l-Phenylalanine ammonia-lyase (maize, potato, and Rhodotorula glutinis) : Explaining the kinetic effects of substrate modification by linear free-energy relationships

The action of phenylalanine ammonia-lyase [EC 4.3.1.5] on a series of para-substituted l-phenylalanines has been investigated. Multiple linear regression analysis has been used to relate the logs of k cat, K m , and k cat K m to substituent parameters for electron withdrawal, hydrophobic bonding, an...

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Veröffentlicht in:	Archives of biochemistry and biophysics 1977-04, Vol.180 (1), p.102-113
Hauptverfasser:	Hanson, Kenneth R., Havir, Evelyn A.
Format:	Artikel
Sprache:	eng
Schlagworte:	Ammonia-Lyases - metabolism corn Kinetics Mitosporic Fungi - enzymology Models, Chemical Phenylalanine - pharmacology Phenylalanine Ammonia-Lyase - metabolism Plants - enzymology potatoes Rhodotorula - enzymology Rhodotorula glutinis Stereoisomerism Thermodynamics yeasts Zea mays - enzymology
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