The Circumambulation of a Phosphirane: Taking 9-Phenyl-9-phosphabicyclo[6.1.0]nona-2,4,6-triene for a "Walk"
Walking rings: At room temperature, the P‐R entity of a bicyclic phosphirane (see picture) “walks” along the perimeter of the larger ring. Although this concerted rearrangement is similar to that of its hydrocarbon analogue, the additional 1,5‐sigmatropic shift follows a different mechanism.
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| Veröffentlicht in: | Angewandte Chemie International Edition 2004-01, Vol.43 (6), p.714-717 |
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| container_end_page | 717 |
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| container_issue | 6 |
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| container_title | Angewandte Chemie International Edition |
| container_volume | 43 |
| creator | Bulo, Rosa E. Jansen, Helen Ehlers, Andreas W. de Kanter, Fransiscus J. J. Schakel, Marius Lutz, Martin Spek, Anthony L. Lammertsma, Koop |
| description | Walking rings: At room temperature, the P‐R entity of a bicyclic phosphirane (see picture) “walks” along the perimeter of the larger ring. Although this concerted rearrangement is similar to that of its hydrocarbon analogue, the additional 1,5‐sigmatropic shift follows a different mechanism. |
| doi_str_mv | 10.1002/anie.200351855 |
| format | Article |
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| identifier | ISSN: 1433-7851 |
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| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | density functional calculations phosphorus heterocycles sigmatropic rearrangement |
| title | The Circumambulation of a Phosphirane: Taking 9-Phenyl-9-phosphabicyclo[6.1.0]nona-2,4,6-triene for a "Walk" |
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