Excess molar enthalpies of ternary mixtures (1-hexene + tetrahydrofuran + 2,2-dimethylbutane or 2,3-dimethylbutane) at the temperature 298.15 K

Excess molar enthalpies, measured at the temperature 298.15 K and atmospheric pressure conditions by means of a flow microcalorimeter, are reported for the ternary mixtures x 1 C 6 H 12 + x 2 C 4 H 8 O + ( 1 - x 1 - x 2 ) { ( CH 3 ) 3 CCH 2 CH 3 or ( CH 3 ) 2 CHCH ( CH 3 ) 2 } . A smooth representat...

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Veröffentlicht in:The Journal of chemical thermodynamics 2011-03, Vol.43 (3), p.323-328
Hauptverfasser: Nazmul Hasan, S.M., Peng, Ding-Yu
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container_title The Journal of chemical thermodynamics
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creator Nazmul Hasan, S.M.
Peng, Ding-Yu
description Excess molar enthalpies, measured at the temperature 298.15 K and atmospheric pressure conditions by means of a flow microcalorimeter, are reported for the ternary mixtures x 1 C 6 H 12 + x 2 C 4 H 8 O + ( 1 - x 1 - x 2 ) { ( CH 3 ) 3 CCH 2 CH 3 or ( CH 3 ) 2 CHCH ( CH 3 ) 2 } . A smooth representation of the results is described and used to construct constant-enthalpy contours on a Roozeboom diagram. It is shown that good estimates of the excess molar enthalpies of the ternary systems can be obtained from the Liebermann–Fried model by using the physical properties of the components and the parameters determined from their binary mixtures.
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source ScienceDirect Journals (5 years ago - present)
subjects 1-Hexene
2,2-Dimethylbutane
2,3-Dimethylbutane
Atmospheric pressure
Barometric pressure
Chemical thermodynamics
Chemistry
Contours
Enthalpy
Estimates
Exact sciences and technology
Excess enthalpy
General and physical chemistry
Liebermann–Fried model
Mathematical models
Mixtures
Physical properties
Representations
Ternary mixture
Tetrahydrofuran
Thermodynamic properties
title Excess molar enthalpies of ternary mixtures (1-hexene + tetrahydrofuran + 2,2-dimethylbutane or 2,3-dimethylbutane) at the temperature 298.15 K
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