Characterization of subsurface polycyclic aromatic hydrocarbons at the Deepwater Horizon site
Here, we report the initial observations of distributions of polycyclic aromatic hydrocarbons (PAH) in subsurface waters near the Deepwater Horizon oil well site (also referred to as the Macondo, Mississippi Canyon Block 252 or MC252 well). Profiles of in situ fluorescence and beam attenuation condu...
Gespeichert in:
Veröffentlicht in: | Geophysical research letters 2010-10, Vol.37 (20), p.n/a |
---|---|
Hauptverfasser: | , , , , , , , , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | n/a |
---|---|
container_issue | 20 |
container_start_page | |
container_title | Geophysical research letters |
container_volume | 37 |
creator | Diercks, Arne-R. Highsmith, Raymond C. Asper, Vernon L. Joung, DongJoo Zhou, Zhengzhen Guo, Laodong Shiller, Alan M. Joye, Samantha B. Teske, Andreas P. Guinasso, Norman Wade, Terry L. Lohrenz, Steven E. |
description | Here, we report the initial observations of distributions of polycyclic aromatic hydrocarbons (PAH) in subsurface waters near the Deepwater Horizon oil well site (also referred to as the Macondo, Mississippi Canyon Block 252 or MC252 well). Profiles of in situ fluorescence and beam attenuation conducted during 9‐16 May 2010 were characterized by distinct peaks at depths greater than 1000 m, with highest intensities close to the wellhead and decreasing intensities with increasing distance from the wellhead. Gas chromatography/mass spectrometry (GC/MS) analyses of water samples coinciding with the deep fluorescence and beam attenuation anomalies confirmed the presence of polycyclic aromatic hydrocarbons (PAH) at concentrations reaching 189 μg L−1 (ppb). Subsurface exposure to PAH at levels considered to be toxic to marine organisms would have occurred in discrete depth layers between 1000 and 1400 m in the region southwest of the wellhead site and extending at least as far as 13 km. |
doi_str_mv | 10.1029/2010GL045046 |
format | Article |
fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_815539711</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>815539711</sourcerecordid><originalsourceid>FETCH-LOGICAL-c4778-8064db01a913f3e00790698b0ff0850fbee9c5023635698f23f14f6b5cbb0b443</originalsourceid><addsrcrecordid>eNp9kU9rFDEYh4MouFZvfoCAiB5cffN_cpStboVFi614kpCkCZs6O1mTGer46c2ypYiHnhLC83vyexOEnhN4S4DqdxQIrDfABXD5AC2I5nzZAaiHaAGg254q-Rg9qfUaABgwskA_VltbrB9DSX_smPKAc8R1cnUq0fqA97mf_ez75LEtedcQj7fzVcneFpeHiu2Ix23ApyHsb2zT4LPcVM1T0xieokfR9jU8u11P0LePHy5XZ8vNl_Wn1fvN0nOlutZR8isHxGrCIgutsQapOwcxQicguhC0F0CZZKKdR8oi4VE64Z0Dxzk7Qa-O3n3Jv6ZQR7NL1Ye-t0PIUzUdEYJpRUgjX99LEqmIYITTA_riP_Q6T2Voc5j22kwJouBw9Zsj5UuutYRo9iXtbJkbdOC0-fdXGv7yVmqrt30sdvCp3mUoE1pJ1jWOHrmb1If5XqdZf91QxfUhtDyGUh3D77uQLT-NVK2w-f55bS5Pyfn5hZLmgv0FoOmouA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1023751704</pqid></control><display><type>article</type><title>Characterization of subsurface polycyclic aromatic hydrocarbons at the Deepwater Horizon site</title><source>Wiley Free Content</source><source>Wiley Online Library - AutoHoldings Journals</source><source>Wiley-Blackwell AGU Digital Library</source><source>EZB-FREE-00999 freely available EZB journals</source><creator>Diercks, Arne-R. ; Highsmith, Raymond C. ; Asper, Vernon L. ; Joung, DongJoo ; Zhou, Zhengzhen ; Guo, Laodong ; Shiller, Alan M. ; Joye, Samantha B. ; Teske, Andreas P. ; Guinasso, Norman ; Wade, Terry L. ; Lohrenz, Steven E.</creator><creatorcontrib>Diercks, Arne-R. ; Highsmith, Raymond C. ; Asper, Vernon L. ; Joung, DongJoo ; Zhou, Zhengzhen ; Guo, Laodong ; Shiller, Alan M. ; Joye, Samantha B. ; Teske, Andreas P. ; Guinasso, Norman ; Wade, Terry L. ; Lohrenz, Steven E.</creatorcontrib><description>Here, we report the initial observations of distributions of polycyclic aromatic hydrocarbons (PAH) in subsurface waters near the Deepwater Horizon oil well site (also referred to as the Macondo, Mississippi Canyon Block 252 or MC252 well). Profiles of in situ fluorescence and beam attenuation conducted during 9‐16 May 2010 were characterized by distinct peaks at depths greater than 1000 m, with highest intensities close to the wellhead and decreasing intensities with increasing distance from the wellhead. Gas chromatography/mass spectrometry (GC/MS) analyses of water samples coinciding with the deep fluorescence and beam attenuation anomalies confirmed the presence of polycyclic aromatic hydrocarbons (PAH) at concentrations reaching 189 μg L−1 (ppb). Subsurface exposure to PAH at levels considered to be toxic to marine organisms would have occurred in discrete depth layers between 1000 and 1400 m in the region southwest of the wellhead site and extending at least as far as 13 km.</description><identifier>ISSN: 0094-8276</identifier><identifier>EISSN: 1944-8007</identifier><identifier>DOI: 10.1029/2010GL045046</identifier><identifier>CODEN: GPRLAJ</identifier><language>eng</language><publisher>Washington, DC: Blackwell Publishing Ltd</publisher><subject>Attenuation ; beam attenuation ; Beams (structural) ; Canyons ; CDOM fluorescence ; Deepwater Horizon ; Earth sciences ; Earth, ocean, space ; Exact sciences and technology ; Fluorescence ; Gas chromatography ; Geobiology ; Geophysics ; Horizon ; Marine organisms ; Marine pollution ; Mass spectrometry ; Oceanography ; oil spill ; Polyallylamine hydrochloride ; Polycyclic aromatic hydrocarbons ; Water analysis ; Water sampling ; Wellheads</subject><ispartof>Geophysical research letters, 2010-10, Vol.37 (20), p.n/a</ispartof><rights>Copyright 2010 by the American Geophysical Union.</rights><rights>2015 INIST-CNRS</rights><rights>Copyright 2010 by American Geophysical Union</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4778-8064db01a913f3e00790698b0ff0850fbee9c5023635698f23f14f6b5cbb0b443</citedby><cites>FETCH-LOGICAL-c4778-8064db01a913f3e00790698b0ff0850fbee9c5023635698f23f14f6b5cbb0b443</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1029%2F2010GL045046$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1029%2F2010GL045046$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,1427,11493,27901,27902,45550,45551,46384,46443,46808,46867</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=23597638$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Diercks, Arne-R.</creatorcontrib><creatorcontrib>Highsmith, Raymond C.</creatorcontrib><creatorcontrib>Asper, Vernon L.</creatorcontrib><creatorcontrib>Joung, DongJoo</creatorcontrib><creatorcontrib>Zhou, Zhengzhen</creatorcontrib><creatorcontrib>Guo, Laodong</creatorcontrib><creatorcontrib>Shiller, Alan M.</creatorcontrib><creatorcontrib>Joye, Samantha B.</creatorcontrib><creatorcontrib>Teske, Andreas P.</creatorcontrib><creatorcontrib>Guinasso, Norman</creatorcontrib><creatorcontrib>Wade, Terry L.</creatorcontrib><creatorcontrib>Lohrenz, Steven E.</creatorcontrib><title>Characterization of subsurface polycyclic aromatic hydrocarbons at the Deepwater Horizon site</title><title>Geophysical research letters</title><addtitle>Geophys. Res. Lett</addtitle><description>Here, we report the initial observations of distributions of polycyclic aromatic hydrocarbons (PAH) in subsurface waters near the Deepwater Horizon oil well site (also referred to as the Macondo, Mississippi Canyon Block 252 or MC252 well). Profiles of in situ fluorescence and beam attenuation conducted during 9‐16 May 2010 were characterized by distinct peaks at depths greater than 1000 m, with highest intensities close to the wellhead and decreasing intensities with increasing distance from the wellhead. Gas chromatography/mass spectrometry (GC/MS) analyses of water samples coinciding with the deep fluorescence and beam attenuation anomalies confirmed the presence of polycyclic aromatic hydrocarbons (PAH) at concentrations reaching 189 μg L−1 (ppb). Subsurface exposure to PAH at levels considered to be toxic to marine organisms would have occurred in discrete depth layers between 1000 and 1400 m in the region southwest of the wellhead site and extending at least as far as 13 km.</description><subject>Attenuation</subject><subject>beam attenuation</subject><subject>Beams (structural)</subject><subject>Canyons</subject><subject>CDOM fluorescence</subject><subject>Deepwater Horizon</subject><subject>Earth sciences</subject><subject>Earth, ocean, space</subject><subject>Exact sciences and technology</subject><subject>Fluorescence</subject><subject>Gas chromatography</subject><subject>Geobiology</subject><subject>Geophysics</subject><subject>Horizon</subject><subject>Marine organisms</subject><subject>Marine pollution</subject><subject>Mass spectrometry</subject><subject>Oceanography</subject><subject>oil spill</subject><subject>Polyallylamine hydrochloride</subject><subject>Polycyclic aromatic hydrocarbons</subject><subject>Water analysis</subject><subject>Water sampling</subject><subject>Wellheads</subject><issn>0094-8276</issn><issn>1944-8007</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><sourceid>8G5</sourceid><sourceid>BENPR</sourceid><sourceid>GUQSH</sourceid><sourceid>M2O</sourceid><recordid>eNp9kU9rFDEYh4MouFZvfoCAiB5cffN_cpStboVFi614kpCkCZs6O1mTGer46c2ypYiHnhLC83vyexOEnhN4S4DqdxQIrDfABXD5AC2I5nzZAaiHaAGg254q-Rg9qfUaABgwskA_VltbrB9DSX_smPKAc8R1cnUq0fqA97mf_ez75LEtedcQj7fzVcneFpeHiu2Ix23ApyHsb2zT4LPcVM1T0xieokfR9jU8u11P0LePHy5XZ8vNl_Wn1fvN0nOlutZR8isHxGrCIgutsQapOwcxQicguhC0F0CZZKKdR8oi4VE64Z0Dxzk7Qa-O3n3Jv6ZQR7NL1Ye-t0PIUzUdEYJpRUgjX99LEqmIYITTA_riP_Q6T2Voc5j22kwJouBw9Zsj5UuutYRo9iXtbJkbdOC0-fdXGv7yVmqrt30sdvCp3mUoE1pJ1jWOHrmb1If5XqdZf91QxfUhtDyGUh3D77uQLT-NVK2w-f55bS5Pyfn5hZLmgv0FoOmouA</recordid><startdate>201010</startdate><enddate>201010</enddate><creator>Diercks, Arne-R.</creator><creator>Highsmith, Raymond C.</creator><creator>Asper, Vernon L.</creator><creator>Joung, DongJoo</creator><creator>Zhou, Zhengzhen</creator><creator>Guo, Laodong</creator><creator>Shiller, Alan M.</creator><creator>Joye, Samantha B.</creator><creator>Teske, Andreas P.</creator><creator>Guinasso, Norman</creator><creator>Wade, Terry L.</creator><creator>Lohrenz, Steven E.</creator><general>Blackwell Publishing Ltd</general><general>American Geophysical Union</general><general>John Wiley & Sons, Inc</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7TG</scope><scope>7TN</scope><scope>7XB</scope><scope>88I</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>8G5</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>ARAPS</scope><scope>ATCPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>BHPHI</scope><scope>BKSAR</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>F1W</scope><scope>FR3</scope><scope>GNUQQ</scope><scope>GUQSH</scope><scope>H8D</scope><scope>H96</scope><scope>HCIFZ</scope><scope>KL.</scope><scope>KR7</scope><scope>L.G</scope><scope>L6V</scope><scope>L7M</scope><scope>M2O</scope><scope>M2P</scope><scope>M7S</scope><scope>MBDVC</scope><scope>P5Z</scope><scope>P62</scope><scope>PATMY</scope><scope>PCBAR</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PTHSS</scope><scope>PYCSY</scope><scope>Q9U</scope><scope>7SM</scope></search><sort><creationdate>201010</creationdate><title>Characterization of subsurface polycyclic aromatic hydrocarbons at the Deepwater Horizon site</title><author>Diercks, Arne-R. ; Highsmith, Raymond C. ; Asper, Vernon L. ; Joung, DongJoo ; Zhou, Zhengzhen ; Guo, Laodong ; Shiller, Alan M. ; Joye, Samantha B. ; Teske, Andreas P. ; Guinasso, Norman ; Wade, Terry L. ; Lohrenz, Steven E.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4778-8064db01a913f3e00790698b0ff0850fbee9c5023635698f23f14f6b5cbb0b443</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Attenuation</topic><topic>beam attenuation</topic><topic>Beams (structural)</topic><topic>Canyons</topic><topic>CDOM fluorescence</topic><topic>Deepwater Horizon</topic><topic>Earth sciences</topic><topic>Earth, ocean, space</topic><topic>Exact sciences and technology</topic><topic>Fluorescence</topic><topic>Gas chromatography</topic><topic>Geobiology</topic><topic>Geophysics</topic><topic>Horizon</topic><topic>Marine organisms</topic><topic>Marine pollution</topic><topic>Mass spectrometry</topic><topic>Oceanography</topic><topic>oil spill</topic><topic>Polyallylamine hydrochloride</topic><topic>Polycyclic aromatic hydrocarbons</topic><topic>Water analysis</topic><topic>Water sampling</topic><topic>Wellheads</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Diercks, Arne-R.</creatorcontrib><creatorcontrib>Highsmith, Raymond C.</creatorcontrib><creatorcontrib>Asper, Vernon L.</creatorcontrib><creatorcontrib>Joung, DongJoo</creatorcontrib><creatorcontrib>Zhou, Zhengzhen</creatorcontrib><creatorcontrib>Guo, Laodong</creatorcontrib><creatorcontrib>Shiller, Alan M.</creatorcontrib><creatorcontrib>Joye, Samantha B.</creatorcontrib><creatorcontrib>Teske, Andreas P.</creatorcontrib><creatorcontrib>Guinasso, Norman</creatorcontrib><creatorcontrib>Wade, Terry L.</creatorcontrib><creatorcontrib>Lohrenz, Steven E.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Meteorological & Geoastrophysical Abstracts</collection><collection>Oceanic Abstracts</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Research Library (Alumni Edition)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest One Sustainability</collection><collection>ProQuest Central UK/Ireland</collection><collection>Advanced Technologies & Aerospace Collection</collection><collection>Agricultural & Environmental Science Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>Natural Science Collection</collection><collection>Earth, Atmospheric & Aquatic Science Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>Engineering Research Database</collection><collection>ProQuest Central Student</collection><collection>Research Library Prep</collection><collection>Aerospace Database</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 2: Ocean Technology, Policy & Non-Living Resources</collection><collection>SciTech Premium Collection</collection><collection>Meteorological & Geoastrophysical Abstracts - Academic</collection><collection>Civil Engineering Abstracts</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><collection>ProQuest Engineering Collection</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Research Library</collection><collection>Science Database</collection><collection>Engineering Database</collection><collection>Research Library (Corporate)</collection><collection>Advanced Technologies & Aerospace Database</collection><collection>ProQuest Advanced Technologies & Aerospace Collection</collection><collection>Environmental Science Database</collection><collection>Earth, Atmospheric & Aquatic Science Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>Engineering Collection</collection><collection>Environmental Science Collection</collection><collection>ProQuest Central Basic</collection><collection>Earthquake Engineering Abstracts</collection><jtitle>Geophysical research letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Diercks, Arne-R.</au><au>Highsmith, Raymond C.</au><au>Asper, Vernon L.</au><au>Joung, DongJoo</au><au>Zhou, Zhengzhen</au><au>Guo, Laodong</au><au>Shiller, Alan M.</au><au>Joye, Samantha B.</au><au>Teske, Andreas P.</au><au>Guinasso, Norman</au><au>Wade, Terry L.</au><au>Lohrenz, Steven E.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Characterization of subsurface polycyclic aromatic hydrocarbons at the Deepwater Horizon site</atitle><jtitle>Geophysical research letters</jtitle><addtitle>Geophys. Res. Lett</addtitle><date>2010-10</date><risdate>2010</risdate><volume>37</volume><issue>20</issue><epage>n/a</epage><issn>0094-8276</issn><eissn>1944-8007</eissn><coden>GPRLAJ</coden><abstract>Here, we report the initial observations of distributions of polycyclic aromatic hydrocarbons (PAH) in subsurface waters near the Deepwater Horizon oil well site (also referred to as the Macondo, Mississippi Canyon Block 252 or MC252 well). Profiles of in situ fluorescence and beam attenuation conducted during 9‐16 May 2010 were characterized by distinct peaks at depths greater than 1000 m, with highest intensities close to the wellhead and decreasing intensities with increasing distance from the wellhead. Gas chromatography/mass spectrometry (GC/MS) analyses of water samples coinciding with the deep fluorescence and beam attenuation anomalies confirmed the presence of polycyclic aromatic hydrocarbons (PAH) at concentrations reaching 189 μg L−1 (ppb). Subsurface exposure to PAH at levels considered to be toxic to marine organisms would have occurred in discrete depth layers between 1000 and 1400 m in the region southwest of the wellhead site and extending at least as far as 13 km.</abstract><cop>Washington, DC</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1029/2010GL045046</doi><tpages>6</tpages><oa>free_for_read</oa></addata></record> |
fulltext | fulltext |
identifier | ISSN: 0094-8276 |
ispartof | Geophysical research letters, 2010-10, Vol.37 (20), p.n/a |
issn | 0094-8276 1944-8007 |
language | eng |
recordid | cdi_proquest_miscellaneous_815539711 |
source | Wiley Free Content; Wiley Online Library - AutoHoldings Journals; Wiley-Blackwell AGU Digital Library; EZB-FREE-00999 freely available EZB journals |
subjects | Attenuation beam attenuation Beams (structural) Canyons CDOM fluorescence Deepwater Horizon Earth sciences Earth, ocean, space Exact sciences and technology Fluorescence Gas chromatography Geobiology Geophysics Horizon Marine organisms Marine pollution Mass spectrometry Oceanography oil spill Polyallylamine hydrochloride Polycyclic aromatic hydrocarbons Water analysis Water sampling Wellheads |
title | Characterization of subsurface polycyclic aromatic hydrocarbons at the Deepwater Horizon site |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-31T18%3A29%3A42IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Characterization%20of%20subsurface%20polycyclic%20aromatic%20hydrocarbons%20at%20the%20Deepwater%20Horizon%20site&rft.jtitle=Geophysical%20research%20letters&rft.au=Diercks,%20Arne-R.&rft.date=2010-10&rft.volume=37&rft.issue=20&rft.epage=n/a&rft.issn=0094-8276&rft.eissn=1944-8007&rft.coden=GPRLAJ&rft_id=info:doi/10.1029/2010GL045046&rft_dat=%3Cproquest_cross%3E815539711%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1023751704&rft_id=info:pmid/&rfr_iscdi=true |