Aggregation of [Au(CN)4]− Anions: Examination by Crystallography and 15N CP-MAS NMR and the Structural Factors Influencing Intermolecular Au···N Interactions

To investigate the factors influencing the formation of intermolecular Au···NC interactions between [Au(CN)4]− units, a series of [cation] n+[Au(CN)4] n double salts was synthesized, structurally characterized and probed by IR and 15N{1H} CP-MAS NMR spectroscopy. Thus, [ n Bu4N][Au(CN)4], [AsPh4][Au...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Inorganic chemistry 2011-02, Vol.50 (4), p.1265-1274
Hauptverfasser:	Geisheimer, Andrew R, Wren, John E. C, Michaelis, Vladimir K, Kobayashi, Masayuki, Sakai, Ken, Kroeker, Scott, Leznoff, Daniel B
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!