Synthesis of [5]Rotaxanes Containing Bi- and Tridentate Coordination Sites in the Axis

A new example of a linear [5]rotaxane has been synthesized by using the traditional “gathering‐and‐threading” approach but based on an unusual axle incorporating a symmetrical bis(bidentate) chelating fragment built on a 4,7‐phenanthroline core. The stoppering reaction is particularly noteworthy sin...

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Veröffentlicht in:	Chemistry : a European journal 2011-01, Vol.17 (3), p.947-957
Hauptverfasser:	Collin, Jean-Paul, Durot, Stéphanie, Keller, Michel, Sauvage, Jean-Pierre, Trolez, Yann, Cetina, Mario, Rissanen, Kari
Format:	Artikel
Sprache:	eng
Schlagworte:	Axles Blocking Chelating Chemistry click chemistry copper Diffraction Fragmentation Ligands lithium Precursors rotaxanes X-rays zinc
Online-Zugang:	Volltext
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