Synthesis, crystal growth, characterization and structure–NLO property relationship in 1,3-bis(4-methoxyphenyl)prop-2-en-1-one single crystal
High-quality single crystals of 1,3-bis(4-methoxyphenyl)prop-2-en-1-one (BMP) of size 20 mm×16 mm×5 mm have been grown by the slow evaporation of an acetone solution at 28 °C and characterized by elemental analysis, thermo-gravimetric analysis/differential thermal analysis (TGA/DTA), Fourier transfo...
Gespeichert in:
| Veröffentlicht in: | Journal of crystal growth 2009, Vol.311 (2), p.310-315 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 315 |
|---|---|
| container_issue | 2 |
| container_start_page | 310 |
| container_title | Journal of crystal growth |
| container_volume | 311 |
| creator | Ravindra, H.J. Harrison, W.T.A. Suresh Kumar, M.R. Dharmaprakash, S.M. |
| description | High-quality single crystals of 1,3-bis(4-methoxyphenyl)prop-2-en-1-one (BMP) of size 20
mm×16
mm×5
mm have been grown by the slow evaporation of an acetone solution at 28
°C and characterized by elemental analysis, thermo-gravimetric analysis/differential thermal analysis (TGA/DTA), Fourier transform infrared (FTIR) spectroscopy and single-crystal X-ray diffraction. BMP crystallizes in the orthorhombic system with the noncentrosymmetric space group P2
12
12
1. The crystal melts at 107
°C and the average Vickers hardness number is 17
kg
mm
−2. BMP crystals are transparent in the entire visible region and have a lower optical cutoff at 435
nm. A Kurtz powder second harmonic generation (PSHG) measurement indicated that BMP and urea have similar responses. The observed SHG response for BMP is due to effective charge transfer arising from the donor–
π-acceptor–
π-donor (
D–
π–
A–
π–
D) structure of the molecule and the weak C–H…
π interaction observed in the crystal structure, which helps to stack the molecules in a noncentrosymmetric arrangement. |
| doi_str_mv | 10.1016/j.jcrysgro.2008.10.092 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_787267555</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0022024808011901</els_id><sourcerecordid>33539504</sourcerecordid><originalsourceid>FETCH-LOGICAL-c405t-d4085234175ccbdc789d3c9f52e5d77d2b9cf5820a96f06ea0bb3adba51ad8ed3</originalsourceid><addsrcrecordid>eNqFkc1u1DAUhS0EEkPhFVA2_En14J84TnZFFbRII7oA1pZj3zQeZZxge6DpijdgwRv2SeowLUvY2PLVd8658kHoOSVrSmj1drvemjDHyzCuGSF1Hq5Jwx6gFa0lx4IQ9hCt8skwYWX9GD2JcUtIVlKyQr8-zz71EF08LhaXpIciO_1IfX73OmiTILhrndzoC-1tEVPYm7QPcPPz96fNRTGFcYKQ5iLA8IeKvZsK5wt6zHHr4usS7yD149U89eDn4c0iwAyDxxSPHoro_OUA9-FP0aNODxGe3d1H6OuH919Oz_Hm4uzj6bsNNiURCduS1ILxkkphTGuNrBvLTdMJBsJKaVnbmE7UjOim6kgFmrQt17bVgmpbg-VH6NXBN6_zbQ8xqZ2LBoZBexj3UclaskoKITL58p8k54I3gpQZrA6gCWOMATo1BbfTYVaUqKUptVX3TamlqWWem8rCF3cJOho9dEF74-JfNaO0FFzWmTs5cJA_5ruDoKJx4A1YF8AkZUf3v6hbbySxfg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>33539504</pqid></control><display><type>article</type><title>Synthesis, crystal growth, characterization and structure–NLO property relationship in 1,3-bis(4-methoxyphenyl)prop-2-en-1-one single crystal</title><source>ScienceDirect Journals (5 years ago - present)</source><creator>Ravindra, H.J. ; Harrison, W.T.A. ; Suresh Kumar, M.R. ; Dharmaprakash, S.M.</creator><creatorcontrib>Ravindra, H.J. ; Harrison, W.T.A. ; Suresh Kumar, M.R. ; Dharmaprakash, S.M.</creatorcontrib><description>High-quality single crystals of 1,3-bis(4-methoxyphenyl)prop-2-en-1-one (BMP) of size 20
mm×16
mm×5
mm have been grown by the slow evaporation of an acetone solution at 28
°C and characterized by elemental analysis, thermo-gravimetric analysis/differential thermal analysis (TGA/DTA), Fourier transform infrared (FTIR) spectroscopy and single-crystal X-ray diffraction. BMP crystallizes in the orthorhombic system with the noncentrosymmetric space group P2
12
12
1. The crystal melts at 107
°C and the average Vickers hardness number is 17
kg
mm
−2. BMP crystals are transparent in the entire visible region and have a lower optical cutoff at 435
nm. A Kurtz powder second harmonic generation (PSHG) measurement indicated that BMP and urea have similar responses. The observed SHG response for BMP is due to effective charge transfer arising from the donor–
π-acceptor–
π-donor (
D–
π–
A–
π–
D) structure of the molecule and the weak C–H…
π interaction observed in the crystal structure, which helps to stack the molecules in a noncentrosymmetric arrangement.</description><identifier>ISSN: 0022-0248</identifier><identifier>EISSN: 1873-5002</identifier><identifier>DOI: 10.1016/j.jcrysgro.2008.10.092</identifier><identifier>CODEN: JCRGAE</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>A1. Characterization ; A2. Growth from solution ; B1. Organic compound ; B2. Nonlinear optical material ; Charge transfer ; Condensed matter: electronic structure, electrical, magnetic, and optical properties ; Condensed matter: structure, mechanical and thermal properties ; Cross-disciplinary physics: materials science; rheology ; Crystal growth ; Crystals ; Deformation, plasticity, and creep ; Diamond pyramid hardness ; Differential thermal analysis ; Diffraction ; Evaporation ; Exact sciences and technology ; Growth from solutions ; Materials science ; Melts ; Methods of crystal growth; physics of crystal growth ; Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation ; Optical properties of bulk materials and thin films ; Physics ; Single crystals ; Structure of solids and liquids; crystallography ; Structure of specific crystalline solids ; Treatment of materials and its effects on microstructure and properties</subject><ispartof>Journal of crystal growth, 2009, Vol.311 (2), p.310-315</ispartof><rights>2008 Elsevier B.V.</rights><rights>2009 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c405t-d4085234175ccbdc789d3c9f52e5d77d2b9cf5820a96f06ea0bb3adba51ad8ed3</citedby><cites>FETCH-LOGICAL-c405t-d4085234175ccbdc789d3c9f52e5d77d2b9cf5820a96f06ea0bb3adba51ad8ed3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0022024808011901$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,4010,27902,27903,27904,65309</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=21145378$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Ravindra, H.J.</creatorcontrib><creatorcontrib>Harrison, W.T.A.</creatorcontrib><creatorcontrib>Suresh Kumar, M.R.</creatorcontrib><creatorcontrib>Dharmaprakash, S.M.</creatorcontrib><title>Synthesis, crystal growth, characterization and structure–NLO property relationship in 1,3-bis(4-methoxyphenyl)prop-2-en-1-one single crystal</title><title>Journal of crystal growth</title><description>High-quality single crystals of 1,3-bis(4-methoxyphenyl)prop-2-en-1-one (BMP) of size 20
mm×16
mm×5
mm have been grown by the slow evaporation of an acetone solution at 28
°C and characterized by elemental analysis, thermo-gravimetric analysis/differential thermal analysis (TGA/DTA), Fourier transform infrared (FTIR) spectroscopy and single-crystal X-ray diffraction. BMP crystallizes in the orthorhombic system with the noncentrosymmetric space group P2
12
12
1. The crystal melts at 107
°C and the average Vickers hardness number is 17
kg
mm
−2. BMP crystals are transparent in the entire visible region and have a lower optical cutoff at 435
nm. A Kurtz powder second harmonic generation (PSHG) measurement indicated that BMP and urea have similar responses. The observed SHG response for BMP is due to effective charge transfer arising from the donor–
π-acceptor–
π-donor (
D–
π–
A–
π–
D) structure of the molecule and the weak C–H…
π interaction observed in the crystal structure, which helps to stack the molecules in a noncentrosymmetric arrangement.</description><subject>A1. Characterization</subject><subject>A2. Growth from solution</subject><subject>B1. Organic compound</subject><subject>B2. Nonlinear optical material</subject><subject>Charge transfer</subject><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>Crystal growth</subject><subject>Crystals</subject><subject>Deformation, plasticity, and creep</subject><subject>Diamond pyramid hardness</subject><subject>Differential thermal analysis</subject><subject>Diffraction</subject><subject>Evaporation</subject><subject>Exact sciences and technology</subject><subject>Growth from solutions</subject><subject>Materials science</subject><subject>Melts</subject><subject>Methods of crystal growth; physics of crystal growth</subject><subject>Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation</subject><subject>Optical properties of bulk materials and thin films</subject><subject>Physics</subject><subject>Single crystals</subject><subject>Structure of solids and liquids; crystallography</subject><subject>Structure of specific crystalline solids</subject><subject>Treatment of materials and its effects on microstructure and properties</subject><issn>0022-0248</issn><issn>1873-5002</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNqFkc1u1DAUhS0EEkPhFVA2_En14J84TnZFFbRII7oA1pZj3zQeZZxge6DpijdgwRv2SeowLUvY2PLVd8658kHoOSVrSmj1drvemjDHyzCuGSF1Hq5Jwx6gFa0lx4IQ9hCt8skwYWX9GD2JcUtIVlKyQr8-zz71EF08LhaXpIciO_1IfX73OmiTILhrndzoC-1tEVPYm7QPcPPz96fNRTGFcYKQ5iLA8IeKvZsK5wt6zHHr4usS7yD149U89eDn4c0iwAyDxxSPHoro_OUA9-FP0aNODxGe3d1H6OuH919Oz_Hm4uzj6bsNNiURCduS1ILxkkphTGuNrBvLTdMJBsJKaVnbmE7UjOim6kgFmrQt17bVgmpbg-VH6NXBN6_zbQ8xqZ2LBoZBexj3UclaskoKITL58p8k54I3gpQZrA6gCWOMATo1BbfTYVaUqKUptVX3TamlqWWem8rCF3cJOho9dEF74-JfNaO0FFzWmTs5cJA_5ruDoKJx4A1YF8AkZUf3v6hbbySxfg</recordid><startdate>2009</startdate><enddate>2009</enddate><creator>Ravindra, H.J.</creator><creator>Harrison, W.T.A.</creator><creator>Suresh Kumar, M.R.</creator><creator>Dharmaprakash, S.M.</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>2009</creationdate><title>Synthesis, crystal growth, characterization and structure–NLO property relationship in 1,3-bis(4-methoxyphenyl)prop-2-en-1-one single crystal</title><author>Ravindra, H.J. ; Harrison, W.T.A. ; Suresh Kumar, M.R. ; Dharmaprakash, S.M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c405t-d4085234175ccbdc789d3c9f52e5d77d2b9cf5820a96f06ea0bb3adba51ad8ed3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>A1. Characterization</topic><topic>A2. Growth from solution</topic><topic>B1. Organic compound</topic><topic>B2. Nonlinear optical material</topic><topic>Charge transfer</topic><topic>Condensed matter: electronic structure, electrical, magnetic, and optical properties</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Cross-disciplinary physics: materials science; rheology</topic><topic>Crystal growth</topic><topic>Crystals</topic><topic>Deformation, plasticity, and creep</topic><topic>Diamond pyramid hardness</topic><topic>Differential thermal analysis</topic><topic>Diffraction</topic><topic>Evaporation</topic><topic>Exact sciences and technology</topic><topic>Growth from solutions</topic><topic>Materials science</topic><topic>Melts</topic><topic>Methods of crystal growth; physics of crystal growth</topic><topic>Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation</topic><topic>Optical properties of bulk materials and thin films</topic><topic>Physics</topic><topic>Single crystals</topic><topic>Structure of solids and liquids; crystallography</topic><topic>Structure of specific crystalline solids</topic><topic>Treatment of materials and its effects on microstructure and properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ravindra, H.J.</creatorcontrib><creatorcontrib>Harrison, W.T.A.</creatorcontrib><creatorcontrib>Suresh Kumar, M.R.</creatorcontrib><creatorcontrib>Dharmaprakash, S.M.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of crystal growth</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ravindra, H.J.</au><au>Harrison, W.T.A.</au><au>Suresh Kumar, M.R.</au><au>Dharmaprakash, S.M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis, crystal growth, characterization and structure–NLO property relationship in 1,3-bis(4-methoxyphenyl)prop-2-en-1-one single crystal</atitle><jtitle>Journal of crystal growth</jtitle><date>2009</date><risdate>2009</risdate><volume>311</volume><issue>2</issue><spage>310</spage><epage>315</epage><pages>310-315</pages><issn>0022-0248</issn><eissn>1873-5002</eissn><coden>JCRGAE</coden><abstract>High-quality single crystals of 1,3-bis(4-methoxyphenyl)prop-2-en-1-one (BMP) of size 20
mm×16
mm×5
mm have been grown by the slow evaporation of an acetone solution at 28
°C and characterized by elemental analysis, thermo-gravimetric analysis/differential thermal analysis (TGA/DTA), Fourier transform infrared (FTIR) spectroscopy and single-crystal X-ray diffraction. BMP crystallizes in the orthorhombic system with the noncentrosymmetric space group P2
12
12
1. The crystal melts at 107
°C and the average Vickers hardness number is 17
kg
mm
−2. BMP crystals are transparent in the entire visible region and have a lower optical cutoff at 435
nm. A Kurtz powder second harmonic generation (PSHG) measurement indicated that BMP and urea have similar responses. The observed SHG response for BMP is due to effective charge transfer arising from the donor–
π-acceptor–
π-donor (
D–
π–
A–
π–
D) structure of the molecule and the weak C–H…
π interaction observed in the crystal structure, which helps to stack the molecules in a noncentrosymmetric arrangement.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jcrysgro.2008.10.092</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0022-0248 |
| ispartof | Journal of crystal growth, 2009, Vol.311 (2), p.310-315 |
| issn | 0022-0248 1873-5002 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_787267555 |
| source | ScienceDirect Journals (5 years ago - present) |
| subjects | A1. Characterization A2. Growth from solution B1. Organic compound B2. Nonlinear optical material Charge transfer Condensed matter: electronic structure, electrical, magnetic, and optical properties Condensed matter: structure, mechanical and thermal properties Cross-disciplinary physics: materials science rheology Crystal growth Crystals Deformation, plasticity, and creep Diamond pyramid hardness Differential thermal analysis Diffraction Evaporation Exact sciences and technology Growth from solutions Materials science Melts Methods of crystal growth physics of crystal growth Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation Optical properties of bulk materials and thin films Physics Single crystals Structure of solids and liquids crystallography Structure of specific crystalline solids Treatment of materials and its effects on microstructure and properties |
| title | Synthesis, crystal growth, characterization and structure–NLO property relationship in 1,3-bis(4-methoxyphenyl)prop-2-en-1-one single crystal |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-27T17%3A47%3A23IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis,%20crystal%20growth,%20characterization%20and%20structure%E2%80%93NLO%20property%20relationship%20in%201,3-bis(4-methoxyphenyl)prop-2-en-1-one%20single%20crystal&rft.jtitle=Journal%20of%20crystal%20growth&rft.au=Ravindra,%20H.J.&rft.date=2009&rft.volume=311&rft.issue=2&rft.spage=310&rft.epage=315&rft.pages=310-315&rft.issn=0022-0248&rft.eissn=1873-5002&rft.coden=JCRGAE&rft_id=info:doi/10.1016/j.jcrysgro.2008.10.092&rft_dat=%3Cproquest_cross%3E33539504%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=33539504&rft_id=info:pmid/&rft_els_id=S0022024808011901&rfr_iscdi=true |