catena-Poly[[diiodidomercury(II)]-μ-nicotine-κN:N']

catena-Poly[[diiodidomercury(II)]-μ-nicotine-κN:N']

The title polymeric complex, [HgI(2)(C(10)H(14)N(2))](n), was prepared from a solution of nicotine, mercury(II) iodide and 4-cyano-pyridine in dimethyl-formamide. Each nicotine mol-ecule is bonded to two Hg atoms, one through the pyrrolidine N atom and the other through the pyridine N atom, forming...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2008-07, Vol.64 (Pt 8), p.m1026-m1026
Hauptverfasser: Jiang, Zhengjing, Tang, Guodong, Lu, Lude
Format: Artikel
Sprache:eng
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Zusammenfassung:The title polymeric complex, [HgI(2)(C(10)H(14)N(2))](n), was prepared from a solution of nicotine, mercury(II) iodide and 4-cyano-pyridine in dimethyl-formamide. Each nicotine mol-ecule is bonded to two Hg atoms, one through the pyrrolidine N atom and the other through the pyridine N atom, forming infinite zigzag polymeric chains. The coordin-ation around mercury is completed by two iodide ligands, resulting in a distorted tetra-hedral arrangement.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536808020904