Design Aspects for the Development of Mixed-Metal Supramolecular Complexes Capable of Visible Light Induced Photocleavage of DNA

Mixed-metal supramolecular complexes that couple ruthenium or osmium based light absorbers to a central rhodium(III) core have been designed which photocleave DNA upon irradiation with visible light. The complexes [{(bpy)2Ru(dpp)}2RhCl2](PF6)5, [{(bpy)2Os(dpp)}2RhCl2](PF6)5, and [{(tpy)RuCl(dpp)}2Rh...

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Veröffentlicht in:	Inorganic chemistry 2004-01, Vol.43 (1), p.303-308
Hauptverfasser:	Holder, Alvin A, Swavey, Shawn, Brewer, Karen J
Format:	Artikel
Sprache:	eng
Schlagworte:	DNA - chemistry DNA - radiation effects Electrochemistry Hydrolysis Light Models, Molecular Photochemistry Spectrometry, Mass, Fast Atom Bombardment
Online-Zugang:	Volltext
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