Conformation and Packing of Porphyrin Polymer Chains Deposited Using Electrospray on a Gold Surface
Molecular worms: Porphyrin polymers and oligomers are deposited on a Au(111) surface using electrospray deposition and are shown to adopt an arrangement where chains from neighboring molecules are interdigitated. Although the flexible nature of the polymers gives rise to sharp kinks and the crossing...
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| Veröffentlicht in: | Angewandte Chemie (International ed.) 2010-11, Vol.49 (48), p.9136-9139 |
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| container_end_page | 9139 |
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| container_issue | 48 |
| container_start_page | 9136 |
| container_title | Angewandte Chemie (International ed.) |
| container_volume | 49 |
| creator | Saywell, Alex Sprafke, Johannes K Esdaile, Louisa J Britton, Andrew J Rienzo, Anna Anderson, Harry L O'Shea, James N Beton, Peter H |
| description | Molecular worms: Porphyrin polymers and oligomers are deposited on a Au(111) surface using electrospray deposition and are shown to adopt an arrangement where chains from neighboring molecules are interdigitated. Although the flexible nature of the polymers gives rise to sharp kinks and the crossing of polymer strands (see scheme), a longer correlation length as compared with solvated oligomers is observed. |
| doi_str_mv | 10.1002/anie.201004896 |
| format | Article |
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| identifier | ISSN: 1433-7851 |
| ispartof | Angewandte Chemie (International ed.), 2010-11, Vol.49 (48), p.9136-9139 |
| issn | 1433-7851 1521-3773 |
| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | electrospray deposition molecular electronics porphyrin polymers scanning probe microscopy X-ray adsorbtion spectroscopy |
| title | Conformation and Packing of Porphyrin Polymer Chains Deposited Using Electrospray on a Gold Surface |
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