Direct formation of nanophase hydroxyapatite on cathodically polarized electrodes
Ultrafine-grained, nanophase coatings of hydroxyapatite were synthesized by electrocrystallization from dilute electrolytes ([Ca]=6.1 x 10-4 M, [phosphate]=3.6 x 10-4 M) at pH values comparable with the biological pH. At these comparatively low supersaturations, hydroxyapatite is shown to be precipi...
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Veröffentlicht in: | Journal of materials science. Materials in medicine 1998-02, Vol.9 (2), p.67-72 |
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description | Ultrafine-grained, nanophase coatings of hydroxyapatite were synthesized by electrocrystallization from dilute electrolytes ([Ca]=6.1 x 10-4 M, [phosphate]=3.6 x 10-4 M) at pH values comparable with the biological pH. At these comparatively low supersaturations, hydroxyapatite is shown to be precipitated without the formation of a precursor phase. A description of the sequence of events occurring at the electrode-electrolyte interface is given to explain the mechanism involved in the direct formation of nanophase hydroxyapatite on polarized electrodes. |
doi_str_mv | 10.1023/A:1008838813120 |
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subjects | Biomedical materials Hydroxyapatite Materials science |
title | Direct formation of nanophase hydroxyapatite on cathodically polarized electrodes |
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