Epitaxial growth of Cr2O3 thin film on Al2O3 (0001 ) substrate by radio frequency magnetron sputtering combined with rapid-thermal annealing

We prepared epitaxially grown Cr2O3 thin films on Al2O3 (0001) substrate by using radio frequency magnetron sputtering at room temperature followed by a rapid-thermal annealing process. It is shown that the phase and the crystallinity of as-grown samples depend on the flow ratios of the working gas...

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Veröffentlicht in:Thin solid films 2010-06, Vol.518 (17), p.4813-4816
Hauptverfasser: JEONG, Sang-Yong, LEE, Jin-Bok, NA, Hyunseok, SEONG, Tae-Yeon
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container_end_page 4816
container_issue 17
container_start_page 4813
container_title Thin solid films
container_volume 518
creator JEONG, Sang-Yong
LEE, Jin-Bok
NA, Hyunseok
SEONG, Tae-Yeon
description We prepared epitaxially grown Cr2O3 thin films on Al2O3 (0001) substrate by using radio frequency magnetron sputtering at room temperature followed by a rapid-thermal annealing process. It is shown that the phase and the crystallinity of as-grown samples depend on the flow ratios of the working gas (Ar/O2). X-ray diffraction (XRD) results show that oxygen-rich CrO3 phase having preferred orientation is formed when sputter-grown at room temperature under the working gas (Ar/O2) flow ratios of 9:1 and 7:3. XRD I[brvbar]-scanning results exhibit that annealing causes the oxygen-rich CrO3 phase to transform into epitaxial Cr2O3 phase, which is confirmed by X-ray photoemission spectroscopy. The samples grown at the gas flow ratio of 9:1 exhibit very smooth surfaces with root mean square roughness of 0.1-0.3nm.
doi_str_mv 10.1016/j.tsf.2010.01.046
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subjects Aluminum oxide
Annealing
Chromium oxides
Composition and phase identification
Condensed matter: structure, mechanical and thermal properties
Cross-disciplinary physics: materials science
rheology
Deposition by sputtering
Epitaxial growth
Exact sciences and technology
Magnetron sputtering
Materials science
Methods of deposition of films and coatings
film growth and epitaxy
Phase transformations
Physics
Radio frequencies
Structure and morphology
thickness
Surfaces and interfaces
thin films and whiskers (structure and nonelectronic properties)
Theory and models of film growth
Thin film structure and morphology
Thin films
X-rays
title Epitaxial growth of Cr2O3 thin film on Al2O3 (0001 ) substrate by radio frequency magnetron sputtering combined with rapid-thermal annealing
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