A General and Efficient Iridium-Catalyzed Hydroformylation of Olefins
Breaking with conventional wisdom: Hydroformylation catalysts are generally based on rhodium; earlier, cobalt was used. Iridium, which is less expensive than rhodium, was considered too unreactive. However, iridium/phosphine complexes have now been shown to form active catalysts for the hydroformyla...
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Veröffentlicht in: | Angewandte Chemie International Edition 2011-01, Vol.50 (1), p.280-284 |
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