A novel fast response fiber-optic pH sensor based on nanoporous self-assembled multilayer films

Three-component multilayer films were prepared by consecutively depositing a polycation blend of poly(4-vinylpyridiniomethanecarboxylate) (PVPMC) and poly(diallyldimethylammonium) (PDDA) with poly(acrylic acid) (PAA). The self-assembly and disintegration behavior of the multilayer films were investi...

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Veröffentlicht in:Journal of materials chemistry 2010-09, Vol.20 (36), p.7754-7760
Hauptverfasser: Gui, Zhangliang, Qian, Jinwen, Yin, Mingjie, An, Quanfu, Gu, Bobo, Zhang, Aping
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container_end_page 7760
container_issue 36
container_start_page 7754
container_title Journal of materials chemistry
container_volume 20
creator Gui, Zhangliang
Qian, Jinwen
Yin, Mingjie
An, Quanfu
Gu, Bobo
Zhang, Aping
description Three-component multilayer films were prepared by consecutively depositing a polycation blend of poly(4-vinylpyridiniomethanecarboxylate) (PVPMC) and poly(diallyldimethylammonium) (PDDA) with poly(acrylic acid) (PAA). The self-assembly and disintegration behavior of the multilayer films were investigated in details by UV-vis absorption spectroscopy, quartz crystal microbalance (QCM) and atomic force microscopy (AFM). It was found that nanoporous PDDA/PAA multilayer films can be obtained conveniently by partly disintegrating (PVPMC + PDDA)/PAA multilayer films in a 0.15 M NaCl solution. A novel fast response fiber-optic pH sensor was successfully prepared by constructing nanoporous self-assembly multilayer films on the thin-core fiber interferometer (TCFMI) surface. The response time of a fiber-optic pH sensor deposited with nanoporous PDDA/PAA multilayer film (20 s rise time (t sub(r)) and 15 s fall time (t sub(f))) was only one-tenth of that with the nonporous PDDA/PAA multilayer film (240 s and 160 s for t sub(r) and t sub(f)).
doi_str_mv 10.1039/c0jm01476a
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Fiber optics
Microorganisms
Multilayers
Nanocomposites
Nanomaterials
Nanostructure
Optical fibers
Self assembly
title A novel fast response fiber-optic pH sensor based on nanoporous self-assembled multilayer films
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