Adsorption and removal of Cu (II) ions from aqueous solution using pretreated fish bones
Pretreated fish bones obtained from engraulis European anchovy ( Engraulis encrasicolus), European anchovy ( Sardine pilchardus), bogue ( Boops boops), bluefish ( Pomatomus saltatrix) and gilthead seabream ( Sparus aurata) were used as natural, cost-effective, waste sorbents for the adsorption and r...
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| Veröffentlicht in: | Desalination 2010-12, Vol.264 (1), p.37-47 |
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| creator | Kizilkaya, Bayram Tekinay, A. Adem Dilgin, Yusuf |
| description | Pretreated fish bones obtained from engraulis European anchovy (
Engraulis encrasicolus), European anchovy (
Sardine pilchardus), bogue (
Boops boops), bluefish (
Pomatomus saltatrix) and gilthead seabream (
Sparus aurata) were used as natural, cost-effective, waste sorbents for the adsorption and removal of copper from aqueous systems. The removal efficiency of the adsorbent was investigated as a function of pH, contact time, initial metal concentration, temperature, cleaning process, fish species and adsorbent dose. The maximum adsorption capacity was 150.7
mg/g at optimum conditions. The kinetic results of adsorption obeyed a pseudo-second-order model. Copper adsorption fitted the Langmuir isotherm. Δ
H
0 value was 12.9
kJ/mol indicating that the adsorption mechanism was endothermic. The activation energy,
E
a
, was determined as 52.9
kJ/mol. Weber–Morris and Urano–Tachikawa diffusion models were also applied to experimental equilibrium data. The fish bones were effectively used as a sorbent for the removal of Cu ions from aqueous solution. |
| doi_str_mv | 10.1016/j.desal.2010.06.076 |
| format | Article |
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Engraulis encrasicolus), European anchovy (
Sardine pilchardus), bogue (
Boops boops), bluefish (
Pomatomus saltatrix) and gilthead seabream (
Sparus aurata) were used as natural, cost-effective, waste sorbents for the adsorption and removal of copper from aqueous systems. The removal efficiency of the adsorbent was investigated as a function of pH, contact time, initial metal concentration, temperature, cleaning process, fish species and adsorbent dose. The maximum adsorption capacity was 150.7
mg/g at optimum conditions. The kinetic results of adsorption obeyed a pseudo-second-order model. Copper adsorption fitted the Langmuir isotherm. Δ
H
0 value was 12.9
kJ/mol indicating that the adsorption mechanism was endothermic. The activation energy,
E
a
, was determined as 52.9
kJ/mol. Weber–Morris and Urano–Tachikawa diffusion models were also applied to experimental equilibrium data. The fish bones were effectively used as a sorbent for the removal of Cu ions from aqueous solution.</description><identifier>ISSN: 0011-9164</identifier><identifier>EISSN: 1873-4464</identifier><identifier>DOI: 10.1016/j.desal.2010.06.076</identifier><identifier>CODEN: DSLNAH</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Adsorbents ; Adsorption ; Anchovies ; Applied sciences ; Aqueous solutions ; Bones ; Boops boops ; Chemical engineering ; Copper ; Diffusion ; Endothermic reactions ; Engraulis ; Engraulis encrasicolus ; Exact sciences and technology ; Fish ; Fish bone ; Kinetic ; Marine ; Pollution ; Pomatomus saltatrix ; Removal ; Sardinops ; Sorbents ; Sparus aurata</subject><ispartof>Desalination, 2010-12, Vol.264 (1), p.37-47</ispartof><rights>2010 Elsevier B.V.</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c464t-4102d45849e1d5e5a3ef895a6cbc9235d153f764906a7533e9bbf90c35af809a3</citedby><cites>FETCH-LOGICAL-c464t-4102d45849e1d5e5a3ef895a6cbc9235d153f764906a7533e9bbf90c35af809a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.desal.2010.06.076$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>315,781,785,3551,27925,27926,45996</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=23377482$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Kizilkaya, Bayram</creatorcontrib><creatorcontrib>Tekinay, A. Adem</creatorcontrib><creatorcontrib>Dilgin, Yusuf</creatorcontrib><title>Adsorption and removal of Cu (II) ions from aqueous solution using pretreated fish bones</title><title>Desalination</title><description>Pretreated fish bones obtained from engraulis European anchovy (
Engraulis encrasicolus), European anchovy (
Sardine pilchardus), bogue (
Boops boops), bluefish (
Pomatomus saltatrix) and gilthead seabream (
Sparus aurata) were used as natural, cost-effective, waste sorbents for the adsorption and removal of copper from aqueous systems. The removal efficiency of the adsorbent was investigated as a function of pH, contact time, initial metal concentration, temperature, cleaning process, fish species and adsorbent dose. The maximum adsorption capacity was 150.7
mg/g at optimum conditions. The kinetic results of adsorption obeyed a pseudo-second-order model. Copper adsorption fitted the Langmuir isotherm. Δ
H
0 value was 12.9
kJ/mol indicating that the adsorption mechanism was endothermic. The activation energy,
E
a
, was determined as 52.9
kJ/mol. Weber–Morris and Urano–Tachikawa diffusion models were also applied to experimental equilibrium data. The fish bones were effectively used as a sorbent for the removal of Cu ions from aqueous solution.</description><subject>Adsorbents</subject><subject>Adsorption</subject><subject>Anchovies</subject><subject>Applied sciences</subject><subject>Aqueous solutions</subject><subject>Bones</subject><subject>Boops boops</subject><subject>Chemical engineering</subject><subject>Copper</subject><subject>Diffusion</subject><subject>Endothermic reactions</subject><subject>Engraulis</subject><subject>Engraulis encrasicolus</subject><subject>Exact sciences and technology</subject><subject>Fish</subject><subject>Fish bone</subject><subject>Kinetic</subject><subject>Marine</subject><subject>Pollution</subject><subject>Pomatomus saltatrix</subject><subject>Removal</subject><subject>Sardinops</subject><subject>Sorbents</subject><subject>Sparus aurata</subject><issn>0011-9164</issn><issn>1873-4464</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNp9kE9vEzEQxS0EEiHwCbj4giiHDfb63_rAoYqARqrEBSRulmOPwdFmHTy7lfrtcZqqx55GM_PezNOPkPecbTjj-vNhEwH9uOlZmzC9YUa_ICs-GNFJqeVLsmKM885yLV-TN4iH1vZWiBX5fR2x1NOcy0T9FGmFY7nzIy2Jbhd6tdt9om2FNNVypP7fAmVBimVcHhwL5ukPPVWYK_gZIk0Z_9J9mQDfklfJjwjvHuua_Pr29ef2prv98X23vb7tQgs2d5KzPko1SAs8KlBeQBqs8jrsg-2FilyJZLS0THujhAC73yfLglA-Dcx6sSYfL3dPtbR4OLtjxgDj6KdzVjcI3jjodmtNrp5VcmMMN6xXvEnFRRpqQayQ3Knmo6_3jjN3Ju4O7oG4OxN3TLtGvLk-PD7wGPyYqp9CxidrL4QxcjgH-XLRQeNyl6E6DBmmADFXCLOLJT_75z-acJau</recordid><startdate>20101215</startdate><enddate>20101215</enddate><creator>Kizilkaya, Bayram</creator><creator>Tekinay, A. Adem</creator><creator>Dilgin, Yusuf</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SU</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>KR7</scope><scope>7ST</scope><scope>7TN</scope><scope>7UA</scope><scope>F1W</scope><scope>H95</scope><scope>L.G</scope><scope>SOI</scope></search><sort><creationdate>20101215</creationdate><title>Adsorption and removal of Cu (II) ions from aqueous solution using pretreated fish bones</title><author>Kizilkaya, Bayram ; Tekinay, A. Adem ; Dilgin, Yusuf</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c464t-4102d45849e1d5e5a3ef895a6cbc9235d153f764906a7533e9bbf90c35af809a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Adsorbents</topic><topic>Adsorption</topic><topic>Anchovies</topic><topic>Applied sciences</topic><topic>Aqueous solutions</topic><topic>Bones</topic><topic>Boops boops</topic><topic>Chemical engineering</topic><topic>Copper</topic><topic>Diffusion</topic><topic>Endothermic reactions</topic><topic>Engraulis</topic><topic>Engraulis encrasicolus</topic><topic>Exact sciences and technology</topic><topic>Fish</topic><topic>Fish bone</topic><topic>Kinetic</topic><topic>Marine</topic><topic>Pollution</topic><topic>Pomatomus saltatrix</topic><topic>Removal</topic><topic>Sardinops</topic><topic>Sorbents</topic><topic>Sparus aurata</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kizilkaya, Bayram</creatorcontrib><creatorcontrib>Tekinay, A. Adem</creatorcontrib><creatorcontrib>Dilgin, Yusuf</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Environmental Engineering Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>Civil Engineering Abstracts</collection><collection>Environment Abstracts</collection><collection>Oceanic Abstracts</collection><collection>Water Resources Abstracts</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 1: Biological Sciences & Living Resources</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><collection>Environment Abstracts</collection><jtitle>Desalination</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kizilkaya, Bayram</au><au>Tekinay, A. Adem</au><au>Dilgin, Yusuf</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Adsorption and removal of Cu (II) ions from aqueous solution using pretreated fish bones</atitle><jtitle>Desalination</jtitle><date>2010-12-15</date><risdate>2010</risdate><volume>264</volume><issue>1</issue><spage>37</spage><epage>47</epage><pages>37-47</pages><issn>0011-9164</issn><eissn>1873-4464</eissn><coden>DSLNAH</coden><abstract>Pretreated fish bones obtained from engraulis European anchovy (
Engraulis encrasicolus), European anchovy (
Sardine pilchardus), bogue (
Boops boops), bluefish (
Pomatomus saltatrix) and gilthead seabream (
Sparus aurata) were used as natural, cost-effective, waste sorbents for the adsorption and removal of copper from aqueous systems. The removal efficiency of the adsorbent was investigated as a function of pH, contact time, initial metal concentration, temperature, cleaning process, fish species and adsorbent dose. The maximum adsorption capacity was 150.7
mg/g at optimum conditions. The kinetic results of adsorption obeyed a pseudo-second-order model. Copper adsorption fitted the Langmuir isotherm. Δ
H
0 value was 12.9
kJ/mol indicating that the adsorption mechanism was endothermic. The activation energy,
E
a
, was determined as 52.9
kJ/mol. Weber–Morris and Urano–Tachikawa diffusion models were also applied to experimental equilibrium data. The fish bones were effectively used as a sorbent for the removal of Cu ions from aqueous solution.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.desal.2010.06.076</doi><tpages>11</tpages></addata></record> |
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| source | Access via ScienceDirect (Elsevier) |
| subjects | Adsorbents Adsorption Anchovies Applied sciences Aqueous solutions Bones Boops boops Chemical engineering Copper Diffusion Endothermic reactions Engraulis Engraulis encrasicolus Exact sciences and technology Fish Fish bone Kinetic Marine Pollution Pomatomus saltatrix Removal Sardinops Sorbents Sparus aurata |
| title | Adsorption and removal of Cu (II) ions from aqueous solution using pretreated fish bones |
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