Phosphine-catalyzed asymmetric additions of malonate esters to {gamma}-substituted allenoates and allenamides

Because carbonyl groups are ubiquitous in organic chemistry, the ability to synthesize functionalized carbonyl compounds, particularly enantioselectively, is an important objective. We have developed a straightforward and versatile method for catalytic asymmetric carbon-carbon bond formation at the...

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Veröffentlicht in:	Proceedings of the National Academy of Sciences - PNAS 2010-11, Vol.107 (48), p.20652-20654
Hauptverfasser:	Sinisi, Riccardo, Sun, Jianwei, Fu, Gregory C
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbon Catalysis Catalysts Chemical bonds Organic chemistry
Online-Zugang:	Volltext
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