Effect of Sodium Chloride-induced Salinity on Phyto-availability and Speciation of Cd in Soil Solution

A greenhouse experiment with two levels of Cd (0.5 and 10 mg Cd kg-¹, in the form of CdCl₂), and five salinity levels of irrigation water (0, 8.6, 17.1, 34.2 and 68.4 mM NaCl) in triplicate was conducted to determine the effect of NaCl-induced salinity on the solubility and availability of Cd in cla...

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Veröffentlicht in:Water, air, and soil pollution air, and soil pollution, 2007-10, Vol.185 (1-4), p.43-51
Hauptverfasser: Ghallab, Ahmed, Usman, Adel Rabie Ahmed
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description A greenhouse experiment with two levels of Cd (0.5 and 10 mg Cd kg-¹, in the form of CdCl₂), and five salinity levels of irrigation water (0, 8.6, 17.1, 34.2 and 68.4 mM NaCl) in triplicate was conducted to determine the effect of NaCl-induced salinity on the solubility and availability of Cd in clay loam and sandy calcareous soils. Corn seeds (Zea mays L.) were sown in pots. Forty-five days after planting, the shoots were harvested, and their Cd concentration was determined. The post-harvest electrical conductivity (ECe), pH, and concentrations of cations and anions were determined in soil saturation paste extracts. Increasing irrigation water salinity resulted in significant increases in the total soluble Cd concentration in both studied soils. A positive correlation was found between the total soluble Cd and the chloride concentration in the soil solution.Solution speciation, calculated with MINEQL+ (a chemical equilibrium modeling system), predicted that Cd was present mainly as free Cd²⁺ ions followed by CdCl⁺ and [graphic removed] in the soils irrigated with deionized water. However, Cd species in the soil solution were significantly altered by increasing chloride concentration, with Cd-chloro complexes becoming the dominant Cd species in the soil solution. Increasing the salinity level resulted in significant decreases in the shoot dry matter and increases in the shoot Cd concentration. Shoot Cd concentration was positively correlated with both the total Cd and Cd-chloro complexes in the soil solution.
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Corn seeds (Zea mays L.) were sown in pots. Forty-five days after planting, the shoots were harvested, and their Cd concentration was determined. The post-harvest electrical conductivity (ECe), pH, and concentrations of cations and anions were determined in soil saturation paste extracts. Increasing irrigation water salinity resulted in significant increases in the total soluble Cd concentration in both studied soils. A positive correlation was found between the total soluble Cd and the chloride concentration in the soil solution.Solution speciation, calculated with MINEQL+ (a chemical equilibrium modeling system), predicted that Cd was present mainly as free Cd²⁺ ions followed by CdCl⁺ and [graphic removed] in the soils irrigated with deionized water. However, Cd species in the soil solution were significantly altered by increasing chloride concentration, with Cd-chloro complexes becoming the dominant Cd species in the soil solution. Increasing the salinity level resulted in significant decreases in the shoot dry matter and increases in the shoot Cd concentration. Shoot Cd concentration was positively correlated with both the total Cd and Cd-chloro complexes in the soil solution.</description><identifier>ISSN: 0049-6979</identifier><identifier>EISSN: 1573-2932</identifier><identifier>DOI: 10.1007/s11270-007-9424-y</identifier><identifier>CODEN: WAPLAC</identifier><language>eng</language><publisher>Dordrecht: Dordrecht : Springer Netherlands</publisher><subject>alluvial soils ; Anions ; Applied sciences ; bioaccumulation ; bioavailability ; Biological and medical sciences ; Biological and physicochemical properties of pollutants. Interaction in the soil ; cadmium ; Calcareous soils ; Cations ; chemical speciation ; Clay loam ; clay loam soils ; corn ; Dry matter ; dry matter accumulation ; Earth sciences ; Earth, ocean, space ; Electrical conductivity ; Engineering and environment geology. Geothermics ; Environmental monitoring ; Exact sciences and technology ; Fundamental and applied biological sciences. Psychology ; heavy metals ; Irrigation ; Irrigation water ; Non agrochemicals pollutants ; Phytopathology. Animal pests. Plant and forest protection ; polluted soils ; Pollution ; Pollution effects and side effects of agrochemicals on crop plants and forest trees. Other anthropogenic factors ; Pollution effects. Side effects of agrochemicals ; Pollution, environment geology ; saline water ; Salinity ; Salinity effects ; Sandy soils ; Saturated soils ; Shoots ; Sodium chloride ; Soil and sediments pollution ; soil pollution ; soil salinity ; Soil solution ; Soils ; Speciation ; Water salinity ; water solubility ; Zea mays</subject><ispartof>Water, air, and soil pollution, 2007-10, Vol.185 (1-4), p.43-51</ispartof><rights>2008 INIST-CNRS</rights><rights>Springer Science+Business Media B.V. 2007</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c486t-1ee43f79903f74244b12bdfc072bd44e399e1cca2bfea8f30f1ab053c1cfd9c53</citedby><cites>FETCH-LOGICAL-c486t-1ee43f79903f74244b12bdfc072bd44e399e1cca2bfea8f30f1ab053c1cfd9c53</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&amp;idt=19120915$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Ghallab, Ahmed</creatorcontrib><creatorcontrib>Usman, Adel Rabie Ahmed</creatorcontrib><title>Effect of Sodium Chloride-induced Salinity on Phyto-availability and Speciation of Cd in Soil Solution</title><title>Water, air, and soil pollution</title><description>A greenhouse experiment with two levels of Cd (0.5 and 10 mg Cd kg-¹, in the form of CdCl₂), and five salinity levels of irrigation water (0, 8.6, 17.1, 34.2 and 68.4 mM NaCl) in triplicate was conducted to determine the effect of NaCl-induced salinity on the solubility and availability of Cd in clay loam and sandy calcareous soils. Corn seeds (Zea mays L.) were sown in pots. Forty-five days after planting, the shoots were harvested, and their Cd concentration was determined. The post-harvest electrical conductivity (ECe), pH, and concentrations of cations and anions were determined in soil saturation paste extracts. Increasing irrigation water salinity resulted in significant increases in the total soluble Cd concentration in both studied soils. A positive correlation was found between the total soluble Cd and the chloride concentration in the soil solution.Solution speciation, calculated with MINEQL+ (a chemical equilibrium modeling system), predicted that Cd was present mainly as free Cd²⁺ ions followed by CdCl⁺ and [graphic removed] in the soils irrigated with deionized water. However, Cd species in the soil solution were significantly altered by increasing chloride concentration, with Cd-chloro complexes becoming the dominant Cd species in the soil solution. Increasing the salinity level resulted in significant decreases in the shoot dry matter and increases in the shoot Cd concentration. Shoot Cd concentration was positively correlated with both the total Cd and Cd-chloro complexes in the soil solution.</description><subject>alluvial soils</subject><subject>Anions</subject><subject>Applied sciences</subject><subject>bioaccumulation</subject><subject>bioavailability</subject><subject>Biological and medical sciences</subject><subject>Biological and physicochemical properties of pollutants. Interaction in the soil</subject><subject>cadmium</subject><subject>Calcareous soils</subject><subject>Cations</subject><subject>chemical speciation</subject><subject>Clay loam</subject><subject>clay loam soils</subject><subject>corn</subject><subject>Dry matter</subject><subject>dry matter accumulation</subject><subject>Earth sciences</subject><subject>Earth, ocean, space</subject><subject>Electrical conductivity</subject><subject>Engineering and environment geology. Geothermics</subject><subject>Environmental monitoring</subject><subject>Exact sciences and technology</subject><subject>Fundamental and applied biological sciences. Psychology</subject><subject>heavy metals</subject><subject>Irrigation</subject><subject>Irrigation water</subject><subject>Non agrochemicals pollutants</subject><subject>Phytopathology. Animal pests. 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Corn seeds (Zea mays L.) were sown in pots. Forty-five days after planting, the shoots were harvested, and their Cd concentration was determined. The post-harvest electrical conductivity (ECe), pH, and concentrations of cations and anions were determined in soil saturation paste extracts. Increasing irrigation water salinity resulted in significant increases in the total soluble Cd concentration in both studied soils. A positive correlation was found between the total soluble Cd and the chloride concentration in the soil solution.Solution speciation, calculated with MINEQL+ (a chemical equilibrium modeling system), predicted that Cd was present mainly as free Cd²⁺ ions followed by CdCl⁺ and [graphic removed] in the soils irrigated with deionized water. However, Cd species in the soil solution were significantly altered by increasing chloride concentration, with Cd-chloro complexes becoming the dominant Cd species in the soil solution. Increasing the salinity level resulted in significant decreases in the shoot dry matter and increases in the shoot Cd concentration. Shoot Cd concentration was positively correlated with both the total Cd and Cd-chloro complexes in the soil solution.</abstract><cop>Dordrecht</cop><pub>Dordrecht : Springer Netherlands</pub><doi>10.1007/s11270-007-9424-y</doi><tpages>9</tpages></addata></record>
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subjects alluvial soils
Anions
Applied sciences
bioaccumulation
bioavailability
Biological and medical sciences
Biological and physicochemical properties of pollutants. Interaction in the soil
cadmium
Calcareous soils
Cations
chemical speciation
Clay loam
clay loam soils
corn
Dry matter
dry matter accumulation
Earth sciences
Earth, ocean, space
Electrical conductivity
Engineering and environment geology. Geothermics
Environmental monitoring
Exact sciences and technology
Fundamental and applied biological sciences. Psychology
heavy metals
Irrigation
Irrigation water
Non agrochemicals pollutants
Phytopathology. Animal pests. Plant and forest protection
polluted soils
Pollution
Pollution effects and side effects of agrochemicals on crop plants and forest trees. Other anthropogenic factors
Pollution effects. Side effects of agrochemicals
Pollution, environment geology
saline water
Salinity
Salinity effects
Sandy soils
Saturated soils
Shoots
Sodium chloride
Soil and sediments pollution
soil pollution
soil salinity
Soil solution
Soils
Speciation
Water salinity
water solubility
Zea mays
title Effect of Sodium Chloride-induced Salinity on Phyto-availability and Speciation of Cd in Soil Solution
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