Effect of zwitterionic salt on the electrochemical properties of a solid polymer electrolyte with high temperature stability for lithium ion batteries
In this study, we prepare a kind of solid polymer electrolyte (SPE) based on N-ethyl- N′-methyl imidazolium tetrafluoroborate (EMIBF 4), LiBF 4 and poly(vinylidene difluoride-co-hexafluoropropylene) [P(VdF-HFP)] copolymer. The resultant SPE displays high thermal stability above 300 °C and high room...
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| Veröffentlicht in: | Electrochimica acta 2010-12, Vol.56 (2), p.804-809 |
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| container_title | Electrochimica acta |
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| creator | Li, Z.H. Xia, Q.L. Liu, L.L. Lei, G.T. Xiao, Q.Z. Gao, D.S. Zhou, X.D. |
| description | In this study, we prepare a kind of solid polymer electrolyte (SPE) based on
N-ethyl-
N′-methyl imidazolium tetrafluoroborate (EMIBF
4), LiBF
4 and poly(vinylidene difluoride-co-hexafluoropropylene) [P(VdF-HFP)] copolymer. The resultant SPE displays high thermal stability above 300
°C and high room temperature ionic conductivity near to 10
−3
S
cm
−1. Its electrochemical properties are improved with incorporation of a zwitterionic salt 1-(1-methyl-3-imidazolium)propane-3-sulfonate (MIm3S). When the SPE contains 1.0
wt% of the MIm3S, it has a high ionic conductivity of 1.57
×
10
−3
S
cm
−1 at room temperature, the maximum lithium ions transference number of 0.36 and the minimum apparent activation energy for ions transportation of 30.9
kJ
mol
−1. The charge–discharge performance of a Li
4Ti
5O
12/SPE/LiCoO
2 cell indicates the potential application of the as-prepared SPE in lithium ion batteries. |
| doi_str_mv | 10.1016/j.electacta.2010.09.068 |
| format | Article |
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N-ethyl-
N′-methyl imidazolium tetrafluoroborate (EMIBF
4), LiBF
4 and poly(vinylidene difluoride-co-hexafluoropropylene) [P(VdF-HFP)] copolymer. The resultant SPE displays high thermal stability above 300
°C and high room temperature ionic conductivity near to 10
−3
S
cm
−1. Its electrochemical properties are improved with incorporation of a zwitterionic salt 1-(1-methyl-3-imidazolium)propane-3-sulfonate (MIm3S). When the SPE contains 1.0
wt% of the MIm3S, it has a high ionic conductivity of 1.57
×
10
−3
S
cm
−1 at room temperature, the maximum lithium ions transference number of 0.36 and the minimum apparent activation energy for ions transportation of 30.9
kJ
mol
−1. The charge–discharge performance of a Li
4Ti
5O
12/SPE/LiCoO
2 cell indicates the potential application of the as-prepared SPE in lithium ion batteries.</description><identifier>ISSN: 0013-4686</identifier><identifier>EISSN: 1873-3859</identifier><identifier>DOI: 10.1016/j.electacta.2010.09.068</identifier><identifier>CODEN: ELCAAV</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Applied sciences ; Copolymers ; Direct energy conversion and energy accumulation ; Displays ; Electrical engineering. Electrical power engineering ; Electrical power engineering ; Electrochemical conversion: primary and secondary batteries, fuel cells ; Electrolytes ; Electrolytic cells ; Exact sciences and technology ; Ionic conductivity ; Ionic liquid ; Lithium ion batteries ; Lithium ions ; Polymer electrolyte ; Transportation ; Zwitterionic salt</subject><ispartof>Electrochimica acta, 2010-12, Vol.56 (2), p.804-809</ispartof><rights>2010 Elsevier Ltd</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c377t-4fa8ad66a937c02b19af76dc6a1bc0e932eae4a5655baddc0875736d901325dc3</citedby><cites>FETCH-LOGICAL-c377t-4fa8ad66a937c02b19af76dc6a1bc0e932eae4a5655baddc0875736d901325dc3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.electacta.2010.09.068$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=23451669$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Li, Z.H.</creatorcontrib><creatorcontrib>Xia, Q.L.</creatorcontrib><creatorcontrib>Liu, L.L.</creatorcontrib><creatorcontrib>Lei, G.T.</creatorcontrib><creatorcontrib>Xiao, Q.Z.</creatorcontrib><creatorcontrib>Gao, D.S.</creatorcontrib><creatorcontrib>Zhou, X.D.</creatorcontrib><title>Effect of zwitterionic salt on the electrochemical properties of a solid polymer electrolyte with high temperature stability for lithium ion batteries</title><title>Electrochimica acta</title><description>In this study, we prepare a kind of solid polymer electrolyte (SPE) based on
N-ethyl-
N′-methyl imidazolium tetrafluoroborate (EMIBF
4), LiBF
4 and poly(vinylidene difluoride-co-hexafluoropropylene) [P(VdF-HFP)] copolymer. The resultant SPE displays high thermal stability above 300
°C and high room temperature ionic conductivity near to 10
−3
S
cm
−1. Its electrochemical properties are improved with incorporation of a zwitterionic salt 1-(1-methyl-3-imidazolium)propane-3-sulfonate (MIm3S). When the SPE contains 1.0
wt% of the MIm3S, it has a high ionic conductivity of 1.57
×
10
−3
S
cm
−1 at room temperature, the maximum lithium ions transference number of 0.36 and the minimum apparent activation energy for ions transportation of 30.9
kJ
mol
−1. The charge–discharge performance of a Li
4Ti
5O
12/SPE/LiCoO
2 cell indicates the potential application of the as-prepared SPE in lithium ion batteries.</description><subject>Applied sciences</subject><subject>Copolymers</subject><subject>Direct energy conversion and energy accumulation</subject><subject>Displays</subject><subject>Electrical engineering. Electrical power engineering</subject><subject>Electrical power engineering</subject><subject>Electrochemical conversion: primary and secondary batteries, fuel cells</subject><subject>Electrolytes</subject><subject>Electrolytic cells</subject><subject>Exact sciences and technology</subject><subject>Ionic conductivity</subject><subject>Ionic liquid</subject><subject>Lithium ion batteries</subject><subject>Lithium ions</subject><subject>Polymer electrolyte</subject><subject>Transportation</subject><subject>Zwitterionic salt</subject><issn>0013-4686</issn><issn>1873-3859</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNqFUc1u1DAQthBILC3PUF8Qpyx2nNjxsapKQarEBc7WxJ40XjnxYntBy4PwvPV2S69II3k0-n488xFyxdmWMy4_7bYY0BaotW1ZnTK9ZXJ4RTZ8UKIRQ69fkw1jXDSdHORb8i7nHWNMScU25O_tNFU2jRP989uXgsnH1VuaIdThSsuM9Ek_RTvj4i0Euk9xj6l4zCca0ByDd3Qfw3HB9A8djgVpVZzp7B9mWnCpHCiHhDQXGH3w5UinmGhtZn9YaPWlIzz9APMleTNByPj--b0gPz7ffr_50tx_u_t6c33fWKFUaboJBnBSghbKsnbkGiYlnZXAR8tQixYBO-hl34_gnGWD6pWQTtdrtL2z4oJ8POvWnX4eMBez-GwxBFgxHrIZOt0NvJWiItUZaVPMOeFk9skvkI6GM3MKwuzMSxDmFIRh2tQgKvPDswfker4pwWp9fqG3ouu5lLrirs84rAv_8phMth5Xi86nqmtc9P_1egSOTafr</recordid><startdate>20101230</startdate><enddate>20101230</enddate><creator>Li, Z.H.</creator><creator>Xia, Q.L.</creator><creator>Liu, L.L.</creator><creator>Lei, G.T.</creator><creator>Xiao, Q.Z.</creator><creator>Gao, D.S.</creator><creator>Zhou, X.D.</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20101230</creationdate><title>Effect of zwitterionic salt on the electrochemical properties of a solid polymer electrolyte with high temperature stability for lithium ion batteries</title><author>Li, Z.H. ; Xia, Q.L. ; Liu, L.L. ; Lei, G.T. ; Xiao, Q.Z. ; Gao, D.S. ; Zhou, X.D.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c377t-4fa8ad66a937c02b19af76dc6a1bc0e932eae4a5655baddc0875736d901325dc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Applied sciences</topic><topic>Copolymers</topic><topic>Direct energy conversion and energy accumulation</topic><topic>Displays</topic><topic>Electrical engineering. Electrical power engineering</topic><topic>Electrical power engineering</topic><topic>Electrochemical conversion: primary and secondary batteries, fuel cells</topic><topic>Electrolytes</topic><topic>Electrolytic cells</topic><topic>Exact sciences and technology</topic><topic>Ionic conductivity</topic><topic>Ionic liquid</topic><topic>Lithium ion batteries</topic><topic>Lithium ions</topic><topic>Polymer electrolyte</topic><topic>Transportation</topic><topic>Zwitterionic salt</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Z.H.</creatorcontrib><creatorcontrib>Xia, Q.L.</creatorcontrib><creatorcontrib>Liu, L.L.</creatorcontrib><creatorcontrib>Lei, G.T.</creatorcontrib><creatorcontrib>Xiao, Q.Z.</creatorcontrib><creatorcontrib>Gao, D.S.</creatorcontrib><creatorcontrib>Zhou, X.D.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Electrochimica acta</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Z.H.</au><au>Xia, Q.L.</au><au>Liu, L.L.</au><au>Lei, G.T.</au><au>Xiao, Q.Z.</au><au>Gao, D.S.</au><au>Zhou, X.D.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of zwitterionic salt on the electrochemical properties of a solid polymer electrolyte with high temperature stability for lithium ion batteries</atitle><jtitle>Electrochimica acta</jtitle><date>2010-12-30</date><risdate>2010</risdate><volume>56</volume><issue>2</issue><spage>804</spage><epage>809</epage><pages>804-809</pages><issn>0013-4686</issn><eissn>1873-3859</eissn><coden>ELCAAV</coden><abstract>In this study, we prepare a kind of solid polymer electrolyte (SPE) based on
N-ethyl-
N′-methyl imidazolium tetrafluoroborate (EMIBF
4), LiBF
4 and poly(vinylidene difluoride-co-hexafluoropropylene) [P(VdF-HFP)] copolymer. The resultant SPE displays high thermal stability above 300
°C and high room temperature ionic conductivity near to 10
−3
S
cm
−1. Its electrochemical properties are improved with incorporation of a zwitterionic salt 1-(1-methyl-3-imidazolium)propane-3-sulfonate (MIm3S). When the SPE contains 1.0
wt% of the MIm3S, it has a high ionic conductivity of 1.57
×
10
−3
S
cm
−1 at room temperature, the maximum lithium ions transference number of 0.36 and the minimum apparent activation energy for ions transportation of 30.9
kJ
mol
−1. The charge–discharge performance of a Li
4Ti
5O
12/SPE/LiCoO
2 cell indicates the potential application of the as-prepared SPE in lithium ion batteries.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.electacta.2010.09.068</doi><tpages>6</tpages></addata></record> |
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| ispartof | Electrochimica acta, 2010-12, Vol.56 (2), p.804-809 |
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| subjects | Applied sciences Copolymers Direct energy conversion and energy accumulation Displays Electrical engineering. Electrical power engineering Electrical power engineering Electrochemical conversion: primary and secondary batteries, fuel cells Electrolytes Electrolytic cells Exact sciences and technology Ionic conductivity Ionic liquid Lithium ion batteries Lithium ions Polymer electrolyte Transportation Zwitterionic salt |
| title | Effect of zwitterionic salt on the electrochemical properties of a solid polymer electrolyte with high temperature stability for lithium ion batteries |
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