Coordination behavior and antifungicidal, antibacterial, and antifertility activities of dioxomolybdenum(VI) complexes of biologically active heterocyclic benzothiazolines
Synthesis, characterization, and structural aspects of a new class of dioxomolybdenum(VI) complexes with biologically active benzothiazolines, 2-(2-pyridyl) benzothiazoline, 2-(2-thienyl) benzothiazoline, 2-(2-furyl) benzothiazoline, 2-(3-indolyl) benzothiazoline, glyoxal benzothiazoline, biacetylbe...
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| Veröffentlicht in: | Journal of inorganic biochemistry 1990, Vol.38 (1), p.57-67 |
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| creator | Kanoongo, Neeta Singh, R.V. Tandon, J.P. Goyal, Ravi Bala |
| description | Synthesis, characterization, and structural aspects of a new class of dioxomolybdenum(VI) complexes with biologically active benzothiazolines, 2-(2-pyridyl) benzothiazoline, 2-(2-thienyl) benzothiazoline, 2-(2-furyl) benzothiazoline, 2-(3-indolyl) benzothiazoline, glyoxal benzothiazoline, biacetylbenzothiazoline, benzil benzothiazoline, and terphthaldehyde benzothiazoline have been described. The newly synthesized complexes, [MoO
2(Bzt)
2] and [MoO
2(Bzt′)] (where BztH and Bzt′H
2 represent benzothazoline molecules) have been characterized by elemental analysis, conductance measurements, molecular weight determinations, and magnetic studies. Based on IR,
1H NMR,
13C NMR, and electronic spectral studies, distorted octahedral geometry with cis-MoO
2 group has been indicated for the resulting complexes. Two benzothiazolines and their corresponding metal complexes were screened for their antifungicidal and antibacterial activity on several fungi and bacteria and found to be quite active in this respect. In addition, antifertility activity of representative ligands and their molybdenum complexes was also evaluated and discussed in male mice. |
| doi_str_mv | 10.1016/0162-0134(90)85007-J |
| format | Article |
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2(Bzt)
2] and [MoO
2(Bzt′)] (where BztH and Bzt′H
2 represent benzothazoline molecules) have been characterized by elemental analysis, conductance measurements, molecular weight determinations, and magnetic studies. Based on IR,
1H NMR,
13C NMR, and electronic spectral studies, distorted octahedral geometry with cis-MoO
2 group has been indicated for the resulting complexes. Two benzothiazolines and their corresponding metal complexes were screened for their antifungicidal and antibacterial activity on several fungi and bacteria and found to be quite active in this respect. In addition, antifertility activity of representative ligands and their molybdenum complexes was also evaluated and discussed in male mice.</description><identifier>ISSN: 0162-0134</identifier><identifier>EISSN: 1873-3344</identifier><identifier>DOI: 10.1016/0162-0134(90)85007-J</identifier><identifier>PMID: 2332764</identifier><identifier>CODEN: JIBIDJ</identifier><language>eng</language><publisher>New York, NY: Elsevier Inc</publisher><subject>Animals ; Anti-Bacterial Agents ; Antifungal Agents ; Bioinorganic chemistry ; Chemical Phenomena ; Chemistry ; Exact sciences and technology ; Fertility - drug effects ; Inorganic chemistry and origins of life ; Magnetic Resonance Spectroscopy ; Male ; Mice ; Molecular Structure ; Molybdenum - pharmacology ; Organometallic Compounds - chemical synthesis ; Organometallic Compounds - pharmacology ; Spectrum Analysis ; Sperm Count ; Sperm Motility - drug effects ; Thiazoles - chemical synthesis ; Thiazoles - pharmacology</subject><ispartof>Journal of inorganic biochemistry, 1990, Vol.38 (1), p.57-67</ispartof><rights>1990</rights><rights>1990 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c386t-a98b15c136704f3c1897cbc1a9f02b92dd2b7be6be27dee8f816f97bb04fa3b3</citedby><cites>FETCH-LOGICAL-c386t-a98b15c136704f3c1897cbc1a9f02b92dd2b7be6be27dee8f816f97bb04fa3b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/016201349085007J$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,4010,27900,27901,27902,65534</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=6901998$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/2332764$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Kanoongo, Neeta</creatorcontrib><creatorcontrib>Singh, R.V.</creatorcontrib><creatorcontrib>Tandon, J.P.</creatorcontrib><creatorcontrib>Goyal, Ravi Bala</creatorcontrib><title>Coordination behavior and antifungicidal, antibacterial, and antifertility activities of dioxomolybdenum(VI) complexes of biologically active heterocyclic benzothiazolines</title><title>Journal of inorganic biochemistry</title><addtitle>J Inorg Biochem</addtitle><description>Synthesis, characterization, and structural aspects of a new class of dioxomolybdenum(VI) complexes with biologically active benzothiazolines, 2-(2-pyridyl) benzothiazoline, 2-(2-thienyl) benzothiazoline, 2-(2-furyl) benzothiazoline, 2-(3-indolyl) benzothiazoline, glyoxal benzothiazoline, biacetylbenzothiazoline, benzil benzothiazoline, and terphthaldehyde benzothiazoline have been described. The newly synthesized complexes, [MoO
2(Bzt)
2] and [MoO
2(Bzt′)] (where BztH and Bzt′H
2 represent benzothazoline molecules) have been characterized by elemental analysis, conductance measurements, molecular weight determinations, and magnetic studies. Based on IR,
1H NMR,
13C NMR, and electronic spectral studies, distorted octahedral geometry with cis-MoO
2 group has been indicated for the resulting complexes. Two benzothiazolines and their corresponding metal complexes were screened for their antifungicidal and antibacterial activity on several fungi and bacteria and found to be quite active in this respect. In addition, antifertility activity of representative ligands and their molybdenum complexes was also evaluated and discussed in male mice.</description><subject>Animals</subject><subject>Anti-Bacterial Agents</subject><subject>Antifungal Agents</subject><subject>Bioinorganic chemistry</subject><subject>Chemical Phenomena</subject><subject>Chemistry</subject><subject>Exact sciences and technology</subject><subject>Fertility - drug effects</subject><subject>Inorganic chemistry and origins of life</subject><subject>Magnetic Resonance Spectroscopy</subject><subject>Male</subject><subject>Mice</subject><subject>Molecular Structure</subject><subject>Molybdenum - pharmacology</subject><subject>Organometallic Compounds - chemical synthesis</subject><subject>Organometallic Compounds - pharmacology</subject><subject>Spectrum Analysis</subject><subject>Sperm Count</subject><subject>Sperm Motility - drug effects</subject><subject>Thiazoles - chemical synthesis</subject><subject>Thiazoles - pharmacology</subject><issn>0162-0134</issn><issn>1873-3344</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1990</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNp9kc9u1DAQxiMEKtvCG4CUA0KtRMCOs3F8QUKrAq0qcam4Wv4zYQc58WI7q25fiZfE20R75DAajb7ffBp9UxRvKPlICW0_5aorQllzKchVtyaEV7fPihXtOKsYa5rnxeqEvCzOY_xNCFmvG35WnNWM1bxtVsXfjffB4qgS-rHUsFV79KFUo82VsJ_GX2jQKvfhadbKJAg4jwsCIaHDdCizhntMCLH0fWnRP_jBu4O2ME7D5c-bq9L4YefgYQY0euezu3Ju2YVyC9nem4NxaPI146NPW1SP3uEI8VXxolcuwuulXxT3X6_vN9-rux_fbjZf7irDujZVSnSarg1lLSdNzwztBDfaUCV6UmtRW1trrqHVUHML0PUdbXvBtc60YppdFO9n213wfyaISQ4YDTinRvBTlFzwpqGMZ7CZQRN8jAF6uQs4qHCQlMjji-Qxf3nMXwoin14kb_Pa28V_0gPY09Lyk6y_W3QVczh9UKPBeMJaQagQXcY-zxjkKPYIQUaDMBqwGMAkaT3-_45_3vOzTA</recordid><startdate>1990</startdate><enddate>1990</enddate><creator>Kanoongo, Neeta</creator><creator>Singh, R.V.</creator><creator>Tandon, J.P.</creator><creator>Goyal, Ravi Bala</creator><general>Elsevier Inc</general><general>Elsevier Science</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>1990</creationdate><title>Coordination behavior and antifungicidal, antibacterial, and antifertility activities of dioxomolybdenum(VI) complexes of biologically active heterocyclic benzothiazolines</title><author>Kanoongo, Neeta ; Singh, R.V. ; Tandon, J.P. ; Goyal, Ravi Bala</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c386t-a98b15c136704f3c1897cbc1a9f02b92dd2b7be6be27dee8f816f97bb04fa3b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1990</creationdate><topic>Animals</topic><topic>Anti-Bacterial Agents</topic><topic>Antifungal Agents</topic><topic>Bioinorganic chemistry</topic><topic>Chemical Phenomena</topic><topic>Chemistry</topic><topic>Exact sciences and technology</topic><topic>Fertility - drug effects</topic><topic>Inorganic chemistry and origins of life</topic><topic>Magnetic Resonance Spectroscopy</topic><topic>Male</topic><topic>Mice</topic><topic>Molecular Structure</topic><topic>Molybdenum - pharmacology</topic><topic>Organometallic Compounds - chemical synthesis</topic><topic>Organometallic Compounds - pharmacology</topic><topic>Spectrum Analysis</topic><topic>Sperm Count</topic><topic>Sperm Motility - drug effects</topic><topic>Thiazoles - chemical synthesis</topic><topic>Thiazoles - pharmacology</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kanoongo, Neeta</creatorcontrib><creatorcontrib>Singh, R.V.</creatorcontrib><creatorcontrib>Tandon, J.P.</creatorcontrib><creatorcontrib>Goyal, Ravi Bala</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of inorganic biochemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kanoongo, Neeta</au><au>Singh, R.V.</au><au>Tandon, J.P.</au><au>Goyal, Ravi Bala</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Coordination behavior and antifungicidal, antibacterial, and antifertility activities of dioxomolybdenum(VI) complexes of biologically active heterocyclic benzothiazolines</atitle><jtitle>Journal of inorganic biochemistry</jtitle><addtitle>J Inorg Biochem</addtitle><date>1990</date><risdate>1990</risdate><volume>38</volume><issue>1</issue><spage>57</spage><epage>67</epage><pages>57-67</pages><issn>0162-0134</issn><eissn>1873-3344</eissn><coden>JIBIDJ</coden><abstract>Synthesis, characterization, and structural aspects of a new class of dioxomolybdenum(VI) complexes with biologically active benzothiazolines, 2-(2-pyridyl) benzothiazoline, 2-(2-thienyl) benzothiazoline, 2-(2-furyl) benzothiazoline, 2-(3-indolyl) benzothiazoline, glyoxal benzothiazoline, biacetylbenzothiazoline, benzil benzothiazoline, and terphthaldehyde benzothiazoline have been described. The newly synthesized complexes, [MoO
2(Bzt)
2] and [MoO
2(Bzt′)] (where BztH and Bzt′H
2 represent benzothazoline molecules) have been characterized by elemental analysis, conductance measurements, molecular weight determinations, and magnetic studies. Based on IR,
1H NMR,
13C NMR, and electronic spectral studies, distorted octahedral geometry with cis-MoO
2 group has been indicated for the resulting complexes. Two benzothiazolines and their corresponding metal complexes were screened for their antifungicidal and antibacterial activity on several fungi and bacteria and found to be quite active in this respect. In addition, antifertility activity of representative ligands and their molybdenum complexes was also evaluated and discussed in male mice.</abstract><cop>New York, NY</cop><pub>Elsevier Inc</pub><pmid>2332764</pmid><doi>10.1016/0162-0134(90)85007-J</doi><tpages>11</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0162-0134 |
| ispartof | Journal of inorganic biochemistry, 1990, Vol.38 (1), p.57-67 |
| issn | 0162-0134 1873-3344 |
| language | eng |
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| source | MEDLINE; Elsevier ScienceDirect Journals |
| subjects | Animals Anti-Bacterial Agents Antifungal Agents Bioinorganic chemistry Chemical Phenomena Chemistry Exact sciences and technology Fertility - drug effects Inorganic chemistry and origins of life Magnetic Resonance Spectroscopy Male Mice Molecular Structure Molybdenum - pharmacology Organometallic Compounds - chemical synthesis Organometallic Compounds - pharmacology Spectrum Analysis Sperm Count Sperm Motility - drug effects Thiazoles - chemical synthesis Thiazoles - pharmacology |
| title | Coordination behavior and antifungicidal, antibacterial, and antifertility activities of dioxomolybdenum(VI) complexes of biologically active heterocyclic benzothiazolines |
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