Topologies of metal-organic frameworks based on pyrimidine-5-carboxylate and unexpected gas-sorption selectivity for CO(2)
A simple and multitopic ligand, pyrimidine-5-carboxylate (pmc), has been used to obtain a series of metal-organic frameworks (MOFs) based on Co(2+), Cd(2+), and Cu(2+). The networks possess well-defined topologies of body-centered-cubic, rutile, and interpenetrated NbO structures, respectively. Amon...
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| Veröffentlicht in: | Inorganic chemistry 2010-12, Vol.49 (23), p.10833-10839 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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