Evaluation of Carbodiimides Using a Competition Method

A competitive reaction of activated Boc‐Ala‐OH and Boc‐Phe‐OH with H‐Leu‐resin has been developed for assessing the relative efficiencies of different carbodiimides. This allowed a comparison of the efficiency of the carbodiimides N,N;′‐dicyclohexylcarbodiimide,N,N′‐diisopropylcarbodiimide, N‐tert‐b...

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Veröffentlicht in:	Journal of peptide science 1997-03, Vol.3 (2), p.141-144
Hauptverfasser:	Izdebski, Jan, Kunce, Danuta
Format:	Artikel
Sprache:	eng
Schlagworte:	Alanine - chemistry Aminoacylation Carbodiimides - chemistry Dicyclohexylcarbodiimide - chemistry Indicators and Reagents Leucine - chemistry mechanism of coupling N-tert-butyl-N′-ethylcarbodiimide N-tert-butyl-N′-methylcarbodiimide peptide coupling Peptides - chemical synthesis Peptides - chemistry Phenylalanine - chemistry Resins, Plant symmetrical anhydrides
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