Recognition of Hg(2+) using diametrically disubstituted cyclam unit

A newly synthesized 1,4,8,11-tetraazacyclotetradecane derivative (L), functionalized with a diazo moiety as the reporter functionality, is found to bind specifically to Hg(2+) with an associated change in color that could be visually detected. With biologically benign β-CD, it forms an inclusion com...

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Veröffentlicht in:	Inorganic chemistry 2010-12, Vol.49 (24), p.11485-11492
Hauptverfasser:	Mahato, Prasenjit, Ghosh, Amrita, Saha, Sukdeb, Mishra, Sandhya, Mishra, Sanjiv K, Das, Amitava
Format:	Artikel
Sprache:	eng
Schlagworte:	Azo Compounds - chemistry beta-Cyclodextrins - chemistry Heterocyclic Compounds - chemistry Heterocyclic Compounds - pharmacology Magnetic Resonance Spectroscopy Mercuric Chloride - analysis Pseudomonas putida - drug effects Spectrometry, Mass, Electrospray Ionization Spectrophotometry, Ultraviolet Spectroscopy, Fourier Transform Infrared
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