Excess molar enthalpies of ternary mixtures (1-hexene + tetrahydrofuran + 2,2-dimethylbutane or 2,3-dimethylbutane) at the temperature 298.15 K
Excess molar enthalpies, measured at the temperature 298.15 K and atmospheric pressure conditions by means of a flow microcalorimeter, are reported for the ternary mixtures x 1 C 6 H 12 + x 2 C 4 H 8 O + ( 1 - x 1 - x 2 ) { ( CH 3 ) 3 CCH 2 CH 3 or ( CH 3 ) 2 CHCH ( CH 3 ) 2 } . A smooth representat...
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Veröffentlicht in: | The Journal of chemical thermodynamics 2011-03, Vol.43 (3), p.323-328 |
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container_title | The Journal of chemical thermodynamics |
container_volume | 43 |
creator | Nazmul Hasan, S.M. Peng, Ding-Yu |
description | Excess molar enthalpies, measured at the temperature 298.15
K and atmospheric pressure conditions by means of a flow microcalorimeter, are reported for the ternary mixtures
x
1
C
6
H
12
+
x
2
C
4
H
8
O
+
(
1
-
x
1
-
x
2
)
{
(
CH
3
)
3
CCH
2
CH
3
or
(
CH
3
)
2
CHCH
(
CH
3
)
2
}
. A smooth representation of the results is described and used to construct constant-enthalpy contours on a Roozeboom diagram. It is shown that good estimates of the excess molar enthalpies of the ternary systems can be obtained from the Liebermann–Fried model by using the physical properties of the components and the parameters determined from their binary mixtures. |
doi_str_mv | 10.1016/j.jct.2010.10.002 |
format | Article |
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K and atmospheric pressure conditions by means of a flow microcalorimeter, are reported for the ternary mixtures
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C
6
H
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x
2
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4
H
8
O
+
(
1
-
x
1
-
x
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{
(
CH
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3
CCH
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CH
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(
CH
3
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2
CHCH
(
CH
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2
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. A smooth representation of the results is described and used to construct constant-enthalpy contours on a Roozeboom diagram. It is shown that good estimates of the excess molar enthalpies of the ternary systems can be obtained from the Liebermann–Fried model by using the physical properties of the components and the parameters determined from their binary mixtures.</description><identifier>ISSN: 0021-9614</identifier><identifier>EISSN: 1096-3626</identifier><identifier>DOI: 10.1016/j.jct.2010.10.002</identifier><identifier>CODEN: JCTDAF</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>1-Hexene ; 2,2-Dimethylbutane ; 2,3-Dimethylbutane ; Atmospheric pressure ; Barometric pressure ; Chemical thermodynamics ; Chemistry ; Contours ; Enthalpy ; Estimates ; Exact sciences and technology ; Excess enthalpy ; General and physical chemistry ; Liebermann–Fried model ; Mathematical models ; Mixtures ; Physical properties ; Representations ; Ternary mixture ; Tetrahydrofuran ; Thermodynamic properties</subject><ispartof>The Journal of chemical thermodynamics, 2011-03, Vol.43 (3), p.323-328</ispartof><rights>2010 Elsevier Ltd</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c359t-b47af79ffdcd36b56bbe784c69ee03f8f5a1476669c147591d63ab71af5c8e813</citedby><cites>FETCH-LOGICAL-c359t-b47af79ffdcd36b56bbe784c69ee03f8f5a1476669c147591d63ab71af5c8e813</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jct.2010.10.002$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3548,27923,27924,45994</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=23819388$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Nazmul Hasan, S.M.</creatorcontrib><creatorcontrib>Peng, Ding-Yu</creatorcontrib><title>Excess molar enthalpies of ternary mixtures (1-hexene + tetrahydrofuran + 2,2-dimethylbutane or 2,3-dimethylbutane) at the temperature 298.15 K</title><title>The Journal of chemical thermodynamics</title><description>Excess molar enthalpies, measured at the temperature 298.15
K and atmospheric pressure conditions by means of a flow microcalorimeter, are reported for the ternary mixtures
x
1
C
6
H
12
+
x
2
C
4
H
8
O
+
(
1
-
x
1
-
x
2
)
{
(
CH
3
)
3
CCH
2
CH
3
or
(
CH
3
)
2
CHCH
(
CH
3
)
2
}
. A smooth representation of the results is described and used to construct constant-enthalpy contours on a Roozeboom diagram. It is shown that good estimates of the excess molar enthalpies of the ternary systems can be obtained from the Liebermann–Fried model by using the physical properties of the components and the parameters determined from their binary mixtures.</description><subject>1-Hexene</subject><subject>2,2-Dimethylbutane</subject><subject>2,3-Dimethylbutane</subject><subject>Atmospheric pressure</subject><subject>Barometric pressure</subject><subject>Chemical thermodynamics</subject><subject>Chemistry</subject><subject>Contours</subject><subject>Enthalpy</subject><subject>Estimates</subject><subject>Exact sciences and technology</subject><subject>Excess enthalpy</subject><subject>General and physical chemistry</subject><subject>Liebermann–Fried model</subject><subject>Mathematical models</subject><subject>Mixtures</subject><subject>Physical properties</subject><subject>Representations</subject><subject>Ternary mixture</subject><subject>Tetrahydrofuran</subject><subject>Thermodynamic properties</subject><issn>0021-9614</issn><issn>1096-3626</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNp9kM1u3CAURlHVSJ0kfYDu2FRp1doFM8agrKooTaNE6qZdI4wvMiP_TABHM0-RV86dTtRFFl1dcfj4gEPIB85Kzrj8tik3LpcV-7suGavekBVnWhZCVvItWSHhhZZ8_Y6cprRhjGmh2Yo8Xe8cpETHebCRwpR7O2wDJDp7miFONu7pGHZ5icg-8aKHHUxAv-Bmjrbfd3H2S7QTkuprVXRhhNzvh3bJFmNzRCpe0c_UZpp7wIpxC9EeummlVclrendOTrwdErx_mWfkz4_r31c_i_tfN7dX3-8LJ2qdi3bdWN9o7zvXCdnWsm2hUWsnNQATXvna8nUjpdQOZ615J4VtG2597RQoLs7IxbF3G-eHBVI2Y0gOhgEfOC_JqLpuGG8aiUl-TLo4pxTBm20MI3oxnJmDe7Mx6N4c3B8QmsYzH1_abXJ28CjIhfTvYCUU10IpzF0ec4BffQwQTXIBJgddiICd3Rz-c8sz1UuZjw</recordid><startdate>20110301</startdate><enddate>20110301</enddate><creator>Nazmul Hasan, S.M.</creator><creator>Peng, Ding-Yu</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20110301</creationdate><title>Excess molar enthalpies of ternary mixtures (1-hexene + tetrahydrofuran + 2,2-dimethylbutane or 2,3-dimethylbutane) at the temperature 298.15 K</title><author>Nazmul Hasan, S.M. ; Peng, Ding-Yu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c359t-b47af79ffdcd36b56bbe784c69ee03f8f5a1476669c147591d63ab71af5c8e813</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>1-Hexene</topic><topic>2,2-Dimethylbutane</topic><topic>2,3-Dimethylbutane</topic><topic>Atmospheric pressure</topic><topic>Barometric pressure</topic><topic>Chemical thermodynamics</topic><topic>Chemistry</topic><topic>Contours</topic><topic>Enthalpy</topic><topic>Estimates</topic><topic>Exact sciences and technology</topic><topic>Excess enthalpy</topic><topic>General and physical chemistry</topic><topic>Liebermann–Fried model</topic><topic>Mathematical models</topic><topic>Mixtures</topic><topic>Physical properties</topic><topic>Representations</topic><topic>Ternary mixture</topic><topic>Tetrahydrofuran</topic><topic>Thermodynamic properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nazmul Hasan, S.M.</creatorcontrib><creatorcontrib>Peng, Ding-Yu</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>The Journal of chemical thermodynamics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nazmul Hasan, S.M.</au><au>Peng, Ding-Yu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Excess molar enthalpies of ternary mixtures (1-hexene + tetrahydrofuran + 2,2-dimethylbutane or 2,3-dimethylbutane) at the temperature 298.15 K</atitle><jtitle>The Journal of chemical thermodynamics</jtitle><date>2011-03-01</date><risdate>2011</risdate><volume>43</volume><issue>3</issue><spage>323</spage><epage>328</epage><pages>323-328</pages><issn>0021-9614</issn><eissn>1096-3626</eissn><coden>JCTDAF</coden><abstract>Excess molar enthalpies, measured at the temperature 298.15
K and atmospheric pressure conditions by means of a flow microcalorimeter, are reported for the ternary mixtures
x
1
C
6
H
12
+
x
2
C
4
H
8
O
+
(
1
-
x
1
-
x
2
)
{
(
CH
3
)
3
CCH
2
CH
3
or
(
CH
3
)
2
CHCH
(
CH
3
)
2
}
. A smooth representation of the results is described and used to construct constant-enthalpy contours on a Roozeboom diagram. It is shown that good estimates of the excess molar enthalpies of the ternary systems can be obtained from the Liebermann–Fried model by using the physical properties of the components and the parameters determined from their binary mixtures.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.jct.2010.10.002</doi><tpages>6</tpages></addata></record> |
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ispartof | The Journal of chemical thermodynamics, 2011-03, Vol.43 (3), p.323-328 |
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language | eng |
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source | ScienceDirect Journals (5 years ago - present) |
subjects | 1-Hexene 2,2-Dimethylbutane 2,3-Dimethylbutane Atmospheric pressure Barometric pressure Chemical thermodynamics Chemistry Contours Enthalpy Estimates Exact sciences and technology Excess enthalpy General and physical chemistry Liebermann–Fried model Mathematical models Mixtures Physical properties Representations Ternary mixture Tetrahydrofuran Thermodynamic properties |
title | Excess molar enthalpies of ternary mixtures (1-hexene + tetrahydrofuran + 2,2-dimethylbutane or 2,3-dimethylbutane) at the temperature 298.15 K |
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