Enantioselective desymmetrization of meso-epoxides with anilines catalyzed by polymeric and monomeric Ti(IV) salen complexes

The active catalysts for the enantioselective ring opening (ARO) of meso‐stilbene oxide, cis‐butene oxide, cyclohexene oxide, cyclopentene oxide, and cyclooctene oxide with various substituted anilines were generated in situ by the reaction of Ti(OiPr)4 with poly‐[(R,R)‐N,N′‐bis‐{3‐(1,1‐dimethylethy...

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Veröffentlicht in:	Chirality (New York, N.Y.) N.Y.), 2011-01, Vol.23 (1), p.76-83
Hauptverfasser:	Kureshy, Rukhsana I., Kumar, Manish, Agrawal, Santosh, Khan, Noor-Ul H., Dangi, Balchand, Abdi, Sayed H. R., Bajaj, Hari C.
Format:	Artikel
Sprache:	eng
Schlagworte:	Additives Aniline Catalysis Catalysts chiral monomeric and polymeric Ti(IV) Chirality Cyclohexene enantioselective ring opening meso-epoxides Oxides Recycled salen syn and anti-β-aminoalcohol
Online-Zugang:	Volltext
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