catena-Poly[bis[1-chloromethyl-1,4-diazoniabicyclo[2.2.2]octane] [cadmium(II)-tri-μ-chlorido-[chloridocadmium(II)]-di-μ-chlorido-[chloridocadmium(II)]-tri-μ-chlorido] tetrahydrate]
The title compound, {(C7H15N2Cl)2[Cd3Cl10]·4H2O}n, consists of 1‐chloromethyl‐1,4‐diazoniabicyclo[2.2.2]octane dications, one‐dimensional inorganic chains of {[Cd3Cl10]4−} anions and uncoordinated water molecules. Each of the two independent CdII ions, one with site symmetry 2/m and the other with s...
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| Veröffentlicht in: | Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2010-11, Vol.66 (11), p.m348-m350 |
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| container_issue | 11 |
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| container_title | Acta crystallographica. Section C, Crystal structure communications |
| container_volume | 66 |
| creator | Xiao, Jing-Mei |
| description | The title compound, {(C7H15N2Cl)2[Cd3Cl10]·4H2O}n, consists of 1‐chloromethyl‐1,4‐diazoniabicyclo[2.2.2]octane dications, one‐dimensional inorganic chains of {[Cd3Cl10]4−} anions and uncoordinated water molecules. Each of the two independent CdII ions, one with site symmetry 2/m and the other with site symmetry m, is octahedrally coordinated by chloride ions (two with site symmetry m and one with site symmetry 2), giving rise to novel polymeric zigzag chains of corner‐sharing Cd‐centred octahedra parallel to the c axis. The organic cations, bisected by mirror planes that contain the two N atoms, three methylene C atoms and the Cl atom, are ordered. Hydrogen bonds (O—H...Cl and O—H...O) between the water molecules (both with O atoms in a mirror plane) and the chloride anions of neighbouring chloridocadmate chains form a three‐dimensional supramolecular network. |
| doi_str_mv | 10.1107/S0108270110040813 |
| format | Article |
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Each of the two independent CdII ions, one with site symmetry 2/m and the other with site symmetry m, is octahedrally coordinated by chloride ions (two with site symmetry m and one with site symmetry 2), giving rise to novel polymeric zigzag chains of corner‐sharing Cd‐centred octahedra parallel to the c axis. The organic cations, bisected by mirror planes that contain the two N atoms, three methylene C atoms and the Cl atom, are ordered. Hydrogen bonds (O—H...Cl and O—H...O) between the water molecules (both with O atoms in a mirror plane) and the chloride anions of neighbouring chloridocadmate chains form a three‐dimensional supramolecular network.</description><identifier>ISSN: 0108-2701</identifier><identifier>EISSN: 1600-5759</identifier><identifier>DOI: 10.1107/S0108270110040813</identifier><identifier>PMID: 21051814</identifier><language>eng</language><publisher>5 Abbey Square, Chester, Cheshire CH1 2HU, England: International Union of Crystallography</publisher><subject>Anions ; Chloride ions ; Chlorides ; Crystal structure ; Hydrogen bonds ; Neighbouring ; Planes ; Symmetry</subject><ispartof>Acta crystallographica. 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Section C, Crystal structure communications</title><addtitle>Acta Cryst. C</addtitle><description>The title compound, {(C7H15N2Cl)2[Cd3Cl10]·4H2O}n, consists of 1‐chloromethyl‐1,4‐diazoniabicyclo[2.2.2]octane dications, one‐dimensional inorganic chains of {[Cd3Cl10]4−} anions and uncoordinated water molecules. Each of the two independent CdII ions, one with site symmetry 2/m and the other with site symmetry m, is octahedrally coordinated by chloride ions (two with site symmetry m and one with site symmetry 2), giving rise to novel polymeric zigzag chains of corner‐sharing Cd‐centred octahedra parallel to the c axis. The organic cations, bisected by mirror planes that contain the two N atoms, three methylene C atoms and the Cl atom, are ordered. Hydrogen bonds (O—H...Cl and O—H...O) between the water molecules (both with O atoms in a mirror plane) and the chloride anions of neighbouring chloridocadmate chains form a three‐dimensional supramolecular network.</description><subject>Anions</subject><subject>Chloride ions</subject><subject>Chlorides</subject><subject>Crystal structure</subject><subject>Hydrogen bonds</subject><subject>Neighbouring</subject><subject>Planes</subject><subject>Symmetry</subject><issn>0108-2701</issn><issn>1600-5759</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNqNkt9uFCEUh4nR2LX6AN6Y3lkTqRxgBuayWW3dZOOfVK06mRCGYbLUmaXCbHR8MW98Bp9JNtM2RhNruAByvt8XDoDQfSAHAEQ8OSFAJBUkbQgnEtgNNIOcEJyJrLiJZtsy3tZ30J0YzwghlFJ2G-1QIBlI4DP03ejBrjV-5buxrF0sAZtV54Pv7bAaOwyPOW6c_ubXTtfOjKbzJT1Io_Jm0Gtb7ZVGN73b9PuLxSM8BId__pgUrvG4vFz9BlVJ-B_QH6pqb7BD0KuxCenE1V10q9VdtPcu5l309ujZm_lzvHx5vJgfLrFhkua4hswUWrY1y6zVmvEiXQIRvG0by-uWQ1tYkmWkAGCsMFqy3DacsMIyLYHWbBc9nLznwX_e2Dio3kVjuy717jdRSV5wmQuSX0uKnOYikSyR-_8kIaFAQTCaUJhQE3yMwbbqPLheh1EBUds_oP76Aynz4EK_qXvbXCUuHz0BcgK-uM6O1xvV4Yf5yWtG822TeIq6ONivV1EdPqlcMJGp0xfH6t2SPT06XX5U79kvur7O0A</recordid><startdate>201011</startdate><enddate>201011</enddate><creator>Xiao, Jing-Mei</creator><general>International Union of Crystallography</general><scope>BSCLL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope></search><sort><creationdate>201011</creationdate><title>catena-Poly[bis[1-chloromethyl-1,4-diazoniabicyclo[2.2.2]octane] [cadmium(II)-tri-μ-chlorido-[chloridocadmium(II)]-di-μ-chlorido-[chloridocadmium(II)]-tri-μ-chlorido] tetrahydrate]</title><author>Xiao, Jing-Mei</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3826-b15c9a8fb35eeaa349000074ffde4bf41f9e0550911339ca836ed4039e3a812b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Anions</topic><topic>Chloride ions</topic><topic>Chlorides</topic><topic>Crystal structure</topic><topic>Hydrogen bonds</topic><topic>Neighbouring</topic><topic>Planes</topic><topic>Symmetry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xiao, Jing-Mei</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Acta crystallographica. Section C, Crystal structure communications</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xiao, Jing-Mei</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>catena-Poly[bis[1-chloromethyl-1,4-diazoniabicyclo[2.2.2]octane] [cadmium(II)-tri-μ-chlorido-[chloridocadmium(II)]-di-μ-chlorido-[chloridocadmium(II)]-tri-μ-chlorido] tetrahydrate]</atitle><jtitle>Acta crystallographica. Section C, Crystal structure communications</jtitle><addtitle>Acta Cryst. C</addtitle><date>2010-11</date><risdate>2010</risdate><volume>66</volume><issue>11</issue><spage>m348</spage><epage>m350</epage><pages>m348-m350</pages><issn>0108-2701</issn><eissn>1600-5759</eissn><abstract>The title compound, {(C7H15N2Cl)2[Cd3Cl10]·4H2O}n, consists of 1‐chloromethyl‐1,4‐diazoniabicyclo[2.2.2]octane dications, one‐dimensional inorganic chains of {[Cd3Cl10]4−} anions and uncoordinated water molecules. Each of the two independent CdII ions, one with site symmetry 2/m and the other with site symmetry m, is octahedrally coordinated by chloride ions (two with site symmetry m and one with site symmetry 2), giving rise to novel polymeric zigzag chains of corner‐sharing Cd‐centred octahedra parallel to the c axis. The organic cations, bisected by mirror planes that contain the two N atoms, three methylene C atoms and the Cl atom, are ordered. Hydrogen bonds (O—H...Cl and O—H...O) between the water molecules (both with O atoms in a mirror plane) and the chloride anions of neighbouring chloridocadmate chains form a three‐dimensional supramolecular network.</abstract><cop>5 Abbey Square, Chester, Cheshire CH1 2HU, England</cop><pub>International Union of Crystallography</pub><pmid>21051814</pmid><doi>10.1107/S0108270110040813</doi></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0108-2701 |
| ispartof | Acta crystallographica. Section C, Crystal structure communications, 2010-11, Vol.66 (11), p.m348-m350 |
| issn | 0108-2701 1600-5759 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_849486706 |
| source | Wiley Journals; Alma/SFX Local Collection |
| subjects | Anions Chloride ions Chlorides Crystal structure Hydrogen bonds Neighbouring Planes Symmetry |
| title | catena-Poly[bis[1-chloromethyl-1,4-diazoniabicyclo[2.2.2]octane] [cadmium(II)-tri-μ-chlorido-[chloridocadmium(II)]-di-μ-chlorido-[chloridocadmium(II)]-tri-μ-chlorido] tetrahydrate] |
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