Solution behavior of 4-arm poly( tert-butyl acrylate) star polymers

This paper reports the synthesis of 4-arm poly( tert-butyl acrylate) stars of different molar masses up to 10 6 g/mol by the “core-first” method using ATRP. All obtained stars have a monomodal and narrow molar-mass distribution (

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Veröffentlicht in:	European polymer journal 2010-12, Vol.46 (12), p.2341-2351
Hauptverfasser:	Mendrek, Barbara, Trzebicka, Barbara, Wałach, Wojciech, Dworak, Andrzej
Format:	Artikel
Sprache:	eng
Schlagworte:	Acrylates Applied sciences Branching parameters Exact sciences and technology Fluid dynamics Fluid flow Gel permeation chromatography Hydrodynamics Intrinsic viscosity Light scattering Mathematical analysis Organic polymers Physicochemistry of polymers Poly( tert-butyl acrylate) Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts Solvents Star polymers Stars ρ Ratio
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Beschreibung
Zusammenfassung:	This paper reports the synthesis of 4-arm poly( tert-butyl acrylate) stars of different molar masses up to 10 6 g/mol by the “core-first” method using ATRP. All obtained stars have a monomodal and narrow molar-mass distribution (
ISSN:	0014-3057 1873-1945
DOI:	10.1016/j.eurpolymj.2010.09.042