Binding N2, N2H2, N2H4, and NH3 to Transition-Metal Sulfur Sites: Modeling Potential Intermediates of Biological N2 Fixation

In the quest for low‐molecular‐weight metal sulfur complexes that bind nitrogenase‐relevant small molecules and can serve as model complexes for nitrogenase, compounds with the [Ru(PiPr3)(‘N2Me2S2’)] fragment were found (‘N2Me2S2’2−=1,2‐ethanediamine‐N,N′‐dimethyl‐N,N′‐bis(2‐benzenethiolate)2−). Thi...

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Veröffentlicht in:	Chemistry : a European journal 2004-02, Vol.10 (4), p.819-830
Hauptverfasser:	Sellmann, Dieter, Hille, A., Rösler, A., Heinemann, F. W., Moll, M., Brehm, G., Schneider, S., Reiher, M., Hess, B. A., Bauer, W.
Format:	Artikel
Sprache:	eng
Schlagworte:	enzyme models nitrogen fixation ruthenium S ligands
Online-Zugang:	Volltext
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