In situ polymerization/intercalation of substituted anilines into iron (III) oxychloride

Aniline along with the substituted anilines, 2-methylaniline, 2-ethylaniline, 2-propylaniline, have been polymerized and intercalated into FeOCl via an in situ polymerization/intercalation process. Powder X-ray diffraction provides evidence for the intercalation of the polymers. FTIR and thermo grav...

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Veröffentlicht in:Solid state ionics 2010-07, Vol.181 (19), p.933-938
Hauptverfasser: Scully, Stephen F., Bissessur, Rabin, Dahn, Douglas C., Xie, Guanhua
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container_end_page 938
container_issue 19
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container_title Solid state ionics
container_volume 181
creator Scully, Stephen F.
Bissessur, Rabin
Dahn, Douglas C.
Xie, Guanhua
description Aniline along with the substituted anilines, 2-methylaniline, 2-ethylaniline, 2-propylaniline, have been polymerized and intercalated into FeOCl via an in situ polymerization/intercalation process. Powder X-ray diffraction provides evidence for the intercalation of the polymers. FTIR and thermo gravimetric analysis (TGA) also support the inclusion of the polyanilines between the layers of FeOCl. The electrical resistivity of the intercalation compounds was measured as a function of temperature, and is consistent, in most cases, with the variable-range hopping (Mott law) model.
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subjects Aniline
Diffraction
Electrical resistivity
FeOCl
In situ polymerization
Intercalation
Intercalation compounds
Iron
Polymerization
Polymers
Resistivity measurements
Thermal analysis
X-ray diffraction
X-rays
title In situ polymerization/intercalation of substituted anilines into iron (III) oxychloride
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