Strong donor-acceptor couplings in a special pair-antenna model

Strong donor-acceptor couplings in a special pair-antenna model

A special pair model composed of two cofacial zinc porphyrins (acceptor) linked to a free base (donor) acts as an energy transfer dyad. Despite the absence of conjugation, ππ*/charge transfer excited states and ultrafast energy transfer (∼5 ps) are noted.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2010-12, Vol.46 (48), p.9176-9178
Hauptverfasser: Filatov, Mikhail A, Laquai, Frédéric, Fortin, Daniel, Guilard, Roger, Harvey, Pierre D
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container_issue 48
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container_title Chemical communications (Cambridge, England)
container_volume 46
creator Filatov, Mikhail A
Laquai, Frédéric
Fortin, Daniel
Guilard, Roger
Harvey, Pierre D
description A special pair model composed of two cofacial zinc porphyrins (acceptor) linked to a free base (donor) acts as an energy transfer dyad. Despite the absence of conjugation, ππ*/charge transfer excited states and ultrafast energy transfer (∼5 ps) are noted.
doi_str_mv 10.1039/c0cc03665j
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title Strong donor-acceptor couplings in a special pair-antenna model
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