Zinc Isotopic Composition of Particulate Matter Generated during the Combustion of Coal and Coal + Tire-Derived Fuels
Atmospheric Zn emissions from the burning of coal and tire-derived fuel (TDF) for power generation can be considerable. In an effort to lay the foundation for tracking these contributions, we evaluated the Zn isotopes of coal, a mixture of 95 wt % coal + 5 wt % TDF, and the particulate matter (PM) d...
Gespeichert in:
| Veröffentlicht in: | Environmental science & technology 2010-12, Vol.44 (23), p.9219-9224 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 9224 |
|---|---|
| container_issue | 23 |
| container_start_page | 9219 |
| container_title | Environmental science & technology |
| container_volume | 44 |
| creator | Borrok, David M Gieré, Reto Ren, Minghua Landa, Edward R |
| description | Atmospheric Zn emissions from the burning of coal and tire-derived fuel (TDF) for power generation can be considerable. In an effort to lay the foundation for tracking these contributions, we evaluated the Zn isotopes of coal, a mixture of 95 wt % coal + 5 wt % TDF, and the particulate matter (PM) derived from their combustion in a power-generating plant. The average Zn concentrations and δ66Zn were 36 mg/kg and 183 mg/kg and +0.24‰ and +0.13‰ for the coal and coal + TDF, respectively. The δ66Zn of the PM sequestered in the cyclone-type mechanical separator was the lightest measured, −0.48‰ for coal and −0.81‰ for coal+TDF. The δ66Zn of the PM from the electrostatic precipitator showed a slight enrichment in the heavier Zn isotopes relative to the starting material. PM collected from the stack had the heaviest δ66Zn in the system, +0.63‰ and +0.50‰ for the coal and coal + TDF, respectively. Initial fractionation during the generation of a Zn-rich vapor is followed by temperature-dependent fractionation as Zn condenses onto the PM. The isotopic changes of the two fuel types are similar, suggesting that their inherent chemical differences have only a secondary impact on the isotopic fractionation process. |
| doi_str_mv | 10.1021/es102439g |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_817652090</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>817652090</sourcerecordid><originalsourceid>FETCH-LOGICAL-a352t-70f72be4ebf01135754bb0fb1bcbcdb9f15685caf2bd82be3c629d213d4e5e803</originalsourceid><addsrcrecordid>eNpl0d1rFDEQAPBQlPasfeg_IEEoIrKaSTb78VhOWwsVfahQ-rIk2UlN2dtc8yH435vjrj3Qp5nAbybDDCGnwD4C4_AJYwm16O8PyAIkZ5XsJLwgC8ZAVL1obo_IqxgfGGNcsO6QHHFgdctkvyD5zs2GXkWf_NoZuvSrtY8uOT9Tb-kPFZIzeVIJ6TeVEgZ6iTOG8h7pmIOb72n6hZsyneNT1dKriap53CYf6I0LWH3G4H6XqouMU3xNXlo1RTzZxWPy8-LLzfJrdf398mp5fl0pIXmqWmZbrrFGbRmAkK2stWZWgzbajLq3IJtOGmW5HrsChWl4P3IQY40SOyaOybtt33XwjxljGlYuGpwmNaPPceigbcq--o18-4988DnMZbih4yChaRpe0PstMsHHGNAO6-BWKvwZgA2bSwzPlyj2za5h1iscn-XT6gs42wEVjZpsULNxce-E7Nuuh71TJu6H-v_Dv9bLnGI</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>821516662</pqid></control><display><type>article</type><title>Zinc Isotopic Composition of Particulate Matter Generated during the Combustion of Coal and Coal + Tire-Derived Fuels</title><source>MEDLINE</source><source>American Chemical Society Journals</source><creator>Borrok, David M ; Gieré, Reto ; Ren, Minghua ; Landa, Edward R</creator><creatorcontrib>Borrok, David M ; Gieré, Reto ; Ren, Minghua ; Landa, Edward R</creatorcontrib><description>Atmospheric Zn emissions from the burning of coal and tire-derived fuel (TDF) for power generation can be considerable. In an effort to lay the foundation for tracking these contributions, we evaluated the Zn isotopes of coal, a mixture of 95 wt % coal + 5 wt % TDF, and the particulate matter (PM) derived from their combustion in a power-generating plant. The average Zn concentrations and δ66Zn were 36 mg/kg and 183 mg/kg and +0.24‰ and +0.13‰ for the coal and coal + TDF, respectively. The δ66Zn of the PM sequestered in the cyclone-type mechanical separator was the lightest measured, −0.48‰ for coal and −0.81‰ for coal+TDF. The δ66Zn of the PM from the electrostatic precipitator showed a slight enrichment in the heavier Zn isotopes relative to the starting material. PM collected from the stack had the heaviest δ66Zn in the system, +0.63‰ and +0.50‰ for the coal and coal + TDF, respectively. Initial fractionation during the generation of a Zn-rich vapor is followed by temperature-dependent fractionation as Zn condenses onto the PM. The isotopic changes of the two fuel types are similar, suggesting that their inherent chemical differences have only a secondary impact on the isotopic fractionation process.</description><identifier>ISSN: 0013-936X</identifier><identifier>EISSN: 1520-5851</identifier><identifier>DOI: 10.1021/es102439g</identifier><identifier>PMID: 21047059</identifier><identifier>CODEN: ESTHAG</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Air Pollutants - analysis ; Air Pollutants - chemistry ; Airborne particulates ; Applied sciences ; Chemical Fractionation ; Coal ; Coal - analysis ; Electrostatic precipitators ; Emissions ; Energy and the Environment ; Environmental Monitoring ; Exact sciences and technology ; Hot Temperature ; Incineration ; Isotopes ; Particle Size ; Particulate Matter - analysis ; Particulate Matter - chemistry ; Pollution ; Power plants ; Power Plants - instrumentation ; Zinc ; Zinc Isotopes - analysis ; Zinc Isotopes - chemistry</subject><ispartof>Environmental science & technology, 2010-12, Vol.44 (23), p.9219-9224</ispartof><rights>Copyright © 2010 American Chemical Society</rights><rights>2015 INIST-CNRS</rights><rights>Copyright American Chemical Society Dec 1, 2010</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a352t-70f72be4ebf01135754bb0fb1bcbcdb9f15685caf2bd82be3c629d213d4e5e803</citedby><cites>FETCH-LOGICAL-a352t-70f72be4ebf01135754bb0fb1bcbcdb9f15685caf2bd82be3c629d213d4e5e803</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/es102439g$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/es102439g$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,2765,27076,27924,27925,56738,56788</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=23597891$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/21047059$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Borrok, David M</creatorcontrib><creatorcontrib>Gieré, Reto</creatorcontrib><creatorcontrib>Ren, Minghua</creatorcontrib><creatorcontrib>Landa, Edward R</creatorcontrib><title>Zinc Isotopic Composition of Particulate Matter Generated during the Combustion of Coal and Coal + Tire-Derived Fuels</title><title>Environmental science & technology</title><addtitle>Environ. Sci. Technol</addtitle><description>Atmospheric Zn emissions from the burning of coal and tire-derived fuel (TDF) for power generation can be considerable. In an effort to lay the foundation for tracking these contributions, we evaluated the Zn isotopes of coal, a mixture of 95 wt % coal + 5 wt % TDF, and the particulate matter (PM) derived from their combustion in a power-generating plant. The average Zn concentrations and δ66Zn were 36 mg/kg and 183 mg/kg and +0.24‰ and +0.13‰ for the coal and coal + TDF, respectively. The δ66Zn of the PM sequestered in the cyclone-type mechanical separator was the lightest measured, −0.48‰ for coal and −0.81‰ for coal+TDF. The δ66Zn of the PM from the electrostatic precipitator showed a slight enrichment in the heavier Zn isotopes relative to the starting material. PM collected from the stack had the heaviest δ66Zn in the system, +0.63‰ and +0.50‰ for the coal and coal + TDF, respectively. Initial fractionation during the generation of a Zn-rich vapor is followed by temperature-dependent fractionation as Zn condenses onto the PM. The isotopic changes of the two fuel types are similar, suggesting that their inherent chemical differences have only a secondary impact on the isotopic fractionation process.</description><subject>Air Pollutants - analysis</subject><subject>Air Pollutants - chemistry</subject><subject>Airborne particulates</subject><subject>Applied sciences</subject><subject>Chemical Fractionation</subject><subject>Coal</subject><subject>Coal - analysis</subject><subject>Electrostatic precipitators</subject><subject>Emissions</subject><subject>Energy and the Environment</subject><subject>Environmental Monitoring</subject><subject>Exact sciences and technology</subject><subject>Hot Temperature</subject><subject>Incineration</subject><subject>Isotopes</subject><subject>Particle Size</subject><subject>Particulate Matter - analysis</subject><subject>Particulate Matter - chemistry</subject><subject>Pollution</subject><subject>Power plants</subject><subject>Power Plants - instrumentation</subject><subject>Zinc</subject><subject>Zinc Isotopes - analysis</subject><subject>Zinc Isotopes - chemistry</subject><issn>0013-936X</issn><issn>1520-5851</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNpl0d1rFDEQAPBQlPasfeg_IEEoIrKaSTb78VhOWwsVfahQ-rIk2UlN2dtc8yH435vjrj3Qp5nAbybDDCGnwD4C4_AJYwm16O8PyAIkZ5XsJLwgC8ZAVL1obo_IqxgfGGNcsO6QHHFgdctkvyD5zs2GXkWf_NoZuvSrtY8uOT9Tb-kPFZIzeVIJ6TeVEgZ6iTOG8h7pmIOb72n6hZsyneNT1dKriap53CYf6I0LWH3G4H6XqouMU3xNXlo1RTzZxWPy8-LLzfJrdf398mp5fl0pIXmqWmZbrrFGbRmAkK2stWZWgzbajLq3IJtOGmW5HrsChWl4P3IQY40SOyaOybtt33XwjxljGlYuGpwmNaPPceigbcq--o18-4988DnMZbih4yChaRpe0PstMsHHGNAO6-BWKvwZgA2bSwzPlyj2za5h1iscn-XT6gs42wEVjZpsULNxce-E7Nuuh71TJu6H-v_Dv9bLnGI</recordid><startdate>20101201</startdate><enddate>20101201</enddate><creator>Borrok, David M</creator><creator>Gieré, Reto</creator><creator>Ren, Minghua</creator><creator>Landa, Edward R</creator><general>American Chemical Society</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QO</scope><scope>7ST</scope><scope>7T7</scope><scope>7U7</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>P64</scope><scope>SOI</scope><scope>7X8</scope></search><sort><creationdate>20101201</creationdate><title>Zinc Isotopic Composition of Particulate Matter Generated during the Combustion of Coal and Coal + Tire-Derived Fuels</title><author>Borrok, David M ; Gieré, Reto ; Ren, Minghua ; Landa, Edward R</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a352t-70f72be4ebf01135754bb0fb1bcbcdb9f15685caf2bd82be3c629d213d4e5e803</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Air Pollutants - analysis</topic><topic>Air Pollutants - chemistry</topic><topic>Airborne particulates</topic><topic>Applied sciences</topic><topic>Chemical Fractionation</topic><topic>Coal</topic><topic>Coal - analysis</topic><topic>Electrostatic precipitators</topic><topic>Emissions</topic><topic>Energy and the Environment</topic><topic>Environmental Monitoring</topic><topic>Exact sciences and technology</topic><topic>Hot Temperature</topic><topic>Incineration</topic><topic>Isotopes</topic><topic>Particle Size</topic><topic>Particulate Matter - analysis</topic><topic>Particulate Matter - chemistry</topic><topic>Pollution</topic><topic>Power plants</topic><topic>Power Plants - instrumentation</topic><topic>Zinc</topic><topic>Zinc Isotopes - analysis</topic><topic>Zinc Isotopes - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Borrok, David M</creatorcontrib><creatorcontrib>Gieré, Reto</creatorcontrib><creatorcontrib>Ren, Minghua</creatorcontrib><creatorcontrib>Landa, Edward R</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Biotechnology Research Abstracts</collection><collection>Environment Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Toxicology Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Environment Abstracts</collection><collection>MEDLINE - Academic</collection><jtitle>Environmental science & technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Borrok, David M</au><au>Gieré, Reto</au><au>Ren, Minghua</au><au>Landa, Edward R</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Zinc Isotopic Composition of Particulate Matter Generated during the Combustion of Coal and Coal + Tire-Derived Fuels</atitle><jtitle>Environmental science & technology</jtitle><addtitle>Environ. Sci. Technol</addtitle><date>2010-12-01</date><risdate>2010</risdate><volume>44</volume><issue>23</issue><spage>9219</spage><epage>9224</epage><pages>9219-9224</pages><issn>0013-936X</issn><eissn>1520-5851</eissn><coden>ESTHAG</coden><abstract>Atmospheric Zn emissions from the burning of coal and tire-derived fuel (TDF) for power generation can be considerable. In an effort to lay the foundation for tracking these contributions, we evaluated the Zn isotopes of coal, a mixture of 95 wt % coal + 5 wt % TDF, and the particulate matter (PM) derived from their combustion in a power-generating plant. The average Zn concentrations and δ66Zn were 36 mg/kg and 183 mg/kg and +0.24‰ and +0.13‰ for the coal and coal + TDF, respectively. The δ66Zn of the PM sequestered in the cyclone-type mechanical separator was the lightest measured, −0.48‰ for coal and −0.81‰ for coal+TDF. The δ66Zn of the PM from the electrostatic precipitator showed a slight enrichment in the heavier Zn isotopes relative to the starting material. PM collected from the stack had the heaviest δ66Zn in the system, +0.63‰ and +0.50‰ for the coal and coal + TDF, respectively. Initial fractionation during the generation of a Zn-rich vapor is followed by temperature-dependent fractionation as Zn condenses onto the PM. The isotopic changes of the two fuel types are similar, suggesting that their inherent chemical differences have only a secondary impact on the isotopic fractionation process.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>21047059</pmid><doi>10.1021/es102439g</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0013-936X |
| ispartof | Environmental science & technology, 2010-12, Vol.44 (23), p.9219-9224 |
| issn | 0013-936X 1520-5851 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_817652090 |
| source | MEDLINE; American Chemical Society Journals |
| subjects | Air Pollutants - analysis Air Pollutants - chemistry Airborne particulates Applied sciences Chemical Fractionation Coal Coal - analysis Electrostatic precipitators Emissions Energy and the Environment Environmental Monitoring Exact sciences and technology Hot Temperature Incineration Isotopes Particle Size Particulate Matter - analysis Particulate Matter - chemistry Pollution Power plants Power Plants - instrumentation Zinc Zinc Isotopes - analysis Zinc Isotopes - chemistry |
| title | Zinc Isotopic Composition of Particulate Matter Generated during the Combustion of Coal and Coal + Tire-Derived Fuels |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-27T17%3A16%3A06IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Zinc%20Isotopic%20Composition%20of%20Particulate%20Matter%20Generated%20during%20the%20Combustion%20of%20Coal%20and%20Coal%20+%20Tire-Derived%20Fuels&rft.jtitle=Environmental%20science%20&%20technology&rft.au=Borrok,%20David%20M&rft.date=2010-12-01&rft.volume=44&rft.issue=23&rft.spage=9219&rft.epage=9224&rft.pages=9219-9224&rft.issn=0013-936X&rft.eissn=1520-5851&rft.coden=ESTHAG&rft_id=info:doi/10.1021/es102439g&rft_dat=%3Cproquest_cross%3E817652090%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=821516662&rft_id=info:pmid/21047059&rfr_iscdi=true |