The role of boron on the magneto-caloric effect of FeZrB metallic glasses

Fe-rich FeZrB metallic glasses exhibit magneto-caloric effect (MCE) around room temperature. Amorphous ribbons of two different compositions, Fe 91Zr 7B 2 and Fe 88Zr 8B 4, with respective Curie temperature values of 230 and 285 K have been studied. Although the maximum magnetic entropy change is re...

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Veröffentlicht in:Intermetallics 2010-12, Vol.18 (12), p.2464-2467
Hauptverfasser: Álvarez, Pablo, Gorria, Pedro, Sánchez Marcos, Jorge, Fernández Barquín, Luis, Blanco, Jesús A.
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container_end_page 2467
container_issue 12
container_start_page 2464
container_title Intermetallics
container_volume 18
creator Álvarez, Pablo
Gorria, Pedro
Sánchez Marcos, Jorge
Fernández Barquín, Luis
Blanco, Jesús A.
description Fe-rich FeZrB metallic glasses exhibit magneto-caloric effect (MCE) around room temperature. Amorphous ribbons of two different compositions, Fe 91Zr 7B 2 and Fe 88Zr 8B 4, with respective Curie temperature values of 230 and 285 K have been studied. Although the maximum magnetic entropy change is relatively moderate ( | Δ S M | max  ∼ 3 J K −1 kg −1 under an applied magnetic field change from 0 to 50 kOe), the MCE spreads over a broad temperature interval ( ∆T ∼ 200 K), giving rise to a large refrigerant capacity loss (RC ∼ 435 J kg −1) without any hysteresis. The Curie temperature can be easily tuned between 200 and 350 K by changing the boron content. Therefore, the MCE can be controlled over a wide temperature interval, thus making these amorphous alloys promising candidates for magnetic refrigeration near room temperature.
doi_str_mv 10.1016/j.intermet.2010.07.018
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subjects A. magnetic intermetallics
Amorphous materials
B. magnetic properties
Boron
Curie temperature
Entropy
G. ambient-temperature uses
G. magnetic applications
Iron
Metallic glasses
Ribbons
Tapes (metallic)
title The role of boron on the magneto-caloric effect of FeZrB metallic glasses
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