The synthesis of modified polyethylene via coordination polymerization followed by ATRP, RAFT, NMRP or ROP
Research on the synthesis of modified polyethylene (PE) is of great significance to both academic study and industrial applications. The synthesis of modified polyethylene has experienced remarkable and significant progress in the control over the microstructure, composition, molecular weight and mo...
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| Veröffentlicht in: | Progress in polymer science 2010-10, Vol.35 (10), p.1195-1216 |
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| creator | Zhao, Yulai Wang, Li Xiao, Anguo Yu, Haojie |
| description | Research on the synthesis of modified polyethylene (PE) is of great significance to both academic study and industrial applications. The synthesis of modified polyethylene has experienced remarkable and significant progress in the control over the microstructure, composition, molecular weight and molecular weight distribution of the polymeric products. This review summarizes the achievements in the synthesis of modified polyethylene via combining coordination polymerization with atom transfer radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT) polymerization, nitroxide-mediated radical polymerization (NMRP) or ring-opening polymerization (ROP) for the last decade. In addition, the mechanisms of the aforementioned polymerization techniques are expounded in this contribution. |
| doi_str_mv | 10.1016/j.progpolymsci.2010.05.002 |
| format | Article |
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The synthesis of modified polyethylene has experienced remarkable and significant progress in the control over the microstructure, composition, molecular weight and molecular weight distribution of the polymeric products. This review summarizes the achievements in the synthesis of modified polyethylene via combining coordination polymerization with atom transfer radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT) polymerization, nitroxide-mediated radical polymerization (NMRP) or ring-opening polymerization (ROP) for the last decade. 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In addition, the mechanisms of the aforementioned polymerization techniques are expounded in this contribution.</description><subject>Applied sciences</subject><subject>ATRP</subject><subject>Chain transfer</subject><subject>Copolymerization</subject><subject>Exact sciences and technology</subject><subject>Microstructure</subject><subject>Modified polyethylene</subject><subject>Molecular weight</subject><subject>Molecular weight distribution</subject><subject>NMRP</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polyethylenes</subject><subject>Polymerization</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>Radicals</subject><subject>RAFT</subject><subject>Rafts</subject><subject>ROP</subject><subject>Synthesis</subject><issn>0079-6700</issn><issn>1873-1619</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNqNkE1r3DAQhkVJoZuP_yAKJZd4O7Ity8ptSZq2kDTLsjkLWRp3tdjWVnJSnF8fbTeEHnMahnk_mIeQzwzmDFj1dTvfBf9757upj8bNc0gH4HOA_AOZsVoUGauYPCIzACGzSgB8IscxbgGYYFzMyHa9QRqnYdxgdJH6lvbeutahpftUHDdThwPSJ6ep8T5YN-jR-eHftcfgng9r67vO_02uZqKL9Wp5QVeLm_UF_XW3WlIf6Op-eUo-trqLePY6T8jDzbf11Y_s9v77z6vFbWbKWo5ZjY3lQkheCdvWoDm3HOvG5sJymUtscsNZYVGKquLQGt7YqtRgc8PQYqOLE3J-yE1o_jxiHFXvosGu0wP6x6jqUpairAuelJcHpQk-xoCt2gXX6zApBmrPV23V_3zVnq8CrhLfZP7yWqOj0V0b9GBcfEvIi4IzWbCkuz7oMP385DColISDQesCmlFZ795T9wIDt5l9</recordid><startdate>20101001</startdate><enddate>20101001</enddate><creator>Zhao, Yulai</creator><creator>Wang, Li</creator><creator>Xiao, Anguo</creator><creator>Yu, Haojie</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20101001</creationdate><title>The synthesis of modified polyethylene via coordination polymerization followed by ATRP, RAFT, NMRP or ROP</title><author>Zhao, Yulai ; Wang, Li ; Xiao, Anguo ; Yu, Haojie</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c489t-8ebd5779567df80a55d5e8bd27d5929eb2c513de976650fc5bd64a0d2c1edeba3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Applied sciences</topic><topic>ATRP</topic><topic>Chain transfer</topic><topic>Copolymerization</topic><topic>Exact sciences and technology</topic><topic>Microstructure</topic><topic>Modified polyethylene</topic><topic>Molecular weight</topic><topic>Molecular weight distribution</topic><topic>NMRP</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polyethylenes</topic><topic>Polymerization</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>Radicals</topic><topic>RAFT</topic><topic>Rafts</topic><topic>ROP</topic><topic>Synthesis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhao, Yulai</creatorcontrib><creatorcontrib>Wang, Li</creatorcontrib><creatorcontrib>Xiao, Anguo</creatorcontrib><creatorcontrib>Yu, Haojie</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Progress in polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhao, Yulai</au><au>Wang, Li</au><au>Xiao, Anguo</au><au>Yu, Haojie</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The synthesis of modified polyethylene via coordination polymerization followed by ATRP, RAFT, NMRP or ROP</atitle><jtitle>Progress in polymer science</jtitle><date>2010-10-01</date><risdate>2010</risdate><volume>35</volume><issue>10</issue><spage>1195</spage><epage>1216</epage><pages>1195-1216</pages><issn>0079-6700</issn><eissn>1873-1619</eissn><coden>PRPSB8</coden><abstract>Research on the synthesis of modified polyethylene (PE) is of great significance to both academic study and industrial applications. 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| ispartof | Progress in polymer science, 2010-10, Vol.35 (10), p.1195-1216 |
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| source | Elsevier ScienceDirect Journals Complete |
| subjects | Applied sciences ATRP Chain transfer Copolymerization Exact sciences and technology Microstructure Modified polyethylene Molecular weight Molecular weight distribution NMRP Organic polymers Physicochemistry of polymers Polyethylenes Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts Radicals RAFT Rafts ROP Synthesis |
| title | The synthesis of modified polyethylene via coordination polymerization followed by ATRP, RAFT, NMRP or ROP |
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