Isomorphic substitution in vanadinite [Pb5(VO4)3Cl]-a Raman spectroscopic study
The Raman and infrared spectra of vanadinite [Pb5(VO4)3Cl] specimens from three localities were studied. Raman spectra were found to be both orientation and temperature dependent. Measurement of the Raman spectra at liquid nitrogen temperature allowed better band separation and increased the intensi...
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| Veröffentlicht in: | Journal of Raman spectroscopy 2003-03, Vol.34 (3), p.214-220 |
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| container_title | Journal of Raman spectroscopy |
| container_volume | 34 |
| creator | Frost, Ray L. Crane, Martin Williams, Peter A. Theo Kloprogge, J. |
| description | The Raman and infrared spectra of vanadinite [Pb5(VO4)3Cl] specimens from three localities were studied. Raman spectra were found to be both orientation and temperature dependent. Measurement of the Raman spectra at liquid nitrogen temperature allowed better band separation and increased the intensities of weak bands, thus permitting band assignment. Two types of isomorphous substitution were identified: (a) substitution in the bulk of the crystal where electron beam microanalysis identifies the presence of calcium and copper and (b) surface substitution where infrared spectroscopy shows the isomorphous substitution of vanadate by phosphate and of chloride by hydroxyl groups. Copyright © 2003 John Wiley & Sons, Ltd. |
| doi_str_mv | 10.1002/jrs.978 |
| format | Article |
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Raman spectra were found to be both orientation and temperature dependent. Measurement of the Raman spectra at liquid nitrogen temperature allowed better band separation and increased the intensities of weak bands, thus permitting band assignment. Two types of isomorphous substitution were identified: (a) substitution in the bulk of the crystal where electron beam microanalysis identifies the presence of calcium and copper and (b) surface substitution where infrared spectroscopy shows the isomorphous substitution of vanadate by phosphate and of chloride by hydroxyl groups. 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Raman Spectrosc</addtitle><description>The Raman and infrared spectra of vanadinite [Pb5(VO4)3Cl] specimens from three localities were studied. Raman spectra were found to be both orientation and temperature dependent. Measurement of the Raman spectra at liquid nitrogen temperature allowed better band separation and increased the intensities of weak bands, thus permitting band assignment. Two types of isomorphous substitution were identified: (a) substitution in the bulk of the crystal where electron beam microanalysis identifies the presence of calcium and copper and (b) surface substitution where infrared spectroscopy shows the isomorphous substitution of vanadate by phosphate and of chloride by hydroxyl groups. Copyright © 2003 John Wiley & Sons, Ltd.</description><subject>apatite</subject><subject>Band spectra</subject><subject>Calcium</subject><subject>Chlorides</subject><subject>Hydroxyl groups</subject><subject>infrared spectroscopy</subject><subject>mimetite</subject><subject>Phosphates</subject><subject>pyromorphite</subject><subject>Raman microscopy</subject><subject>Raman spectra</subject><subject>Separation</subject><subject>Vanadates</subject><subject>vanadinite</subject><issn>0377-0486</issn><issn>1097-4555</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2003</creationdate><recordtype>article</recordtype><recordid>eNp10F1LwzAUBuAgCs4p_oXeqUhn0iZNeilD53RsMj8GioSTNMPMftm06v69HRW98urcPOflnBehQ4IHBOPgbFW5QczFFuoRHHOfMsa2UQ-HnPuYimgX7Tm3whjHcUR6aDZ2RVZU5avVnmuUq23d1LbIPZt7H5BDYnNbG-_5VrHjxxk9CYfpiw_eHDLIPVcaXVeF00W5Wa-bZL2PdpaQOnPwM_vo4fLifnjlT2aj8fB84uuAc-GbhGJilDA8NpqaOFRCLyOlINYAoWJaJcCBRBAIrqjQjCREcUY1XWKIQgj76KjLLavivTGulpl12qQp5KZonOSCt98LHPxJ3V7qKrOUZWUzqNaSYLlpTLaNyda28rSTnzY16_-YvJ7fddrvtHW1-frVUL3JiIecycV0JDm5YXQxfZI4_AZbmHyH</recordid><startdate>200303</startdate><enddate>200303</enddate><creator>Frost, Ray L.</creator><creator>Crane, Martin</creator><creator>Williams, Peter A.</creator><creator>Theo Kloprogge, J.</creator><general>John Wiley & Sons, Ltd</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>200303</creationdate><title>Isomorphic substitution in vanadinite [Pb5(VO4)3Cl]-a Raman spectroscopic study</title><author>Frost, Ray L. ; Crane, Martin ; Williams, Peter A. ; Theo Kloprogge, J.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2778-ed401eb8e79ec4e93b8cf6bba9caa3b5cbda7a16a287b48c51d1b754c4f0a63a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2003</creationdate><topic>apatite</topic><topic>Band spectra</topic><topic>Calcium</topic><topic>Chlorides</topic><topic>Hydroxyl groups</topic><topic>infrared spectroscopy</topic><topic>mimetite</topic><topic>Phosphates</topic><topic>pyromorphite</topic><topic>Raman microscopy</topic><topic>Raman spectra</topic><topic>Separation</topic><topic>Vanadates</topic><topic>vanadinite</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Frost, Ray L.</creatorcontrib><creatorcontrib>Crane, Martin</creatorcontrib><creatorcontrib>Williams, Peter A.</creatorcontrib><creatorcontrib>Theo Kloprogge, J.</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of Raman spectroscopy</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Frost, Ray L.</au><au>Crane, Martin</au><au>Williams, Peter A.</au><au>Theo Kloprogge, J.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Isomorphic substitution in vanadinite [Pb5(VO4)3Cl]-a Raman spectroscopic study</atitle><jtitle>Journal of Raman spectroscopy</jtitle><addtitle>J. Raman Spectrosc</addtitle><date>2003-03</date><risdate>2003</risdate><volume>34</volume><issue>3</issue><spage>214</spage><epage>220</epage><pages>214-220</pages><issn>0377-0486</issn><eissn>1097-4555</eissn><abstract>The Raman and infrared spectra of vanadinite [Pb5(VO4)3Cl] specimens from three localities were studied. Raman spectra were found to be both orientation and temperature dependent. Measurement of the Raman spectra at liquid nitrogen temperature allowed better band separation and increased the intensities of weak bands, thus permitting band assignment. Two types of isomorphous substitution were identified: (a) substitution in the bulk of the crystal where electron beam microanalysis identifies the presence of calcium and copper and (b) surface substitution where infrared spectroscopy shows the isomorphous substitution of vanadate by phosphate and of chloride by hydroxyl groups. 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| ispartof | Journal of Raman spectroscopy, 2003-03, Vol.34 (3), p.214-220 |
| issn | 0377-0486 1097-4555 |
| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | apatite Band spectra Calcium Chlorides Hydroxyl groups infrared spectroscopy mimetite Phosphates pyromorphite Raman microscopy Raman spectra Separation Vanadates vanadinite |
| title | Isomorphic substitution in vanadinite [Pb5(VO4)3Cl]-a Raman spectroscopic study |
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