In situ polymerization/intercalation of substituted anilines into iron (III) oxychloride
Aniline along with the substituted anilines, 2-methylaniline, 2-ethylaniline, 2-propylaniline, have been polymerized and intercalated into FeOCl via an in situ polymerization/intercalation process. Powder X-ray diffraction provides evidence for the intercalation of the polymers. FTIR and thermo grav...
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Veröffentlicht in: | Solid state ionics 2010-07, Vol.181 (19), p.933-938 |
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creator | Scully, Stephen F. Bissessur, Rabin Dahn, Douglas C. Xie, Guanhua |
description | Aniline along with the substituted anilines, 2-methylaniline, 2-ethylaniline, 2-propylaniline, have been polymerized and intercalated into FeOCl via an
in situ polymerization/intercalation process. Powder X-ray diffraction provides evidence for the intercalation of the polymers. FTIR and thermo gravimetric analysis (TGA) also support the inclusion of the polyanilines between the layers of FeOCl. The electrical resistivity of the intercalation compounds was measured as a function of temperature, and is consistent, in most cases, with the variable-range hopping (Mott law) model. |
doi_str_mv | 10.1016/j.ssi.2010.05.015 |
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in situ polymerization/intercalation process. Powder X-ray diffraction provides evidence for the intercalation of the polymers. FTIR and thermo gravimetric analysis (TGA) also support the inclusion of the polyanilines between the layers of FeOCl. The electrical resistivity of the intercalation compounds was measured as a function of temperature, and is consistent, in most cases, with the variable-range hopping (Mott law) model.</description><subject>Aniline</subject><subject>Diffraction</subject><subject>Electrical resistivity</subject><subject>FeOCl</subject><subject>In situ polymerization</subject><subject>Intercalation</subject><subject>Intercalation compounds</subject><subject>Iron</subject><subject>Polymerization</subject><subject>Polymers</subject><subject>Resistivity measurements</subject><subject>Thermal analysis</subject><subject>X-ray diffraction</subject><subject>X-rays</subject><issn>0167-2738</issn><issn>1872-7689</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LxDAQQIMouK7-AG-9qYd2k7b5KJ5k8aOw4EXBW0iTKWbpNmuSiuuvN-t69jQMvDcwD6FLgguCCVusixBsUeK0Y1pgQo_QjAhe5pyJ5hjNEsPzklfiFJ2FsMYYs0qwGXprxyzYOGVbN-w24O23itaNCztG8FoNv1vm-ixMXYgJjGAyNdrBjhCyRLnM-kRct217k7mvnX4fnLcGztFJr4YAF39zjl4f7l-WT_nq-bFd3q1yXZVNzDUDAUx33DScYEM7qHFfs7pivaoUFQp3pOs116WhlAtKlOC0qXvdQWmM7qo5ujrc3Xr3MUGIcmODhmFQI7gpSJE0zHmDE0kOpPYuBA-93Hq7UX4nCZb7iHItU0S5jygxlSlicm4PDqQXPi14GbSFUYOxHnSUxtl_7B9ZYXxj</recordid><startdate>20100716</startdate><enddate>20100716</enddate><creator>Scully, Stephen F.</creator><creator>Bissessur, Rabin</creator><creator>Dahn, Douglas C.</creator><creator>Xie, Guanhua</creator><general>Elsevier B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20100716</creationdate><title>In situ polymerization/intercalation of substituted anilines into iron (III) oxychloride</title><author>Scully, Stephen F. ; Bissessur, Rabin ; Dahn, Douglas C. ; Xie, Guanhua</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c329t-c6e8e6cb7d9710d5be40f46436fa3a58a0b1bfc7c2d557851a87594fcbe2ddcb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Aniline</topic><topic>Diffraction</topic><topic>Electrical resistivity</topic><topic>FeOCl</topic><topic>In situ polymerization</topic><topic>Intercalation</topic><topic>Intercalation compounds</topic><topic>Iron</topic><topic>Polymerization</topic><topic>Polymers</topic><topic>Resistivity measurements</topic><topic>Thermal analysis</topic><topic>X-ray diffraction</topic><topic>X-rays</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Scully, Stephen F.</creatorcontrib><creatorcontrib>Bissessur, Rabin</creatorcontrib><creatorcontrib>Dahn, Douglas C.</creatorcontrib><creatorcontrib>Xie, Guanhua</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Solid state ionics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Scully, Stephen F.</au><au>Bissessur, Rabin</au><au>Dahn, Douglas C.</au><au>Xie, Guanhua</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>In situ polymerization/intercalation of substituted anilines into iron (III) oxychloride</atitle><jtitle>Solid state ionics</jtitle><date>2010-07-16</date><risdate>2010</risdate><volume>181</volume><issue>19</issue><spage>933</spage><epage>938</epage><pages>933-938</pages><issn>0167-2738</issn><eissn>1872-7689</eissn><abstract>Aniline along with the substituted anilines, 2-methylaniline, 2-ethylaniline, 2-propylaniline, have been polymerized and intercalated into FeOCl via an
in situ polymerization/intercalation process. Powder X-ray diffraction provides evidence for the intercalation of the polymers. FTIR and thermo gravimetric analysis (TGA) also support the inclusion of the polyanilines between the layers of FeOCl. The electrical resistivity of the intercalation compounds was measured as a function of temperature, and is consistent, in most cases, with the variable-range hopping (Mott law) model.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.ssi.2010.05.015</doi><tpages>6</tpages></addata></record> |
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subjects | Aniline Diffraction Electrical resistivity FeOCl In situ polymerization Intercalation Intercalation compounds Iron Polymerization Polymers Resistivity measurements Thermal analysis X-ray diffraction X-rays |
title | In situ polymerization/intercalation of substituted anilines into iron (III) oxychloride |
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