Ring opening of acylated β- d-arabinofuranose 1,2,5-orthobenzoates with nucleophiles allows access to novel selectively-protected arabinofuranose building blocks

β- d-Arabinofuranose 1,2,5-orthobenzoates with 3- O-acetyl, 3- O-benzoyl, and 3- O-chloroacetyl groups were prepared in an efficient manner starting from readily available crystalline methyl 2,3,5-tri- O-benzoyl-α- d-arabinofuranoside, and ring-opening reactions of these compounds with O- and S-nucl...

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Veröffentlicht in:	Carbohydrate research 2011-01, Vol.346 (1), p.7-15
Hauptverfasser:	Podvalnyy, Nikita M., Sedinkin, Sergey L., Abronina, Polina I., Zinin, Alexander I., Fedina, Ksenia G., Torgov, Vladimir I., Kononov, Leonid O.
Format:	Artikel
Sprache:	eng
Schlagworte:	1,2,5-Orthobenzoate Arabinofuranose arabinose Arabinose - analogs & derivatives Arabinose - chemistry benzoates Benzoates - chemistry Building blocks Carbohydrate Sequence glycosidic linkages Molecular Sequence Data Ring opening Thioglycosides Thioglycosides - chemistry
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