Redox-Induced Palladium Migrations that Allow Reversible Topological Changes between Palladium(II) Complexes of Möbius Aromatic [28]Hexaphyrin and Hückel Aromatic [26]Hexaphyrin

Plane twisted: A twisted Möbius aromatic [28]hexaphyrin/PdII complex and a planar Hückel aromatic [26]hexaphyrin/PdII complex are reversibly interconvertible by an unprecedented palladium migration through oxidation and reduction (see scheme). The [26]hexaphyrin/PdII complex is a precursor to [26]he...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Angewandte Chemie (International ed.) 2010-12, Vol.49 (49), p.9488-9491
Hauptverfasser:	Inoue, Mitsunori, Osuka, Atsuhiro
Format:	Artikel
Sprache:	eng
Schlagworte:	aromaticity Crystallography, X-Ray hexaphyrins metalation Metalloporphyrins - chemistry Models, Molecular Molecular Conformation Oxidation-Reduction palladium Palladium - chemistry porphyrinoids
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

container_end_page	9491
container_issue	49
container_start_page	9488
container_title	Angewandte Chemie (International ed.)
container_volume	49
creator	Inoue, Mitsunori Osuka, Atsuhiro
description	Plane twisted: A twisted Möbius aromatic [28]hexaphyrin/PdII complex and a planar Hückel aromatic [26]hexaphyrin/PdII complex are reversibly interconvertible by an unprecedented palladium migration through oxidation and reduction (see scheme). The [26]hexaphyrin/PdII complex is a precursor to [26]hexaphyrin hetero‐bis(metal) complexes having PdII/CuIII or PdII/AgIII centers. C gray, N blue, H white, F green, Pd yellow.
doi_str_mv	10.1002/anie.201005334
format	Article
fullrecord	<record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_815960846</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>815960846</sourcerecordid><originalsourceid>FETCH-LOGICAL-c4064-383705a544913356ccb3628f734ceed41fbd4eec82382428ec2d42ea0ed27fbc3</originalsourceid><addsrcrecordid>eNqFkU9v0zAYhyMEYmNw5Qi-AYcU_0viHKsy1krbQGMbSAhZjvOm9ebExU5o-7mQOHHbF8NTx-gNvYf3lfz8Hsn6JclzgkcEY_pWdQZGFMc7Y4w_SPZJRknKioI9jDdnLC1ERvaSJyFcRV4InD9O9ijBjLCS7Cc_z6B263TW1YOGGn1U1qraDC06MXOveuO6gPqF6tHYWrdCZ_ADfDCVBXTuls66udHKoslCdXMIqIJ-BdD907yezd6giWuXFtbx3TXo5OZXZYaAxt610a_RVyq-TWGtlouNNx1SXY2mN7_1NdhdJt9hniaPGmUDPLvbB8nF-8PzyTQ9_nA0m4yPU81xzlMmWIEzlXFeEsayXOuK5VQ0BeMaoOakqWoOoAVlgnIqQNOaU1AYalo0lWYHyautd-nd9wFCL1sTNMSvdeCGIAXJyhwLnkdytCW1dyF4aOTSm1b5jSRY3vYkb3uS9z3FwIs79VC1UN_jf4uJQLkFVsbC5j86OT6dHe7K023WhB7W91nlr2VesCKTn0-PJC4uL9-VX0qJI_9yyzfKSTX3JsiLT1HHMCnj4Jz9AUwBu0U</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>815960846</pqid></control><display><type>article</type><title>Redox-Induced Palladium Migrations that Allow Reversible Topological Changes between Palladium(II) Complexes of Möbius Aromatic [28]Hexaphyrin and Hückel Aromatic [26]Hexaphyrin</title><source>MEDLINE</source><source>Wiley Online Library Journals Frontfile Complete</source><creator>Inoue, Mitsunori ; Osuka, Atsuhiro</creator><creatorcontrib>Inoue, Mitsunori ; Osuka, Atsuhiro</creatorcontrib><description>Plane twisted: A twisted Möbius aromatic [28]hexaphyrin/PdII complex and a planar Hückel aromatic [26]hexaphyrin/PdII complex are reversibly interconvertible by an unprecedented palladium migration through oxidation and reduction (see scheme). The [26]hexaphyrin/PdII complex is a precursor to [26]hexaphyrin hetero‐bis(metal) complexes having PdII/CuIII or PdII/AgIII centers. C gray, N blue, H white, F green, Pd yellow.</description><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.201005334</identifier><identifier>PMID: 21031391</identifier><language>eng</language><publisher>Weinheim: Wiley-VCH Verlag</publisher><subject>aromaticity ; Crystallography, X-Ray ; hexaphyrins ; metalation ; Metalloporphyrins - chemistry ; Models, Molecular ; Molecular Conformation ; Oxidation-Reduction ; palladium ; Palladium - chemistry ; porphyrinoids</subject><ispartof>Angewandte Chemie (International ed.), 2010-12, Vol.49 (49), p.9488-9491</ispartof><rights>Copyright © 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4064-383705a544913356ccb3628f734ceed41fbd4eec82382428ec2d42ea0ed27fbc3</citedby><cites>FETCH-LOGICAL-c4064-383705a544913356ccb3628f734ceed41fbd4eec82382428ec2d42ea0ed27fbc3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fanie.201005334$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fanie.201005334$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27903,27904,45553,45554</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/21031391$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Inoue, Mitsunori</creatorcontrib><creatorcontrib>Osuka, Atsuhiro</creatorcontrib><title>Redox-Induced Palladium Migrations that Allow Reversible Topological Changes between Palladium(II) Complexes of Möbius Aromatic [28]Hexaphyrin and Hückel Aromatic [26]Hexaphyrin</title><title>Angewandte Chemie (International ed.)</title><addtitle>Angew. Chem. Int. Ed</addtitle><description>Plane twisted: A twisted Möbius aromatic [28]hexaphyrin/PdII complex and a planar Hückel aromatic [26]hexaphyrin/PdII complex are reversibly interconvertible by an unprecedented palladium migration through oxidation and reduction (see scheme). The [26]hexaphyrin/PdII complex is a precursor to [26]hexaphyrin hetero‐bis(metal) complexes having PdII/CuIII or PdII/AgIII centers. C gray, N blue, H white, F green, Pd yellow.</description><subject>aromaticity</subject><subject>Crystallography, X-Ray</subject><subject>hexaphyrins</subject><subject>metalation</subject><subject>Metalloporphyrins - chemistry</subject><subject>Models, Molecular</subject><subject>Molecular Conformation</subject><subject>Oxidation-Reduction</subject><subject>palladium</subject><subject>Palladium - chemistry</subject><subject>porphyrinoids</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkU9v0zAYhyMEYmNw5Qi-AYcU_0viHKsy1krbQGMbSAhZjvOm9ebExU5o-7mQOHHbF8NTx-gNvYf3lfz8Hsn6JclzgkcEY_pWdQZGFMc7Y4w_SPZJRknKioI9jDdnLC1ERvaSJyFcRV4InD9O9ijBjLCS7Cc_z6B263TW1YOGGn1U1qraDC06MXOveuO6gPqF6tHYWrdCZ_ADfDCVBXTuls66udHKoslCdXMIqIJ-BdD907yezd6giWuXFtbx3TXo5OZXZYaAxt610a_RVyq-TWGtlouNNx1SXY2mN7_1NdhdJt9hniaPGmUDPLvbB8nF-8PzyTQ9_nA0m4yPU81xzlMmWIEzlXFeEsayXOuK5VQ0BeMaoOakqWoOoAVlgnIqQNOaU1AYalo0lWYHyautd-nd9wFCL1sTNMSvdeCGIAXJyhwLnkdytCW1dyF4aOTSm1b5jSRY3vYkb3uS9z3FwIs79VC1UN_jf4uJQLkFVsbC5j86OT6dHe7K023WhB7W91nlr2VesCKTn0-PJC4uL9-VX0qJI_9yyzfKSTX3JsiLT1HHMCnj4Jz9AUwBu0U</recordid><startdate>20101203</startdate><enddate>20101203</enddate><creator>Inoue, Mitsunori</creator><creator>Osuka, Atsuhiro</creator><general>Wiley-VCH Verlag</general><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><scope>FBQ</scope><scope>BSCLL</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20101203</creationdate><title>Redox-Induced Palladium Migrations that Allow Reversible Topological Changes between Palladium(II) Complexes of Möbius Aromatic [28]Hexaphyrin and Hückel Aromatic [26]Hexaphyrin</title><author>Inoue, Mitsunori ; Osuka, Atsuhiro</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4064-383705a544913356ccb3628f734ceed41fbd4eec82382428ec2d42ea0ed27fbc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>aromaticity</topic><topic>Crystallography, X-Ray</topic><topic>hexaphyrins</topic><topic>metalation</topic><topic>Metalloporphyrins - chemistry</topic><topic>Models, Molecular</topic><topic>Molecular Conformation</topic><topic>Oxidation-Reduction</topic><topic>palladium</topic><topic>Palladium - chemistry</topic><topic>porphyrinoids</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Inoue, Mitsunori</creatorcontrib><creatorcontrib>Osuka, Atsuhiro</creatorcontrib><collection>AGRIS</collection><collection>Istex</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Angewandte Chemie (International ed.)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Inoue, Mitsunori</au><au>Osuka, Atsuhiro</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Redox-Induced Palladium Migrations that Allow Reversible Topological Changes between Palladium(II) Complexes of Möbius Aromatic [28]Hexaphyrin and Hückel Aromatic [26]Hexaphyrin</atitle><jtitle>Angewandte Chemie (International ed.)</jtitle><addtitle>Angew. Chem. Int. Ed</addtitle><date>2010-12-03</date><risdate>2010</risdate><volume>49</volume><issue>49</issue><spage>9488</spage><epage>9491</epage><pages>9488-9491</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><abstract>Plane twisted: A twisted Möbius aromatic [28]hexaphyrin/PdII complex and a planar Hückel aromatic [26]hexaphyrin/PdII complex are reversibly interconvertible by an unprecedented palladium migration through oxidation and reduction (see scheme). The [26]hexaphyrin/PdII complex is a precursor to [26]hexaphyrin hetero‐bis(metal) complexes having PdII/CuIII or PdII/AgIII centers. C gray, N blue, H white, F green, Pd yellow.</abstract><cop>Weinheim</cop><pub>Wiley-VCH Verlag</pub><pmid>21031391</pmid><doi>10.1002/anie.201005334</doi><tpages>4</tpages></addata></record>
fulltext	fulltext
identifier	ISSN: 1433-7851
ispartof	Angewandte Chemie (International ed.), 2010-12, Vol.49 (49), p.9488-9491
issn	1433-7851 1521-3773
language	eng
recordid	cdi_proquest_miscellaneous_815960846
source	MEDLINE; Wiley Online Library Journals Frontfile Complete
subjects	aromaticity Crystallography, X-Ray hexaphyrins metalation Metalloporphyrins - chemistry Models, Molecular Molecular Conformation Oxidation-Reduction palladium Palladium - chemistry porphyrinoids
title	Redox-Induced Palladium Migrations that Allow Reversible Topological Changes between Palladium(II) Complexes of Möbius Aromatic [28]Hexaphyrin and Hückel Aromatic [26]Hexaphyrin
url	https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-22T07%3A54%3A47IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Redox-Induced%20Palladium%20Migrations%20that%20Allow%20Reversible%20Topological%20Changes%20between%20Palladium(II)%20Complexes%20of%20M%C3%B6bius%20Aromatic%20%5B28%5DHexaphyrin%20and%20H%C3%BCckel%20Aromatic%20%5B26%5DHexaphyrin&rft.jtitle=Angewandte%20Chemie%20(International%20ed.)&rft.au=Inoue,%20Mitsunori&rft.date=2010-12-03&rft.volume=49&rft.issue=49&rft.spage=9488&rft.epage=9491&rft.pages=9488-9491&rft.issn=1433-7851&rft.eissn=1521-3773&rft_id=info:doi/10.1002/anie.201005334&rft_dat=%3Cproquest_cross%3E815960846%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=815960846&rft_id=info:pmid/21031391&rfr_iscdi=true