Fourier transform Raman spectra (in aqueous solution) of serine and tetraaqua serine aluminium(III) cation complex: [Al(Ser)(H2O)4]2+. DFT: B3LYP/3-21G structural and vibrational calculations

The tetraaquaserine aluminium(III) cation complex was prepared from a mixture of solutions 5 mol l−1 of Al(NO3)3·9H2O and serine (Ser) at pH 0.5. Raman spectra of serine and of serine with Al(NO3)3·9H2O, both in aqueous solution, show that four water molecules participate in the coordination sphere...

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Veröffentlicht in:	Journal of Raman spectroscopy 2004-01, Vol.35 (1), p.19-27
Hauptverfasser:	Téllez S., Claudio A., de Moraes Silva, Andrea, Felcman, Judith
Format:	Artikel
Sprache:	eng
Schlagworte:	Approximation Aqueous solutions Cations Density functional theory DFT: B3LYP/3-21G calculated spectra Fourier transforms FT-Raman geometric parameters Mathematical analysis Raman spectra Raman spectroscopy serine tetraaquaserine Al(III) cation complex
Online-Zugang:	Volltext
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