Single crystal EPR study of the dinuclear Cu(II) complex [Cu(tda)(phen)](2)·H(2)tda (tda = thiodiacetate, phen = phenanthroline): influence of weak interdimeric magnetic interactions

We report powder and single crystal EPR measurements of [Cu(tda)(phen)](2)·H(2)tda (tda = thiodiacetate, phen = phenanthroline) at 9.7 GHz. This compound consists of centrosymmetric copper(II) ion dimers, weakly ferromagnetically exchange-coupled (J = +3.2 cm(-1)), in which the dimeric units are lin...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2010-12, Vol.114 (50), p.13069-13075
Hauptverfasser:	Neuman, Nicolás I, Perec, Mireille, González, Pablo J, Passeggi, Mario C G, Rizzi, Alberto C, Brondino, Carlos D
Format:	Artikel
Sprache:	eng
Schlagworte:	Copper - chemistry Crystallography, X-Ray Dimerization Electron Spin Resonance Spectroscopy Ligands Magnetics Models, Molecular Molecular Conformation Organometallic Compounds - chemistry
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!