Selective Catalytic Oxidation of Glycerol to Dihydroxyacetone
High selectivity and high yield characterize the oxidation of glycerol into dihydroxyacetone using catalyst 1, with benzoquinone or air as the oxidant. The mechanism proposed involves reversible palladium‐alkoxide formation with the turnover‐limiting reoxidation of the palladium complex.
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| Veröffentlicht in: | Angewandte Chemie (International ed.) 2010-12, Vol.49 (49), p.9456-9459 |
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| container_end_page | 9459 |
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| container_issue | 49 |
| container_start_page | 9456 |
| container_title | Angewandte Chemie (International ed.) |
| container_volume | 49 |
| creator | Painter, Ron M Pearson, David M Waymouth, Robert M |
| description | High selectivity and high yield characterize the oxidation of glycerol into dihydroxyacetone using catalyst 1, with benzoquinone or air as the oxidant. The mechanism proposed involves reversible palladium‐alkoxide formation with the turnover‐limiting reoxidation of the palladium complex. |
| doi_str_mv | 10.1002/anie.201004063 |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 1433-7851 |
| ispartof | Angewandte Chemie (International ed.), 2010-12, Vol.49 (49), p.9456-9459 |
| issn | 1433-7851 1521-3773 |
| language | eng |
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| source | MEDLINE; Wiley Journals |
| subjects | Acetonitriles - chemistry alcohols Benzoquinones - chemistry biomass Catalysis chemoselectivity Dihydroxyacetone - chemical synthesis Dihydroxyacetone - chemistry Glycerol - chemistry Molecular Structure Organometallic Compounds - chemistry oxidation Oxidation-Reduction Oxygen - chemistry palladium Palladium - chemistry |
| title | Selective Catalytic Oxidation of Glycerol to Dihydroxyacetone |
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