Ligand-controlled synthesis of vanadium(I) β-diketiminates and their catalysis in cyclotrimerization of alkynes

Three dimeric vanadium(I) β-diketiminates [V{μ-(η(6)-ArN)C(Me)CHC(Me)C(N-Ar)}](2) (Ar = 2,6-Me(2)C(6)H(3) (2), 2,6-Et(2)C(6)H(3) (3), 9-anthracenyl (4)) were prepared and isolated upon reduction of their corresponding dichloro precursors VCl(2)(Nacnac). Compounds 2-4 all show a structure with each v...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2011-03, Vol.40 (10), p.2324-2331
Hauptverfasser:	Chang, Kai-Chieh, Lu, Chia-Fu, Wang, Po-Yang, Lu, Duan-Yen, Chen, Hong-Zhang, Kuo, Ting-Shen, Tsai, Yi-Chou
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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