Global Topology & Stability and Local Structure & Dynamics in a Synthetic Spin-Labeled Four-Helix Bundle Protein

A maleimide nitroxide spin-label (MAL-6) linked to a cysteine in the hydrophobic core and a coproporphyrin I (CP) appended on the N-terminus of a synthetic helix−loop−helix peptide ([α2]) have been used to examine the designed self-association of a four-helix bundle ([α2]2), focusing on the bundle t...

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