</date><risdate>2011</risdate><volume>355</volume><issue>1</issue><spage>76</spage><epage>80</epage><pages>76-80</pages><issn>0021-9797</issn><eissn>1095-7103</eissn><coden>JCISA5</coden><abstract>Cross-linked PEGEEM colloids that display novel antifouling surface properties are introduced. A simple surfactant-free emulsion polymerization is used to prepare monodisperse cross-linked particles which were characterized by DLS and TEM.
[Display omitted]
► PEGEEM colloids with novel antifouling surface properties is reported for the first time. ► Surfactant-free emulsion polymerization was used to prepare monodisperse crosslinked particles. ► A prominent blockage of BSA adsorption was obtained for the PEG-based sub-micron colloids.
The use of particle formulations with antifouling surface properties attracts increasing interest in several biotechnological applications. Majority of these studies utilize a poly(ethylene glycol) coating to render the corresponding surface nonrecognizable to biological macromolecules. Herein, we report a simple way to prepare novel antifouling colloids composed of oligo(ethylene glycol) backbones via surfactant-free emulsion polymerization. Monodisperse cross-linked poly(ethylene glycol) ethyl ether methacrylate particles were characterized by dynamic light scattering and transmission electron microscopy. The effects of monomer, cross-linker and initiator on particle characteristics were investigated. More importantly, a prominent blockage of bovine serum albumin adsorption was obtained for the poly(ethylene glycol)-based sub-micron (∼200
nm) particles when compared with similar-sized poly(methyl methacrylate) counterparts.</abstract><cop>Amsterdam</cop><pub>Elsevier Inc</pub><pmid>21190697</pmid><doi>10.1016/j.jcis.2010.11.081</doi><tpages>5</tpages></addata></record> |
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| ispartof | Journal of colloid and interface science, 2011-03, Vol.355 (1), p.76-80 |
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| language | eng |
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| source | MEDLINE; ScienceDirect Journals (5 years ago - present) |
| subjects | Adsorption Albumin adsorption Animals Antifouling Cattle Chemistry Colloidal state and disperse state Colloids - chemistry Colloids - metabolism Cross-linked Disinfectants Emulsions - chemistry Ethylene Glycol - chemistry Exact sciences and technology General and physical chemistry Microscopy, Electron, Transmission Nanoparticles - chemistry Nanoparticles - ultrastructure Particle Size Physical and chemical studies. Granulometry. Electrokinetic phenomena Poly(ethylene glycol) ethyl ether methacrylate Polyethylene Glycols - chemistry Polymerization Polymethyl Methacrylate - chemistry Polymethyl Methacrylate - metabolism Serum Albumin, Bovine - metabolism Surface physical chemistry Surface Properties Surface-Active Agents Surfactant-free emulsion polymerization |
| title | Novel antifouling oligo(ethylene glycol) methacrylate particles via surfactant-free emulsion polymerization |
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