Modelling catalytic turnover frequencies in ionic liquids: the determination of the bimolecular rate constant for solvent displacement from [(C6H6)Cr(CO)2Solv] in 1-n-butyl-3-methylimidazolium hexafluorophosphate

Modelling catalytic turnover frequencies in ionic liquids: the determination of the bimolecular rate constant for solvent displacement from [(C6H6)Cr(CO)2Solv] in 1-n-butyl-3-methylimidazolium hexafluorophosphate

The bimolecular rate constant for solvent displacement, k(2), from [(C(6)H(6))Cr(CO)(2)Solv] by an incoming ligand has been determined in the room temperature ionic liquid, [bmim][PF(6)], and is compared to that for the same process in cyclohexane and dichloroethane.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2004-03 (5), p.590-591
Hauptverfasser: Swiderski, Konrad, McLean, Andrew, Gordon, Charles M, Vaughan, D H
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creator Swiderski, Konrad
McLean, Andrew
Gordon, Charles M
Vaughan, D H
description The bimolecular rate constant for solvent displacement, k(2), from [(C(6)H(6))Cr(CO)(2)Solv] by an incoming ligand has been determined in the room temperature ionic liquid, [bmim][PF(6)], and is compared to that for the same process in cyclohexane and dichloroethane.
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title Modelling catalytic turnover frequencies in ionic liquids: the determination of the bimolecular rate constant for solvent displacement from [(C6H6)Cr(CO)2Solv] in 1-n-butyl-3-methylimidazolium hexafluorophosphate
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