Trans-diaryl epoxides: Asymmetric synthesis, ring-opening, and absolute configuration

Anthryl‐phenyl, phenanthryl‐phenyl, and naphthyl‐phenyl trans‐epoxides (1, 2, and 3, respectively) having enantiomeric purities of 95%, 99%, and 96% were synthesized from a diastereo and enantiopure sulfonium salt derived from Eliel's oxathiane. The determination of their (1R,2R) absolute confi...

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Veröffentlicht in:	Chirality (New York, N.Y.) N.Y.), 2004, Vol.16 (3), p.196-203
Hauptverfasser:	Solladié-Cavallo, A., Roje, M., Giraud-Roux, M., Chen, Y., Berova, N., Sunjic, V.
Format:	Artikel
Sprache:	eng
Schlagworte:	Amino Alcohols - chemical synthesis Amino Alcohols - chemistry aryl alcohols configurations epoxides Epoxy Compounds - chemical synthesis Epoxy Compounds - chemistry Methods Models, Molecular Nuclear Magnetic Resonance, Biomolecular Stereoisomerism tweezer CD exciton
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