Structural studies of an arabinoxylan isolated from Litsea glutinosa (Lauraceae)

A water-soluble arabinoxylan ( d-xylose and l-arabinose in the molar ratio 1.0:3.4) was isolated from the mucilaginous bark of Litsea glutinosa (Lauraceae). The results of methylation analysis, partial hydrolysis, and 1H- and 13C-n.m.r. spectroscopy indicated a backbone of (1→4)-linked β- d-xylopran...

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Veröffentlicht in:Carbohydrate research 1990-05, Vol.198 (2), p.343-351
Hauptverfasser: Herath, H.M.T.B., Kumar, N.Savitri, Wimalasiri, K.M.Swarna
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container_title Carbohydrate research
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creator Herath, H.M.T.B.
Kumar, N.Savitri
Wimalasiri, K.M.Swarna
description A water-soluble arabinoxylan ( d-xylose and l-arabinose in the molar ratio 1.0:3.4) was isolated from the mucilaginous bark of Litsea glutinosa (Lauraceae). The results of methylation analysis, partial hydrolysis, and 1H- and 13C-n.m.r. spectroscopy indicated a backbone of (1→4)-linked β- d-xylopranosyl residues substituted at both positions 2 and 3 with side chains composed of either single or (1→3)-linked arabinofuranosyl residues. Both α- l- and β- l-arabinofuranosyl residues were present. It is possible that side chains composed of two β- l-arabinofuranosyl residues are attached mainly at O-2 of some xylosyl residues.
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The results of methylation analysis, partial hydrolysis, and 1H- and 13C-n.m.r. spectroscopy indicated a backbone of (1→4)-linked β- d-xylopranosyl residues substituted at both positions 2 and 3 with side chains composed of either single or (1→3)-linked arabinofuranosyl residues. Both α- l- and β- l-arabinofuranosyl residues were present. It is possible that side chains composed of two β- l-arabinofuranosyl residues are attached mainly at O-2 of some xylosyl residues.</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><pmid>2379194</pmid><doi>10.1016/0008-6215(90)84304-D</doi><tpages>9</tpages></addata></record>
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subjects Analytical, structural and metabolic biochemistry
arabinose
Arabinose - analysis
bark
Biological and medical sciences
Carbohydrate Sequence
Carbohydrates
chemical analysis
Fundamental and applied biological sciences. Psychology
glycoproteins
Holosides
Hydrolysis
isolation
litsea glutinosa
Magnetic Resonance Spectroscopy
Methylation
Molecular Sequence Data
nuclear magnetic resonance spectroscopy
Other biological molecules
Polysaccharides
Solubility
spectral analysis
Trees
Xylans
xylose
Xylose - analysis
title Structural studies of an arabinoxylan isolated from Litsea glutinosa (Lauraceae)
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