The effect of ortho substitution on the mass spectral fragmentation of polychlorinated biphenyls

Isomeric chlorinated biphenyls are observed to yield very similar mass spectra, rarely exhibiting a [M  Cl]+ fragment of any siVgnificant magnitude. However, those isomers containing three ortho chloro substituents display a relatively intense [M  Cl]+ fragment. A rationalization for this observat...

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Veröffentlicht in:	Biological Mass Spectrometry 1976-04, Vol.3 (2), p.88-90
Hauptverfasser:	Levy, Louis A., Oswald, Edward O.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical Phenomena Chemistry Chromatography, Gas Gas Chromatography-Mass Spectrometry Isomerism Polychlorinated Biphenyls - analysis
Online-Zugang:	Volltext
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