Infrared and Raman Spectra, conformations, ab initio calculations and spectral assignments of 1,3-disilabutane (SiH3CH2SiH2CH3)

Raman spectra of 1,3‐disilabutane (SiH3CH2SiH2CH3) as a liquid were recorded at 293 K and as a solid at 78 K. In the Raman cryostat at 78 K an amorphous phase was first formed, giving a spectrum similar to that of the liquid. After annealing to 120 K, the sample crystallized and large changes occurr...

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Veröffentlicht in:	Journal of Raman spectroscopy 2007-09, Vol.38 (9), p.1159-1173
Hauptverfasser:	Guirgis, Gamil A., Mazzone, Paul M., Pasko, Daniel N., Klaeboe, Peter, Horn, Anne, Nielsen, Claus J.
Format:	Artikel
Sprache:	eng
Schlagworte:	1,3‐disilabutane 3-disilabutane Annealing Band spectra Bands conformational analysis Crystallization DFT calculations Liquids Mathematical analysis Raman and infrared spectra Raman spectra Spectra
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