Stereodivergent and Reiterative Synthesis of Bistetrahydrofuran Ring Cores of Annonaceous Acetogenins

Eight diastereoisomers of the bistetrahydrofuran ring cores of annonaceous acetogenins have been synthesized by asymmetric alkynylation of α‐tetrahydrofuranic aldehydes and stereodivergent one‐pot tetrahydrofuran (THF) ring formation. In all cases, the asymmetric alkynylation proceeded with very hig...

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Veröffentlicht in:	Chemistry : a European journal 2004-02, Vol.10 (3), p.672-680
Hauptverfasser:	Kojima, Naoto, Maezaki, Naoyoshi, Tominaga, Hiroaki, Yanai, Minori, Urabe, Daisuke, Tanaka, Tetsuaki
Format:	Artikel
Sprache:	eng
Schlagworte:	annonaceous acetogenins asymmetric alkynylation cyclization stereodivergent synthesis synthetic methods
Online-Zugang:	Volltext
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